Geospatial Analysis of Space–Time Patterning of ENSO Forced Daily Precipitation Distributions in the Gulf of Mexico

The Gulf of Mexico experiences significant changes in the distribution of daily precipitation totals that are linked to the El Niño–Southern Oscillation (ENSO). This research uses geospatial techniques to examine distribution patterns of ENSO-related precipitation. Kolmogorov–Smirnov test results comparing daily rainfall distributions for El Niño and La Niña are mapped at a 1° × 1° latitude/longitude resolution, and hotspot analysis using local Moran's I is performed to identify spatial clustering. Results indicate that ENSO-forced spatial and temporal variation in daily precipitation distributions influence large areas of the Gulf of Mexico region from August through January.     

A comparison of high‐resolution specific conductance‐based end‐member mixing analysis and a graphical method for baseflow separation of four streams in hydrologically challenging agricultural watersheds

Quantifying the relative contributions of different sources of water to a stream hydrograph is important for understanding the hydrology and water quality dynamics of a given watershed. To compare the performance of two methods of hydrograph separation, a graphical program [baseflow index (BFI)] and an end‐member mixing analysis that used high‐resolution specific conductance measurements (SC‐EMMA) were used to estimate daily and average long‐term slowflow additions of water to four small, primarily agricultural streams with different dominant sources of water (natural groundwater, overland flow, subsurface drain outflow, and groundwater from irrigation). Because the result of hydrograph separation by SC‐EMMA is strongly related to the choice of slowflow and fastflow end‐member values, a sensitivity analysis was conducted based on the various approaches reported in the literature to inform the selection of end‐members. There were substantial discrepancies among the BFI and SC‐EMMA, and neither method produced reasonable results for all four streams. Streams that had a small difference in the SC of slowflow compared with fastflow or did not have a monotonic relationship between streamflow and stream SC posed a challenge to the SC‐EMMA method. The utility of the graphical BFI program was limited in the stream that had only gradual changes in streamflow. The results of this comparison suggest that the two methods may be quantifying different sources of water. Even though both methods are easy to apply, they should be applied with consideration of the streamflow and/or SC characteristics of a stream, especially where anthropogenic water sources (irrigation and subsurface drainage) are present. Copyright © 2014 John Wiley & Sons, Ltd.     

Fractal sinuosity of stream channels

Analysis of a diverse set of twelve stream channel planforms indicates that at scales relevant to river meandering, river traces are most reasonably treated as fractal curves. The atypically high degree of channel wandering apparent at such scales is a common characteristic of all single-channel streams, while identifiable meandering appears to be only one way in which this tendency is expressed. At smaller scales of view river paths have shapes of smooth curves appropriate to Euclidian geometry, and toward larger scales a distinct change in degree of wandering marks the transition to bends that are considered to be changes in general river course rather than parts of channel pattern. This analysis method provides a natural, objective calculation of river sinuosity as well as other parameters that more completely specify channel planform.     

The influence of habitat structure on juvenile fish in a New Zealand estuary

Estuarine and sheltered coastal habitats that contain physical structure are potentially important nurseries for juvenile fish. Many of these structured habitats, however, are potentially vulnerable to stressors such as elevated turbidity. Quantifying the benefits that structured habitats provide to juvenile fish may therefore be an important step in the management process. We investigated the value of structured habitat for juvenile fishes in northeastern New Zealand, using artificial seagrass units (ASUs) with varying blade density. ASUs were predominantly settled by juvenile snapper (Pagrus auratus) and spotty (Notolabrus celidotus). The density of both snapper and spotty was greatest on ASUs with the highest blade density. For snapper, a gradient in abundance was present (with higher abundance closer to the harbour mouth), suggesting either a gradient in the supply of recruits or a potential recruitment shadow effect. The size distribution of juvenile snapper (12–70 mm fork length) was very similar on both sampling trips, despite the 2‐month interim period, suggesting an ontogenetic habitat shift dependent on size. The condition of juvenile snapper from ASUs with the highest blade density was also greater than the other ASU treatments. Overall, these results provide new empirical evidence that habitats with physical structure within shallow estuarine systems are important to early stage juvenile fishes such as snapper, and indicate that the location‐specific context of that habitat is also likely important.     

Size characteristics of sediment in interrill overland flow on a semiarid hillslope,Southern Arizona

This study examines the size characteristics of sediment removed from a semiarid hillslope by interrill overland flow. Rainfall simulation experiments were conducted on a runoff plot 18 m wide and 35 m long established on a piedmont hillslope in southern Arizona. The top of the plot coincided with the hillslope divide, and its outlet was located within a shallow rill. Samples of runoff were obtained from two cross-sections located in the interrill portion of the plot upslope of the rill and from a calibrated flume through which was directed interrill overland flow reaching the bottom of the plot. Analyses of sediment contained in these samples showed that sediment in interrill flow is finer than the matrix soil. The fineness of the interrill sediment compared to the matrix soil appears to be due to the inability of interrill overland flow to transport the coarser fraction of the sediment supplied to it by raindrop detachment. This finding implies that the rate of soil erosion in interrill areas is not. as is commonly supposed, limited by the rate at which raindrops can detach sediment but by the rate at which they detach sediment of a size that the overland flow is competent to transport. The relative fineness of sediment eroded from this hillslope is consistent with other evidence for the recent evolution of shrub-covered hillslopes in southern Arizona.     

Stability and equation of state of post-aragonite BaCO3

At ambient conditions, witherite is the stable form of BaCO₃ and has the aragonite structure with space group Pmcn. Above ~10 GPa, BaCO₃ adopts a post-aragonite structure with space group Pmmn. High-pressure and high-temperature synchrotron X-ray diffraction experiments were used to study the stability and equation of state of post-aragonite BaCO₃, which remained stable to the highest experimental P–T conditions of 150 GPa and 2,000 K. We obtained a bulk modulus K ₀ = 88(2) GPa with $K'$  = 4.8(3) and V ₀ = 128.1(5) ų using a third-order Birch-Murnaghan fit to the 300 K experimental data. We also carried out density functional theory (DFT) calculations of enthalpy (H) of two structures of BaCO₃ relative to the enthalpy of the post-aragonite phase. In agreement with previous studies and the current experiments, the calculations show aragonite to post-aragonite phase transitions at ~8 GPa. We also tested a potential high-pressure post–post-aragonite structure (space group C222 ₁ ) featuring four-fold coordination of oxygen around carbon. In agreement with previous DFT studies, ΔH between the C222 ₁ structure and post-aragonite (Pmmn) decreases with pressure, but the Pmmn structure remains energetically favorable to pressures greater than 200 GPa. We conclude that post–post-aragonite phase transformations of carbonates do not follow systematic trends observed for post-aragonite transitions governed solely by the ionic radii of their metal cations.