Radiation-induced decomposition of U(VI) phases to nanocrystals of UO2

U⁶⁺-phases are common alteration products, under oxidizing conditions, of uraninite and the UO₂ in spent nuclear fuel. These U⁶⁺-phases are subjected to a radiation field caused by the α-decay of U, or in the case of spent nuclear fuel, incorporated actinides, such as ²³⁹Pu and ²³⁷Np. In order to evaluate the effects of α-decay events on the stability of the U⁶⁺-phases, we report, for the first time, the results of ion beam irradiations (1.0 MeV Kr²⁺) of U⁶⁺-phases. The heavy-particle irradiations are used to simulate the ballistic interactions of the recoil-nucleus of an α-decay event with the surrounding structure. The Kr²⁺-irradiation decomposed the U⁶⁺-phases to UO₂ nanocrystals at doses as low as 0.006 displacements per atom (dpa). U⁶⁺-phases accumulate substantial radiation doses (∼1.0 displacement per atom) within 100,000 yr if the concentration of incorporated ²³⁹Pu is as high as 1 wt.%. Similar nanocrystals of UO₂ were observed in samples from the natural fission reactors at Oklo, Gabon. Multiple cycles of radiation-induced decomposition to UO₂ followed by alteration to U⁶⁺-phases provide a mechanism for the remobilization of incorporated radionuclides.     

Energy dissipation behaviour of shear panels made of low yield steel

This paper presents the results of a pilot test conducted for evaluating the energy dissipation behaviour of shear panels made of low yield steel whose 0.2 per cent offset yield stress is 120 MPa. A total of six full-scale shear panels were tested with the loading condition, stiffener spacing, and magnitude of axial force as test variables. The shear panels tested yielded at a shear force that is approximately 1/3 of the yield shear force of equivalent shear panels made of common mild steel. Shear panels with proper stiffener arrangement exhibited stable hysteresis, thus ensuring large energy dissipation capacity. Sufficient strain hardening was observed in the shear panels tested, with their energy dissipation capacity about 1.5 times larger than that of an equivalent linear-elastic and perfect-plastic system. Plate buckling did not lead the shear panels to immediate degradation in their energy dissipation capacity. Post-buckling resistance was found to be a subject that requires further studies for quantifying the performance of shear panels made of low yield stress steel as hysteretic dampers.     

Slope instability phenomena in permafrost regions of Qinghai-Tibet Plateau, China

Permafrost covers a significant area of the Qinghai-Tibet Plateau. Slope instability problem in the region was often neglected, though it plays important roles in engineering construction and landform processes. In this paper, the slope instability phenomena in the permafrost regions on the plateau are discussed. The slope failures often occur in the forms of thaw-induced landslides and gelifluction. Thaw-induced landslides are closely related to active layer detachment and changes of permafrost conditions. Such landslides include retrogressive flow and thaw slump and are hazardous to engineering constructions. Gelifluction includes deep-seated movement and surface movement. It is an important factor in landform planation because it may spread over a large area and remain active for a long period of time.     

Trace Element Analysis of Fused Whole-Rock Glasses by Laser Ablation-ICP-MS and PIXE

The concentrations of fifty trace elements, including relatively volatile elements and transition metal elements, in fused glasses of Geological Survey of Japan rock reference materials GSJ JR-2, JA-1, JA-2, JB-1a, JB-3, JGb-1 and JF-1 were determined by particle (proton) induced X-ray emission (PIXE) and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS). The fused glasses were prepared by rapid fusion and subsequent quenching in welded platinum capsules and were found to be homogeneous for major elements and for trace elements with concentrations of more than 1 μg g^-1 within the observed precision (± 10% mean) on a 70 μm sampling scale. The values obtained by PIXE and LA-ICP-MS for the transition elements (Cr, Mn, Fe, Ni and Cu), the relatively volatile elements (Zn, Ga, Rb and Pb) and the refractory elements (Y, Zr, Nb and Th) with concentrations greater than a few μg g^-1 showed good agreement (within 10 % relative difference). The values for almost all the elements detected at concentrations higher than 1 μg g^-1 as determined by LA-ICP-MS also agreed well with the reference values (mean relative difference < ± 10%), except for B and Cu. The good agreement confirmed the appropriateness of the NIST SRM 600 series glass calibration reference material for LA-ICP-MS analysis of glasses with variable major-element compositions for almost all elements. The concentrations of Cu in all the samples were lower than the reference values, which was attributed to adsorption of the transition metals onto the platinum capsule during preparation.     

Crystallization of microlites and degassing during magma ascent: Constraints on the fluid mechanical behavior of magma during the Tenjo Eruption on Kozu Island, Japan

Bubble and crystal textures provide information with regard to the kinetics of the vesiculation and crystallization processes. They also provide insights into the fluid mechanical behavior of magma in a conduit. We performed textural (bubble and crystal) and compositional analyses of pyroclasts that were obtained from the Tenjo pyroclastic flow, which resulted on account of the eruption in 838 A.D. on Kozu Island, about 200 km south of Tokyo, Japan. Pyroclasts in one flow unit (300∼2,060 kg/m³; average density 1330 kg/m³) can be classified into three types on the basis of vesicle textures. Type I pyroclasts have small isolated spherical bubbles with higher vesicularities (67–77 vol.%) and number density (10.8–11.7 log m⁻³). Type II pyroclasts have vesicularities similar to type I (61–69 vol.%), but most bubbles exhibit evidences of bubble coalescence, and lower number densities than type I (8.9–9.5 log m⁻³). Type III pyroclasts contain highly deformed bubbles with lower vesicularities (16–34 vol.%) and number densities (8.2–9.0 log m⁻³). The microlite volume fraction (DRE converted) also changes consistently across type I, type II, and type III as 0.06, 0.08, and 0.10–0.15, respectively. However, the number density of the microlites remains nearly invariant in all the pyroclast types. These facts indicate that the variation in the microlite volume fraction is controlled not by the number density (i.e., nucleation process), but by the size (i.e., growth process); the growth history of each type of microlite was different. Water content determinations show that the three types of pumices have similar H₂O contents (2.6±0.2 wt%). This fact implies that all three types were quenched at nearly the same depth (35±5 MPa, assuming that the magma was water-saturated) in the conduit. If the crystal sizes are limited only by growth time, a variation in this parameter can be related to the residence time, which is attributed to the flow heterogeneity in the conduit. By assuming a laminar Poiseuille-type flow, these textural observations can be explained by the difference in ascent velocity and shearing motion across the conduit, which in turn results in the differences in growth times of crystals, degrees of deformation, and bubble coalescence. Consequently, for crystals in the inner part of the conduit, the crystal growth time from nucleation to quenching is shorter than that near the conduit wall. The vesicle texture variation of bubbles in types I, II, and III results from the difference in the deformation history, implying that the effect of degassing occurred primarily towards the conduit wall.     

Operational Data Assimilation System for the Kuroshio South of Japan: Reanalysis and Validation

We describe an operational ocean data assimilation system for the Kuroshio and its validation using a nine-year reanalysis (historical run from 1993 to 2001) dataset of upper-ocean state estimation in the North Pacific. The horizontal structure of volume transport of the Ryukyu Current System (RCS) is shown from the reanalysis: The RCS is connected to the flow of the subtropical gyre, and its volume transport gradually increases from south-east of Okinawa (5–10 Sv) to the east of Amami-Ohshima Island (20 Sv). Comparing the reanalysis with independent observations on the southeast slope of the Amami-Ohshima Island indicates that the root mean square differences (RMSDs) are 0.076 (0.037) m/s in the period of December 1998 to November 1999 (November 1999 to November 2000) respectively. The reanalysis field has a bias (3.1 Sv) of the volume transport of the RCS and the RMSD (3.5 Sv) which is larger than the observed variability (2.81 Sv). Surface velocity and the Kuroshio axis south of Japan are also examined. Comparison of the reanalysis and ADCP data gave maximum RMSD of 0.749 (0.271) m/s in the strong (weak) current regions, respectively. The annual mean value of the axis error is 19 km in 1998. The RMSD of the error is at most 50 km, in 294 cases in the observation period, which is smaller than the observed root mean square variability of the axis (64 km). This revised version was published online in July 2006 with corrections to the Cover Date.     

Blended-acquisition design of irregular geometries towards faster,cheaper, safer and better seismic surveying

The application of blended acquisition has drawn considerable attention owing to its ability to improve the operational efficiency as well as the data quality and health, safety and environment performance. Furthermore, the acquisition of less data contributes to the business aspect, while the desired data density is still realizable via subsequent data reconstruction. The use of fewer detectors and sources also minimizes operational risks in the field. Therefore, a combined implementation of these technologies potentially enhances the value of a seismic survey further. One way to encourage this is to minimize any imperfection in deblending and data reconstruction during processing. In addition, one may derive survey parameters that enable a further improvement in these processes as introduced in this study. The proposed survey design workflow iteratively performs the following steps to derive the survey parameters responsible for source blending as well as the spatial sampling of detectors and sources. The first step is the application of blending and sampling operators to unblended and well-sampled data. We then apply closed-loop deblending and data reconstruction. The residue for a given design from this step is evaluated and subsequently used by genetic algorithms to simultaneously update the survey parameters related to both blending and spatial sampling. The updated parameters are fed into the next iteration until they satisfy the given termination criteria. We also propose a repeated encoding sequence to form a parameter sequence in genetic algorithms, making the size of problem space manageable. The results of the proposed workflow are outlined using blended dispersed source array data incorporating different scenarios that represent acquisition in marine, transition zone and land environments. Clear differences attributed solely to the parameter design are easily recognizable. Additionally, a comparison among different optimization schemes illustrates the ability of genetic algorithms along with a repeated encoding sequence to find better solutions within a computationally affordable time. The optimized parameters yield a notable enhancement in the deblending and data reconstruction quality and consequently provide optimal acquisition scenarios.     

Depositional and diagenetic history of limestones and dolostones of the Oligo‐Miocene Kujung Formation in the Northeast Java Basin,Indonesia

Lithological and geochemical features of platformal carbonates record the signatures of the global climates and the regional environmental settings and also reconstruct the diagenetic history and porosity evolution, which are essential to evaluate the potential of hydrocarbon reservoirs. This study investigates the platformal carbonates of the Oligo‐Miocene Krunji Formation of North East Java Basin, which are potentially significant hydrocarbon reservoirs. The carbonate sequence in a 283 m thick section at Kranji in East Java is subdivided into three lithological units: limestone unit 1, dolostone unit 2, and limestone unit 3, in ascending order. The strontium‐isotope ratios of well‐preserved calcite samples indicate the depositional period from Chattian (late Oligocene) to Burdigalian (early Miocene), which is consistent with ages of the foraminifer assemblages. Unit 1 consists of low‐porosity limestone, in which two horizons of subaerial exposure are recognized by the occurrence of red‐colored matrix and lower δ¹³C values. Unit 2 consists of dolomitic rock and exhibits coarse‐grained calcitic grains and cross‐stratified structure. Considering that this unit has been subject to dolomitization, the sediment of unit 2 was initially permeable and was likely deposited in a shoal setting. The overlying unit 3 of Aquitanian–Burdigalian age is characterized by a highly granular texture. High porosity and uniformly low δ¹³C and δ¹⁸O values indicate that Unit 3 was subjected to more intense meteoric diagenesis than the Chattian unit 1. This was likely a consequence of the Antarctic ice‐sheet expansion during the Oligocene/Miocene transition, which amplified sea level change. The unit 2 dolomite has high δ¹³C and δ¹⁸O values and a high ⁸⁷Sr/⁸⁶Sr ratio which resulted from the reflux of seawater into permeable the sediment body in middle‐late Miocene (Burdigalian Tortonian) following the deposition of unit 3. The porosity and permeability of the Kujung Formation were initially controlled by sedimentological processes, but largely modified by later diagenetic processes.     

Temporal dynamics of dissolved organic carbon (DOC) produced in a microcosm with red tide forming algae <Emphasis Type="Italic">Chattonella marina</Emphasis> and its associated bacteria

Acute and severe hypoxia associated with harmful algal bloom has become one of the major causes for the environmental deterioration of coastal areas. Although it is generally thought that a large part of the dissolved oxygen consumption at a bloom site is initiated by heterotrophic bacteria that attack organic matter derived from dead or dying algal cells, precise microbial processes leading to the hypoxia are yet to be examined. Here we show temporal dynamics of extracellular dissolved organic carbon (DOC) of the red tide forming raphidophyte Chattonella marina and bacterial populations associating with the algae under laboratory conditions. During the growth of non-axenic strains of C. marina, we monitored abundance of algae, associated bacteria, and DOC in the culture media. Bacterial cell abundance increased in response to the increase in DOC both at the beginning and the late log phase of the algal growth. Flow cytometric analysis revealed that transient increase in the percentage of respiratory-active bacterial cells also coincided with the timing of the increase in bacterial abundance and DOC. These results strongly suggest that DOC released from growing C. marina fuels respiration and growth of planktonic bacteria surrounding the algae. This has implications for the role of DOC released from C. marina bloom before the collapse in mediating interactions between neighboring algae and bacterial assemblage which may eventually lead to algal bloom-associated hypoxia.