Fluvial architecture and diagenesis of the Mt Eclipse Sandstone,northern Ngalia Basin,Australia

The Upper Devonian to Carboniferous Mt Eclipse Sandstone is a basin-wide host to uranium mineralisation in the Ngalia Basin, NT. The fluvial depositional architecture and diagenesis of the Mt Eclipse Sandstone at the Bigrlyi uranium deposit on the northern margin of the basin are deduced from hyperspectral mineral results captured from 200 drill holes, combined with core and outcrop observations across a ~10 km strike length. The succession hosting the uranium mineralisation is interpreted to be deposited in the lower parts of a mature alluvial fan system with low slope angle and dominated by immature, kaolinised, medium-grained subarkosic sandstones and patchy calcite cement. This study reveals the fluvial channel sequence is estimated to be 3 km wide, 100–200 m thick and sourced from the north. This multidisciplinary study also uncovers the complex interaction and codependencies between fluvial/groundwater activity, evaporation, oxidation, fluctuating pH and detrital mineralogy controlling early diagenetic processes in the alluvial fan sediments. Carbon isotope data identify calcite cements as groundwater calcrete, while strontium isotope data suggest limited prolonged water–rock interaction prior and during calcite cementation. The petrographic data reveal the importance of early calcite cement occluding all pore space and preserving detrital minerals from later diagenetic processes. The hyperspectral results highlight the intermittent distribution of the calcite cement and the commonly repetitive mineralogical zonation throughout the 200 drill holes, including the inverse spatial correlation between kaolinite ± goethite ± gypsum vs white mica ± hematite dominated zones. X-ray diffraction and the hyperspectral data reveal the scarcity of early diagenetic clay minerals such as montmorillonite. This paper is the first to report on a systematic mineralogical and sedimentological study for the Mt Eclipse Sandstone. By focusing on the diagenesis and fluvial architecture of this stratigraphic unit, a framework to support exploration for sediment-hosted uranium deposits is established.     

Micro-XANES determination of ferric iron and its application in thermobarometry

Micro-X-ray absorption near-edge structure (XANES) analysis was employed to determine the content of ferric iron in minerals formed in ultrahigh-pressure (UHP) eclogites. It is observed that omphacite and phengite contain significant amounts of Fe³⁺/Fe_tot (0.2–0.6), whereas only very low contents are present in garnet (Fe³⁺/Fe_tot=0.0–0.03), the latter being consistent with results from stoichiometric charge-balance calculations. Furthermore, considerable variations in the Fe³⁺/Fe_tot ratios of omphacite and phengite are observed depending on the textural sites and local bulk chemistry (eclogite and calc-silicate matrix) within one thin section. The oxidation state of isofacial minerals is thus likely to depend on the local fluid composition, which, in the studied case, is controlled by calcareous and meta-basic mineral compositions. These first in-situ measurements of ferric iron in an eclogite sample from the Dabie Shan, E China, are used to recalculate geothermobarometric data. Calculations demonstrate that the temperature during UHP metamorphism was as high as 780 °C, about 80–100 °C higher than previously estimated. Temperatures based on charge balance calculations often give erroneous results. Pressure estimates are in good agreement with former results and confirm metamorphism in the stability field of diamond (43.7 kbar at 750 °C). These P–T data result in a geothermal gradient of ca. 6 °C/km during UHP metamorphism in the Dabie Shan. However, accounting for ferric iron contents in geothermobarometry creates new difficulties inasmuch as calibrations of geothermometers may not be correctable for Fe³⁺ and the actual effect on Mg–Fe²⁺ partitioning is unknown. The present study further shows that micro-XANES is a promising technique for the in situ determination of ferric iron contents without destroying the textural context of the sample: a clear advantage compared to bulk methods.     

Cenozoic intra-plate magmatism in the Darfur volcanic province: mantle source, phonolite-trachyte genesis and relation to other volcanic provinces in NE Africa

Chemical and Sr, Nd and Pb isotopic compositions of Late Cenozoic to Quaternary small-volume phonolite, trachyte and related mafic rocks from the Darfur volcanic province/NW-Sudan have been investigated. Isotope signatures indicate variable but minor crustal contributions. Some phonolitic and trachytic rocks show the same isotopic composition as their primitive mantle-derived parents, and no crustal contributions are visible in the trace element patterns of these samples. The magmatic evolution of the evolved rocks is dominated by crystal fractionation. The Si-undersaturated strongly alkaline phonolite and the Si-saturated mildly alkaline trachyte can be modelled by fractionation of basanite and basalt, respectively. The suite of basanite–basalt–phonolite–trachyte with characteristic isotope signatures from the Darfur volcanic province fits the compositional features of other Cenozoic intra-plate magmatism scattered in North and Central Africa (e.g., Tibesti, Maghreb, Cameroon line), which evolved on a lithosphere that was reworked or formed during the Neoproterozoic.     

Animal production and climate variation in the Faeroe Islands in the 19th century

The article deals with aspects of the historical geography of the Faeroe Islands in the 19th century with a focus on animal production, i.e. sheep and cows. It is based on material from the Regional Archive, Føroya Landsskjalasavn. The tithe lists showing the King's third from Norderöe district, 1801–1859, are analysed in detail and compared with the statements from another series of documents, the Sheriff s half-yearly reports on the state of the district. Together these two sets of records give a detailed picture of the development and variation in the number of cows, paying “butter-tithe” and the number of sheep slaughtered, paying “wool-tithe”. The number of cows surviving the winter, depended on the amount and quality of winter fodder or hay, which was produced in the infield the preceding summer. The sheep, on the other hand, that can survive the winter while grazing in the outfield, are dependent on the severity or mildness of the winter as well as their condition in the lambing period. The two series provide data on summer as well as winter weather conditions. The analysis makes an attempt, using the concepts known from the critical realist theory of science, to find the mechanisms as well as necessary and contingent conditions involved in the two processes.     

Sand,hearths, lithics and a bit of bioturbation: Site formation processes at Umhlatuzana rockshelter,South Africa

Umhlatuzana rockshelter is known for its continuous record of Middle and Later Stone Age lithic assemblages. This study presents multiproxy geoarchaeological data (micromorphology, X-ray diffraction and scanning electron microscopy with energy-dispersive spectroscopy) to reconstruct the depositional and post-depositional history of the site. Although the Stone Age deposits macroscopically appear homogeneous, micromorphological analysis reveals the existence of primary, unaltered depositional microlayering throughout the sequence. Sediments related to combustion activities on-site are observed in both the Holocene and Pleistocene deposits. Post-depositional geochemical alterations result in the formation of several phosphatic minerals that significantly affect the site's preservation conditions. One of those is vashegyite, a rare magnesium phosphate mineral related to acidic and moist sedimentary environments. Bioturbation features are prominent at the microscale, but sediment mixing does not seem to affect the vertical distribution of the artifacts. The observation of horizontal microlayering in both the Pleistocene and Holocene illuminates the dominant mechanism of sedimentation throughout the site's 70,000-year occupational history. It moreover shows that the lithics can be analysed as coherent assemblages.