Self-standing bent silicon crystals for very high efficiency Laue lens

Silicon mono-crystals have been bent thanks to a series of parallel superficial indentations on one of the largest faces of the crystals. This technique relies on irreversible compression of the crystal beneath and beside the indentations. This latter causes deformation with no need for external device, resulting in a uniform self-standing curvature within the crystal. Indented Si crystals have been characterized at European Synchrotron Radiation Facility using a monochromatic beam ranging from 150 to 700 keV. Crystals exhibited very high diffraction efficiency over a broad range of energy, peaking 95% at 150 keV. Measured angular spread of the diffracted beam was always very close to the morphological curvature of the sample under investigation, proving that the energy passband of bent crystals can be controlled by simply imparting a selected curvature to the sample. The method of superficial indentations was found to offer high reproducibility and easy control of diffraction properties of the crystals. Moreover the method is cheap and simple, being based on mass production tools. A Laue lens made of crystals bent by superficial indentations can provide high-efficiency concentration of hard x-ray photons, leading significant improvement in many astrophysical applications.     

The contribution of seismic data in microzonation studies for downtown L��Aquila

After the 2009 April 6th Mw 6.3 L??Aquila earthquake (Central Italy) the Italian Civil Defense Department promoted the microzoning study in the ten zones in the epicentral area that suffered major damage. In this paper we present the activities and the results concerning a temporary seismic network installed in the historical L??Aquila city center indicated as ??macroarea 1?? in the microzoning project. Seismic data were collected to investigate the amplification effects in the city and to support the microzoning activities in verifying both geological profiles and 1D numerical modeling of the seismic response of the city. The conventional spectral approaches using both microtremor and earthquake data allowed to determine the fundamental resonance frequencies and the amplification factors within the city respectively. The spatial variability of these quantities can be related to the geological and geomorphologic characteristics of the investigated area. A comparison between the network data and the data recorded by the two strong motion instruments installed in the city was also made. This allows verifying the relative response of the accelerometric stations that recorded in the city the major events of the sequence.     

Characteristics and dynamics of multiple intertidal bars,north Lincolnshire,England

Multiple intertidal bars and troughs, often referred to as ‘ridges and runnels’, are significant features on many macrotidal sandy beaches. Along the coastline of England and Wales, they are particularly prevalent in the vicinity of estuaries, where the nearshore gradient is gentle and a large surplus of sediment is generally present. This paper examines the dynamics of such bar systems along the north Lincolnshire coast. A digital elevation model of the intertidal morphology obtained using LIDAR demonstrates that three to five intertidal bars are consistently present with a spacing of approximately 100 m. The largest and most pronounced bars (height = 0·5–0·8 m) are found around mean sea level, whereas the least developed bars (height = 0·2–0·5 m) occur in the lower intertidal zone. Annual aerial photographs of the intertidal bar morphology were inspected to try to track individual bars from year to year to derive bar migration rates; however, there is little resemblance between concurrent photographs, and ‘resetting’ of the intertidal profile occurs on an annual basis. Three‐dimensional beach surveys were conducted monthly at three locations along the north Lincolnshire coast over a one‐year period. The intertidal bar morphology responds strongly to the seasonal variation in the forcing conditions, and bars are least numerous and flattest during the more energetic winter months. Morphological changes over the monthly time scale are strongly affected by longshore sediment transport processes and the intertidal bar morphology can migrate along the beach at rates of up to 30 m per month. The behaviour of intertidal bars is complex and varies over a range of spatial and temporal scales in response to a combination of forcing factors (e.g. incident wave energy, different types of wave processes, longshore and cross‐shore sediment transport), relaxation time and morphodynamic feedback. Copyright © 2005 John Wiley & Sons, Ltd.     

Arsenic metabolism in a marine food chain

Radioarsenic was used to identify various chemical forms of arsenic, accumulated as arsenate from food or water, in a three-step food chain consisting of an autotroph, a grazer and a carnivore. Differential extraction procedures carried out on tissues from these organisms suggest that organic forms of arsenic in marine food webs are derived from an in vivo synthesis by primary producers and are efficiently transferred along a marine food chain. The muscle tissue of the carnivorous shrimp which represented the highest trophic level in this food chain could not itself form organic arsenic; in this case arsenate taken up from water was converted largely to arsenite.     

Combining physical-based models and satellite images for the spatio-temporal assessment of soil infiltration capacity

The performance of managed artificial recharge (MAR) facilities by means of surface ponds (SP) is controlled by the temporal evolution of the global infiltration capacity I _c of topsoils. Cost-effective maintenance operations that aim to maintain controlled infiltration values during the activity of the SP require the full knowledge of the spatio-temporal variability of I _c . This task is deemed uncertain. The natural reduction in time of I _c depends on complex physical, biological and chemical reactions that clog the soil pores and has been observed to decay exponentially to an asymptotic non-zero value. Moreover, the relative influence of single clogging processes depend on some initial parameters of the soil, such as the initial infiltration capacity (I _c,0). This property is also uncertain, as aquifers are typically heterogeneous and scarcely characterized in practical situations. We suggest a method to obtain maps of I _c using a geostatistical approach, which is suitable to be extended to engineering risk assessment concerning management of SP facilities. We propose to combine geostatistical inference and a temporally-lumped physical model to reproduce non-uniform clogging in topsoils of a SP, using field campaigns of local and large scale tests and additionally by means of satellite images as secondary information. We then postulate a power-law relationship between the parameter of the exponential law, λ, and I _c,0. It is found that calibrating the two parameters of the power law model it is possible to fit the temporal evolution of total infiltration rate at the pond scale in a MAR test facility. The results can be used to design appropriate measures to selectively limit clogging during operation, extending the life of the infiltration pond.     

Five centuries of Southern Moravian drought variations revealed from living and historic tree rings

Past, present, and projected fluctuations of the hydrological cycle, associated to anthropogenic climate change, describe a pending challenge for natural ecosystems and human civilizations. Here, we compile and analyze long meteorological records from Brno, Czech Republic and nearby tree-ring measurements of living and historic firs from Southern Moravia. This unique paleoclimatic compilation together with innovative reconstruction methods and error estimates allows regional-scale May?CJune drought variability to be estimated back to ad 1500. Driest and wettest conditions occurred in 1653 and 1713, respectively. The ten wettest decades are evenly distributed throughout time, whereas the driest episodes occurred in the seventeenth century and from the 1840s onward. Discussion emphasizes agreement between the new reconstruction and documentary evidence, and stresses possible sources of reconstruction uncertainty including station inhomogeneity, limited frequency preservation, reduced climate sensitivity, and large-scale constraints.     

Statistical downscaling in the arid central Andes: uncertainty analysis of multi-model simulated temperature and precipitation

Statistical downscaling is a technique widely used to overcome the spatial resolution problem of General Circulation Models (GCMs). Nevertheless, the evaluation of uncertainties linked with downscaled temperature and precipitation variables is essential to climate impact studies. This paper shows the potential of a statistical downscaling technique (in this case SDSM) using predictors from three different GCMs (GCGM3, GFDL and MRI) over a highly heterogeneous area in the central Andes. Biases in median and variance are estimated for downscaled temperature and precipitation using robust statistical tests, respectively Mann?CWhitney and Brown?CForsythe's tests. In addition, the ability of the downscaled variables to reproduce extreme events is tested using a frequency analysis. Results show that uncertainties in downscaled precipitations are high and that simulated precipitation variables failed to reproduce extreme events accurately. Nevertheless, a greater confidence remains in downscaled temperatures variables for the area. GCMs performed differently for temperature and precipitation as well as for the different test. In general, this study shows that statistical downscaling is able to simulate with accuracy temperature variables. More inhomogeneities are detected for precipitation variables. This first attempt to test uncertainties of statistical downscaling techniques in the heterogeneous arid central Andes contributes therefore to an improvement of the quality of predictions of climate impact studies in this area.     

Pacific Atmospheric Sulfur Experiment (PASE): dynamics and chemistry of the south Pacific tropical trade wind regime

The Pacific Atmospheric Sulfur Experiment (PASE) was a comprehensive airborne study of the chemistry and dynamics of the tropical trade wind regime (TWR) east of the island of Kiritibati (Christmas Island, 157º, 20?? W, 2º 52?? N). Christmas Island is located due south of Hawaii. Geographically it is in the northern hemisphere yet it is 6?C12º south of the intertropical convergence zone (ITCZ) which places it in the southern hemisphere meteorologically. Christmas Island trade winds in August and September are from east south east at 3?C15 ms^?1. Clouds, if present, are fair weather cumulus located in the middle layer of the TWR which is frequently labeled the buffer layer (BuL). PASE provided clear support for the idea that small particles (80 nm) were subsiding into the tropical trade wind regime (TWR) where sulfur chemistry transformed them to larger particles. Sulfur chemistry promoted the growth of some of these particles until they were large enough to activate to cloud drops. This process, promoted by sulfur chemistry, can produce a cooling effect due to the increase in cloud droplet density and changes in cloud droplet size. These increases in particle size observed in PASE promote additional cooling due to direct scattering from the aerosol. These potential impacts on the radiation balance in the TWR are enhanced by the high solar irradiance and ocean albedo of the TWR. Finally because of the large area involved there is a large factional impact on earth??s radiation budget. The TWR region near Christmas Island appears to be similar to the TWR that persists in August and September, from southwest of the Galapagos to at least Christmas Island. Transport in the TWR between the Galapagos and Christmas involves very little precipitation which could have removed the aerosol thus explaining at least in part the high concentrations of CCN (??300 at 0.5% supersaturation) observed in PASE. As expected the chemistry of sulfur in the trade winds was found to be initiated by the emission of DMS into the convective boundary layer (BL, the lowest of three layers). However, the efficiency with which this DMS is converted to SO₂ has been brought into further question by this study. This unusual result has come about as result of our using two totally different approaches for addressing this long standing question. In the first approach, based on accepted kinetic rate constants and detailed steps for the oxidation of DMS reflecting detailed laboratory studies, a DMS to SO₂ conversion efficiency of 60?C73% was determined. This range of values lies well within the uncertainties of previous studies. However, using a completely different approach, involving a budget analysis, a conversion value of 100% was estimated. The latter value, to be consistent with all other sulfur studies, requires the existence of a completely independent sulfur source which would emit into the atmosphere at a source strength approximately half that measured for DMS under tropical Pacific conditions. At this time, however, there is no credible scientific observation that identifies what this source might be. Thus, the current study has opened for future scientific investigation the major question: is there yet another major tropical marine source of sulfur? Of equal importance, then, is the related question, is our global sulfur budget significantly in error due to the existence of an unknown marine source of sulfur? Pivotal to both questions may be gaining greater insight about the intermediate DMS oxidation species, DMSO, for which rather unusual measurements have been reported in previous marine sulfur studies. The 3 pptv bromine deficit observed in PASE must be lost over the lifetime of the aerosol which is a few days. This observation suggests that the primary BrO production rate is very small. However, considering the uncertainties in these observations and the possible importance of secondary production of bromine radicals through aerosol surface reactions, to completely rule out the importance of bromine chemistry under tropical conditions at this time cannot be justified. This point has been brought into focus from prior work that even at levels of 1 pptv, the effect of BrO oxidation on DMS can still be quite significant. Thus, as in the case of DMS conversion to SO₂, future studies will be needed. In the latter case there will need to be a specific focus on halogen chemistry. Such studies clearly must involve specific measurements of radical species such as BrO.