Double seismic zones and stresses of intermediate depth earthquakes

Summary. Data from Japanese local seismograph networks suggest that the stresses in double seismic zones are in-plate compression for the upper zone and in-plate tension for the lower zone; the stresses do not necessarily appear to be down-dip. It may therefore be possible to identify other double seismic zones on the basis of data which indicate that events with differing orientations of in-plate stresses occur in a given segment of slab.
A global survey of published focal mechanisms for intermediate depth earthquakes suggests that the stress in the slab is controlled, at least in part, by the age of the slab and the rate of convergence. Old and slow slabs are under in-plate tensile stresses and the amount of in-plate compression in the slab increases with increasing convergence rate or decreasing slab age. Young and fast slabs are an exception to this trend; all such slabs are down-dip tensile. Since these slabs all subduct under continents, they may be bent by continental loading. Double seismic zones are not a feature common to all subduction zones and are only observed in slabs which are not dominated by tensile or compressive stresses.
Unbending of the lithosphere and upper mantle phase changes are unlikely to be the causes of the major features of double zones, although they may contribute to producing some of their characteristics. Sagging or thermal effects, possibly aided by asthenospheric relative motion, may produce the local deviatoric stresses that cause double zones.     

Sea surface temperature distribution and its variability across the Tsushima Strait

The sea surface temperature distribution across the Tsushima Strait was monitored over a one-year period on board the ferry Kampu which runs between Shimonoseki, Japan and Pusan, Korea. A cold water region is always observed just near the Korean Coast, and a sharp temperature front is always present in the western channel. A temperature maximum or a warm core is usually found just on the southeast side of the front. The position of the warm core exhibits large short period fluctuations, but no significant seasonal variation is found. Sudden temperature increases followed by sudden temperature decreases are frequently observed in the temporal variation curves at fixed positions during the warming season from April to August. Such events are related to temperature maxima found sporadically in the temperature distribution in the eastern channel during this season, and seem to be caused by warm water intrusion into the Tsushima Strait from the East China Sea.     

Calcium-alkalinity relationship in the North Pacific

The dissolution of calcium carbonate in deep ocean water causes variation in calcium concentration (Ca) and alkalinity (TA) in the ratio of one to two. The decomposition of organic matter generates nitric acid, phosphoric acid and sulfuric acid. A proton flux which is derived from this process also changes alkalinity. Using the variation in nitrate concentration (NO₃) as an index of the proton flux, the relationship betweenCa,TA andNO₃ is expressed asCa=0.5TA+0.63NO₃ The values of Ca obtained from direct measurements in the North Pacific are in good agreement with the values estimated from this equation.     

A numerical study on the formation and variation of a clockwise-circulation during winter in the Yellow Sea

In the Yellow Sea, the north-westerly wind dominates in winter and the existence of horizontal clockwise circulation has been suggested (Yanagi and Takahashi, 1993). The formation and variation mechanisms of this clockwise circulation is investigated using the wind forced numerical model which has a simplified basin configuration of the Yellow Sea. The model results show that two vortices (an anticlockwise vortex off Chinese coast and a clockwise vortex off Korean coast) are generated by the uniform north-westerly wind. Both vortices propagate along the shelf slope as the first mode shelf waves. An anti-clockwise vortex can not grow because it does not balance to the wind forcing. On the other hand, a clockwise vortex can grow and it reaches to the equilibrium condition at the northern part of the Yellow Sea, because this circulation can balance to the wind forcing. The time scale to become into the equilibrium condition is about 2 days. From this fact, it is ascertained that a clockwise circulation in the basin is generated periodically according to the variable wind forcing with 4 days period. The steady part of the current field exists with the fluctuating one which is induced by the periodical north-westerly wind.     

Degradation of outer membrane proteins of <Emphasis Type="Italic">Synechococcus</Emphasis> sp. <Emphasis Type="Italic">in vitro</Emphasis> and <Emphasis Type="Italic">in situ</Emphasis>

To examine the possibility that outer membrane proteins (OMP) of Synechococcus sp. remain in seawater, we investigated the stability of OMPs in vitro and in situ. Some fractions prepared from Synechococcus sp. CSIRO-94 were treated with trypsin and proteinase K. Four tightly bound OMPs were separated from Synechococcus. We designated the two major OMPs of 52 kDa and 48 kDa as Omp52Sy and Omp48Sy, respectively. Degradation of the OMP in natural seawater was monitored in microcosms to which intact Synechococcus cells and outer membrane (OM) were added. Omp52Sy and Omp48Sy were the most stable against trypsin and proteinase K among the OMPs when they were embedded in the OM. However, in the microcosm experiment using intact cells, Omp52Sy and Omp48Sy were detected in the particulate fraction only during the first 4 days, after which they could not longer be detected. Omp52Sy and Omp48Sy were the most stable proteins among the Synechococcus OMPs in vitro, but they might be degraded in situ. This indicates that stability of Synechococcus porin differs depending on complex formation with other membrane molecules, which might cause different preservation of microbial membrane proteins in the dissolved protein pool in the ocean. This study suggests that Gram negative bacterial OM with thin peptidoglycan forms a lipid bilayer that proptects OMP, but Synechococcus OM with thick peptidoglycan cannot form a lipid bilayer. The incomplete bilayer might not be able to protect from protease attack in the natural environment.     

Shipboard calibration of an infrared absorption gas analyser for total carbon dioxide determination in sea water

A new method for shipboard calibration of an infrared absorption carbon dioxide analyser was devised, utilizing the oxidative decomposition reaction of oxalic acid by permanganate in acid solution. With the present method, shipboard analysis of total carbon dioxide in 2 ml of sea water can be carried out with an error of less than 0.5 %. Some improvements in the analyser system are also presented.     

Hydration of rhyolitic glass during weathering as characterized by IR microspectroscopy

The mechanism and rate of hydration of rhyolitic glass during weathering were studied. Doubly polished thin sections of two rhyolites with different duration of weathering (Ohsawa lava: 26,000 yr, Awanomikoto lava: 52,000 yr) were prepared. Optical microscope observation showed that altered layers had developed along the glass surfaces. IR spectral line profile analysis was conducted on the glass sections from the surface to the interior for a length of 250 μm and the contents of molecular H₂O (H₂O_m), OH species (OH) and total water (H₂O_t) were determined. The diffusion profile of H₂O_m in Ohsawa lava extends beyond the layer observed by optical microscope. The content of H₂O_m in the hydrated region is much higher than that of OH species. Thus, the reaction from H₂O_m to OH appears to be little and H₂O_m is the dominant water species moving into the glass during weathering. Based on the concentration profiles, the diffusion coefficients of H₂O_m(D_H2Om) and H₂O_t(D_H2Ot) were determined to be 2.8 × 10⁻¹⁰ and 3.4 × 10⁻¹⁰ μm² s⁻¹ for Ohsawa lava, and 5.2 × 10⁻¹¹ and 4.1 × 10⁻¹¹ μm² s⁻¹ for Awanomikoto lava, respectively. The obtained D_H2Om during weathering are more than 2-3 orders of magnitude larger than the diffusion coefficient at ∼20 °C that is extrapolated from the diffusivity data for >400 °C. This might suggest that the mechanism of water transport is different at weathering conditions and >400 °C.