Relationship among O, Mg isotopes and the petrography of two spinel-bearing compound chondrules

The petrological properties, and O and Al-Mg isotopic compositions of two spinel-bearing chondrules from the Allende CV chondrite were investigated using scanning electron microscopy and secondary ion mass spectrometry. A coarse spinel grain in a barred-olivine (BO) chondrule is less enriched in ¹⁶O (Δ¹⁷O ∼ −5‰; Δ¹⁷O = δ¹⁷O - 0.52 δ¹⁸O), whereas smaller spinel grains in a plagioclase-rich chondrule member of a compound chondrule are extremely ¹⁶O-rich (Δ¹⁷O ∼ −17‰) and the spinels have a strongly serrated character. The petrological features and ¹⁶O-enrichments of the spinels in the plagioclase-rich chondrule indicate that spinels originating in coarse-grained Ca-Al-rich Inclusions (CAIs) were incorporated into chondrule precursors and survived the chondrule-forming event. The degree of ¹⁶O-excesses among minerals within each chondrule is correlated to the crystallization sequences. This evidence suggests that the O isotopic variation among minerals may have resulted from incomplete exchange of O isotopes between ¹⁶O-rich chondrule melt and ¹⁶O-poor nebular gas. Aqueous alteration also has changed the O-isotope compositions in the mesostasis. The feldspathic mesostasis in the BO chondrule shows a disturbed Mg-Al isochron indicating that the BO chondrule experienced secondary alteration. While plagioclase in the plagioclase-rich chondrule member of the compound chondrule shows slight ²⁶Mg-excesses corresponding to (²⁶Al/²⁷Al)₀ = [4.6±4.0(2σ)] × 10⁻⁶, nepheline formed by secondary alteration shows no detectable excess. The Al-Mg isotopic system of these chondrules was disturbed by aqueous alteration and thermal metamorphism on the Allende parent body.     

Study of the structure of silica film by infrared spectroscopy and electron diffraction analyses

Amorphous silicon oxide films have been studied on the basis of electron diffraction (ED) analyses and infrared (IR) spectroscopy in order to elucidate the relationship between the structures. After the heat treatment of the film in air at 300 and 500°C, the ED pattern showed halo rings, and the IR spectra clearly changed. Intensity analysis of the ED pattern provided evidence for the structural change of the amorphous film. It was concluded that the spectral changes in the ranges of 9.2–10.2, 12.5–13.5 and 19.5–22.5 μm were the result of phase transitions of the microcrystallites of α-cristobalite to β-cristobalite, and α- or β-quartz. Astrophysical implications have been discussed.     

Particle dynamics in the deep water column of Sagami Bay, Japan. II: seasonal change in profiles of suspended phytodetritus

Vertical distributions of turbidity & phytodetritus (Chl.a and pheopigment), and their seasonal variations were measured in the deep water column of Sagami Bay, Japan, in June 1999, February 2000 and May 2000. Observations were carried out at eight stations along an east-west section of Sagami Bay using a CTD/water sampling system equipped with a memory-type infrared back-scattering meter which had been calibrated for the suspended particles collected in Sagami Bay. Turbidity increased close to the bottom in both summer and winter, indicating the existence of a benthic nepheloid layer throughout the year. But the vertical gradient of turbidity was much larger in summer than in winter. The concentration of Chl.a and pheopigment also increased in the benthic layer in summer, sometimes reaching values of more than 0.01 and 0.2 μg/l, respectively, much higher than those reported in hemipelagic regions of the ocean. In winter, on the other hand, Chl.a kept a constant low value throughout the deep water column. This indicates that the turbid water mass formed in the benthic layer in summer derives from the deposition of large amounts of phytodetritus in spring and the resuspension of these aggregates, which are subsequently decomposed in the benthic layer during the following autumn. Unlike the benthic boundary layer, the turbidity of intermediate water was lower in summer rather than in winter. Because the phytoplankton aggregates exported from the surface water during the spring bloom not only supply phytodetritus to the benthic layer but also scavenge the suspended particles in the water column, the steep vertical gradient of turbidity observed in summer may reflect the dynamic interaction between suspended and sinking particles in the deep water column.     

Origin and decomposition of sinking particulate organic matter in the deep water column inferred from the vertical distributions of its δN, δ and δ

Sinking particles were analyzed for their nitrogen isotopic ratio δ¹⁵N) of total particulate nitrogen (PN), stable carbon isotopic ratio (δ¹³C) and radioactive isotopic ratio (δ¹⁴C) of total particulate organic carbon (POC), at three different latitudinal (temperate, subpolar and equatorial) and geomorphological (trench, proximal abyssal plain and distal abyssal plain) sites in the western North Pacific Ocean using year-long time series sediment trap systems, to clarify the common vertical trends of the isotopic signals in deep water columns. Although the δ¹⁵N and δ¹³C values of sinking particulate organic matter (POM) were partly affected by the resuspension of sedimentary POM from the sea floor, especially in the trench, the changes in δ¹⁵N and δ¹³C values owing to the resuspension could be corrected by calculation of the isotopic mass balance from δ¹⁴C of sinking POC. After this correction, common downward decreasing trends in δ¹⁵N and δ¹³C values were obtained in the deep water columns, irrespective of the latitudes and depths. These coincidental isotopic signals between δ¹⁵N and δ¹³C values provide new constraints for the decomposition process of sinking POM, such as the preferential degradation of ¹⁵N- and ¹³C-rich compounds and the successive re-formation of the sinking particles by higher trophic level organisms in the deep water column.     

Inversion for laterally heterogeneous upper mantle S-wave velocity structure using iterative waveform inversion

In contrast to previous work, which treats the Earth's lateral heterogeneity as an infinitesimal perturbation to a spherically symmetrical starting model, we conduct iterative linearized waveform inversion for the Earth's laterally heterogeneous structure. We use the Direct Solution Method (DSM) (Geller et al. 1990a) to calculate synthetic seismograms and their partial derivatives for a laterally heterogeneous earth model. We invert surface-wave data from the IDA and GEOSCOPE networks. We expand the lateral heterogeneity of rigidity in spherical harmonics up to angular order number 8 and use three parameters to specify the depth dependence of each harmonic, giving us a total of 240 unknowns. The short-wavelength lateral heterogeneity (s = 4, 6 and 8) in the deeper part of the upper mantle obtained by this study differs significantly from M84A. The relative improvement in the variance reduction as compared with model M84A is about 20 per cent for the IDA data and more than 100 per cent for the GEOSCOPE data.     

Deflection and Rotation of CMEs from Active Region 11158

Between 13 and 16 February 2011, a series of coronal mass ejections (CMEs) erupted from multiple polarity inversion lines within active region 11158. For seven of these CMEs we employ the graduated cylindrical shell (GCS) flux rope model to determine the CME trajectory using both Solar Terrestrial Relations Observatory (STEREO) extreme ultraviolet (EUV) and coronagraph images. We then use the model called Forecasting a CME’s Altered Trajectory (ForeCAT) for nonradial CME dynamics driven by magnetic forces to simulate the deflection and rotation of the seven CMEs. We find good agreement between ForeCAT results and reconstructed CME positions and orientations. The CME deflections range in magnitude between \(10^{\circ }\) and \(30^{\circ}\). All CMEs are deflected to the north, but we find variations in the direction of the longitudinal deflection. The rotations range between \(5^{\circ}\) and \(50^{\circ}\) with both clockwise and counterclockwise rotations. Three of the CMEs begin with initial positions within \(2^{\circ}\) from one another. These three CMEs are all deflected primarily northward, with some minor eastward deflection, and rotate counterclockwise. Their final positions and orientations, however, differ by \(20^{\circ}\) and \(30^{\circ}\), respectively. This variation in deflection and rotation results from differences in the CME expansion and radial propagation close to the Sun, as well as from the CME mass. Ultimately, only one of these seven CMEs yielded discernible in situ signatures near Earth, although the active region faced toward Earth throughout the eruptions. We suggest that the differences in the deflection and rotation of the CMEs can explain whether each CME impacted or missed Earth.     

Processes influencing iron distribution in the coastal waters of the Tsugaru Strait,Japan

We report measurements of iron, nutrients, dissolved oxygen, humic-type fluorescence intensity and chlorophyll a concentrations in the coastal waters at the inflow (western) and outflow (eastern) ends of Tsugaru Strait (Japan) in June 2003 and 2004. Two different water masses (intensive eastward flow “subtropical Tsugaru Warm Current Water (TWCw)” and weak westward flow “subarctic Oyashio Water (OW)”) were observed at the eastern end of the strait. TWCw at the southern part of the eastern strait was vertically homogeneous with a uniform concentrations of iron (0.7–1.1 nM for labile dissolved Fe and 14–20 nM for total dissolvable Fe in 2003) as well as other chemical, biological and physical components throughout the water column of 200 m due to strong vertical mixing in the strait. The degree of mixing in the Tsugaru Warm Current (TWC) is predominantly affected by diurnal tidal current, which is strong during the period of tropical tides and weak during the period of equinoctial ones. The especially strong vertical water mixing in 2003 is caused by large dissipation energy input due to the bottom friction of passage-flow through the strait and tidal current. At the northern part of the eastern strait, the fresh surface layer overlying the OW and the deep-bottom waters in 2003 contained large concentrations of dissolved iron, resulting from iron supplied from river runoff and shelf sediments, respectively. These results suggest that the most important mechanism for transporting iron in the strait is the strong vertical water mixing due to the tidal current, and that the iron sources in the coastal waters are the organic-associated, iron-rich freshwater input into the surface water.     

不同类型生态系统水热碳通量的监测与研究

亚太地区环境革新战略项目(APEIS) 在中国5种主要生态系统类型区(草地: 海北、耕地: 禹城、稻田: 桃源、林地: 千烟洲、荒漠: 阜康) 建立了一个以连续观测能量、水分和碳素通量为中心,包括气象、水文、土壤、植被等各项生态要素的监测网络系统,被称之为APEIS-FLUX系统。作者首先对APEIS-FLUX系统的观测数据进行了初步分析,表明该系统稳定可靠,它可以实时地提供高质量、高精度、长期而连续的通量及生态要素的观测数据。对数据的比较清楚地反映出了不同生态系统类型区的水热碳通量的差异性。其次,利用APEIS-FLUX数据对美国航空航天局(NASA) 的MODIS数据产品进行比较验证后发现,除部分产品如地表面温度(MOD11) 等与观测数据较吻合以外,大部分数据产品如土地覆盖(MOD12),叶面积指数(MOD15) 和光合速率与净第一性生产力(MOD17) 等都与观测数据相差深远,有必要对其处理程序和模式进行修正。为此,我们利用APEIS-FLUX的数据作为MOD15和MOD17的生成模型(BIOME-BGC) 的输入数据,并对该模型的有关参数进行了修订。结果表明,该模式在通过修正后,可以很好地模拟植被的生长过程及其相应的水热碳循环过程。