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571.
Quantification of Metals and Semimetals in Carbon‐Rich Rocks: A New Sequential Protocol Including Extraction from Humic Substances 下载免费PDF全文
Renato Henrique‐Pinto Sarah‐Jane Barnes Dany Savard Sadia Mehdi 《Geostandards and Geoanalytical Research》2017,41(1):41-62
We have developed a new sequential extraction technique that does not require complex procedures and is efficient in determining metal and semimetal contents of carbon‐rich rocks. Six geological reference materials (SBC‐1, SCHS‐1, SCo‐1, SDO‐1, SGR‐1b and SLg‐1) and an in‐house black shale (SH‐1) were selected to test the method, which consists of four main digestion steps involving: (a) dilute HCl acid; (b) NaOH; (c) aqua regia; and (d) hydrofluoric acid. Compared with traditional aqua regia + hydrofluoric acid attack, this new protocol recovers more of the moderately volatile elements during early extraction of humic substances. In addition when compared with reference values, those for most elements are in agreement within uncertainty. Furthermore, this new protocol reveals important information on the partitioning of elements; for instance, steps one and two indicate which elements are associated with carbonates and organic phases from fulvic and humic acid extractions, whereas step three provides results for which elements are associated with sulfide minerals and step four indicates which elements remained in the silicate and oxide phases. 相似文献
572.
Variability of the gas transfer velocity of CO<Subscript>2</Subscript> in a macrotidal estuary (the Scheldt) 总被引:1,自引:0,他引:1
Alberto?Vieira?BorgesEmail author Jean-Pierre?Vanderborght Laure-Sophie?Schiettecatte Frédéric?Gazeau Sarah?Ferrón-Smith Bruno?Delille Michel?Frankignoulle 《Estuaries and Coasts》2004,27(4):593-603
We report a large set of 295 interfacial carbon dioxide (CO2) flux measurements obtained in the Scheldt estuary in November 2002 and April 2003, using the floating chamber method. From
concomitant measurements of the air-water CO2 gradient, we computed the gas transfer velocity of CO2. The gas transfer velocity is well correlated to wind speed and a simple linear regression function gives the most consistent
fit to the data. Based on water current measurements, we estimated the contribution of water current induced turbulence to
the gas transfer velocity, using the conceptual relationship of O'Connor and Dobbins (1958). This allowed us to construct
an empirical relationship to compute the gas transfer velocity of CO2 that accounts for the contribution of wind and water current. Based on this relationship, the spatial and temporal variability
of the gas transfer velocity in the Scheldt estuary was investigated. Water currents contribute significantly to the gas transfer
velocity, but the spatial and temporal variability (from daily to seasonal scales) is mainly related to wind speed variability. 相似文献
573.
Identifying factors influencing flood mitigation at the local level in Texas and Florida: the role of organizational capacity 总被引:1,自引:0,他引:1
In the United States, mitigating the adverse impacts of flooding has increasingly become the responsibility of local decision
makers. Despite the importance of understanding why flood mitigation techniques are implemented at the local level, few empirical
studies have been conducted over the last decade. Our study addresses this lack of research by examining the factors influencing
local communities to adopt both structural and non-structural flood mitigation strategies. We use statistical models to predict
multiple flood mitigation techniques implemented by cities and counties based on a survey of floodplain administrators and
planning officials across Texas and Florida. Particular attention is paid to the role of organizational capacity to address
floods in addition to various local geophysical and socioeconomic characteristics. Results indicate that organizational capacity
is a significant factor contributing to the implementation of both structural and non-structural flood mitigation techniques,
even when controlling for contextual characteristics. 相似文献
574.
Jean Klerkx Sarah Deutsch Paul De Paepe 《Contributions to Mineralogy and Petrology》1974,45(2):107-118
The Cape Verde islands are characterized by the presence of very strongly alkalic lavas. Cenozoic volcanics—covering the broadest compositional range present in the archipelago—and ranging from alkali-basalts to phonolites, associated with plutonic essexites and nepheline syenites, were analyzed for Sr isotopic compositions and concentrations in K, Rb and Sr. The close values of the Sr87/Sr86 ratios (ranging from 0.7029 to 0.7033) indicate a comagmatic origin for the different rock types; no correlation appears between the Sr isotopic composition and the K-content of the lavas, thus indicating that the lavas with high K2O/K2O + Na2O ratio are generated from a primary magma by differentiation at shallow depths. The values of the Sr isotopic composition are distinctly lower than most values obtained for lavas of other oceanic islands. The origin of the magma type is discussed on the basis of these isotopic compositions and the K/Rb and Rb/Sr ratios: it is suggested that the primary magma has a nephelinitic composition and was formed by partial melting of a small fraction of undepleted mantle peridotite, containing phlogopite; the deeper part of the mantle where this nephelinitic magma generates would have a strontium isotopic ratio of about 0.703 and a Rb/Sr ratio lower than that of the upper part. 相似文献
575.
Groundwater in alluvial aquifers of the Wakatipu and Wanaka basins, Central Otago, New Zealand, has a composition expressed
in equivalent units of Ca2+≫Mg2+≅Na+>K+ for cations, and HCO3
–≫SO4
2->NO3
–≅Cl– for anions. Ca2+ and HCO3
– occur on a 1 : 1 equivalent basis and account for >80% of the ions in solution. However, some groundwater has increased proportions
of Na+ and SO4
2-, reflecting a different source for this water.
The rock material of the alluvial aquifers of both basins is derived from the erosion and weathering of metamorphic Otago
Schist (grey and green schists). Calcite is an accessory mineral in both the grey and green schists at <5% of the rock. Geological
mapping of both basins indicates that dissolution of calcite from the schist is the only likely mechanism for producing groundwater
with such a constant composition dominated by Ca2+ and HCO3
– on a 1 : 1 equivalent basis. Groundwater with higher proportions of Na+ and SO4
2- occurs near areas where the schist crops out at the surface, and this groundwater represents deeper and possibly older water
derived from basement fluids. Anomalously high K+ in the Wakatipu basin and high NO3
– concentrations in the Wanaka basin cannot be accounted for by interaction with basement lithologies, and these concentrations
probably represent the influence of anthropogenic sources on groundwater composition.
Received, June 1996 Revised, March 1997, July 1997 Accepted, July 1997 相似文献
576.
Holger Class Anozie Ebigbo Rainer Helmig Helge K. Dahle Jan M. Nordbotten Michael A. Celia Pascal Audigane Melanie Darcis Jonathan Ennis-King Yaqing Fan Bernd Flemisch Sarah E. Gasda Min Jin Stefanie Krug Diane Labregere Ali Naderi Beni Rajesh J. Pawar Adil Sbai Sunil G. Thomas Laurent Trenty Lingli Wei 《Computational Geosciences》2009,13(4):409-434
577.
Sarah Bureau du Colombier Patrick Lambert Agnès Bardonnet 《Estuarine, Coastal and Shelf Science》2008
Several studies have shown that eel diadromy is facultative and that migratory divergences may appear during glass eel estuarine migration. The origin of the differences in migratory behaviour among glass eels remains unclear but initial evidence supports the role of individual energetic and thyroidal status. Even if starvation is usually associated with glass eel migration, feeding does seem to occur in some glass eels. The aim of the present study was to investigate feeding behaviour and glass eel growth in relation to the propensity to migrate. Feeding rate and weight gain were higher in fish having a high propensity to migrate (M+ fish) than in fish having a low propensity to migrate (M− fish) in fed glass eels, whereas no clear difference in the variation in body weight was observed among unfed fish (controls). M− fish initially had lower percent dry weight than M+ fish, which suggests a link between appetite, propensity to migrate, and energy content. We discuss the role played by endocrine signals on these processes. In fish, thyroid hormones contribute to the control of growth and development. In addition, they play a role in flatfish and leptocephalus metamorphosis and appear to be involved in smolt and glass eel migratory behaviour. As such, they represent a good candidate which would promote the propensity to migrate as well as digestive system development. Their role in the hormonal control of food intake however remains vague. 相似文献
578.
Frank J Millero Jia-Zhong Zhang Sarah Fiol Sara Sotolongo Rabindra N Roy Kitack Lee Sanjay Mane 《Marine Chemistry》1993,44(2-4)
The pH of seawater can be measured in the field using potentiometric and spectrophotometric methods. The use of pH standards or buffers is an important aspect of the calibration of both methods in a laboratory on a common concentration scale. The buffers can also be used to monitor the performance of pH meter and spectrophotometer during a cruise. A procedure is described for the determination of the pH of seawater, where the proton concentration is expressed as moles kg-H2O−1 using seawater buffers. The buffers are prepared in synthetic seawater in the laboratory by the methods outlined by Bates and coworkers. We have prepared four buffers (Bis, Tris, Morpholine and 2-Aminopyridine) that cover a pH range from 6.8 to 8.8. The emf values of the buffers were measured with a H2, Pt/AgCl, Ag electrode system after their preparation and bottling for use at sea. The measured emf values were found to be in good agreement (±0.05 mV) with the original measurements of Bates and coworkers from 0 to 45°C. The measured pH of these buffers are in good agreement (±0.001 pH units) with the values calculated from the equations of Dickson on the total pH scale based on Bates et al. Studies are underway to access the long term stability of these buffers. We have also used these buffers to calibrate systems used to make potentiometric and spectrophotometric measurements of pH on seawater relative to the H2, Pt/Ag, AgCl electrode from 5 to 45°C. 相似文献
579.
580.
Phillip B. Fenberg Jennifer E. Caselle Joachim Claudet Michaela Clemence Steven D. Gaines Jose Antonio García-Charton Emanuel J. Gonçalves Kirsten Grorud-Colvert Paolo Guidetti Stuart R. Jenkins Peter J.S. Jones Sarah E. Lester Rob McAllen Even Moland Serge Planes Thomas K. Sørensen 《Marine Policy》2012
The ecologically and socio-economically important marine ecosystems of Europe are facing severe threats from a variety of human impacts. To mitigate and potentially reverse some of these impacts, the European Union (EU) has mandated the implementation of the Marine Strategy Framework Directive (MSFD) in order to achieve Good Environmental Status (GES) in EU waters by 2020. The primary initiative for achieving GES is the implementation of coherent networks of marine protected areas (MPAs). Marine reserves are an important type of MPA in which no extraction is allowed, but their usefulness depends upon a number of ecological, management, and political factors. This paper provides a synthesis of the ecological effects of existing European marine reserves and the factors (social and ecological) underlying their effectiveness. Results show that existing European marine reserves foster significant positive increases in key biological variables (density, biomass, body size, and species richness) compared with areas receiving less protection, a pattern mirrored by marine reserves around the globe. For marine reserves to achieve their ecological and social goals, however, they must be designed, managed, and enforced properly. In addition, identifying whether protected areas are ecologically connected as a network, as well as where new MPAs should be established according to the MSFD, requires information on the connectivity of populations across large areas. The adoption of the MSFD demonstrates willingness to achieve the long-term protection of Europe's marine ecosystems, but whether the political will (local, regional, and continent wide) is strong enough to see its mandates through remains to be seen. Although the MSFD does not explicitly require marine reserves, an important step towards the protection of Europe's marine ecosystems is the establishment of marine reserves within wider-use MPAs as connected networks across large spatial scales. 相似文献