Field applicability of self-recovering sustainable liner as landfill final cover

Preventing the penetration of rainwater into a landfill site is the main purpose of the final cover in landfill sites. Conventional designs of landfill covers use geotextiles, such as geomembrane and geosynthetic clay liners, and clay liners to lower the permeability of the final cover of landfill sites. However, differential settlement and climatic effects in landfill sites instigate crack development or structural damage inside the final cover. This study therefore investigates the field applicability of a self-recovering sustainable liner (SRSL) as an alternative to the landfill final cover. The SRSL utilizes the precipitation reaction of two chemical materials to form precipitates that fill the pores and thereby lower the overall permeability of the liner. To examine the field applicability of the SRSL system, uniaxial compression tests and laboratory hydraulic conductivity tests were performed under various climatic effects such as wet/dry and freeze/thaw processes. Furthermore, field-scale hydraulic conductivity tests were performed with intentionally induced cracks to demonstrate the self-recovery performance for practical applications. Extensive laboratory and field test results confirmed the capability of the SRSL final cover system to fulfill the strength and hydraulic conductivity requirements, even in harsh field conditions.     

Sulfate Reduction and Sulfur Cycles at Two Seagrass Beds Inhabited by Cold Affinity <Emphasis Type="Italic">Zostera marina</Emphasis> and Warm Affinity <Emphasis Type="Italic">Halophila nipponica</Emphasis> in Temperate Coastal Waters

To evaluate the impact of invading seagrass on biogeochemical processes associated with sulfur cycles, we investigated the geochemical properties and sulfate reduction rates (SRRs) in sediments inhabited by invasive warm affinity Halophila nipponica and indigenous cold affinity Zostera marina. A more positive relationship between SRR and below-ground biomass (BGB) was observed at the H. nipponica bed (SRR = 0.6809 × BGB ? 4.3162, r ² = 0.9878, p = 0.0006) than at the Z. marina bed (SRR = 0.3470 × BGB ? 4.0341, r ² = 0.7082, p = 0.0357). These results suggested that SR was more stimulated by the dissolved organic carbon (DOC) exuded from the roots of H. nipponica than by the DOC released from the roots of Z. marina. Despite the enhanced SR in spring-summer, the relatively lower proportion (average, 20%) of acid-volatile sulfur (AVS) in total reduced sulfur and the strong correlation between total oxalate-extractable Fe (Fe_(oxal)) and chromium-reducible sulfur (CRS = 0.2321 × total Fe_(oxal) + 1.8180, r ² = 0.3344, p = 0.0076) in the sediments suggested the rapid re-oxidation of sulfide and precipitation of sulfide with Fe. The turnover rate of the AVS at the H. nipponica bed (0.13 day^?1) was 2.5 times lower than that at the Z. marina bed (0.33 day^?1). Together with lower AVS turnover, the stronger correlation of SRR to BGB in the H. nipponica bed suggests that the extension of H. nipponica resulting from the warming of seawater might provoke more sulfide accumulation in coastal sediments.     

The role of eddies in solute transport and recovery in rock fractures: Implication for groundwater remediation

A better understanding of solute transport and retention mechanism in rock fractures has been challenging due to difficulty in their direct observations in microscale rough‐walled fractures. Six representative troughs in a rough‐walled fracture were selected for microscale observations of eddy formation with increasing flow velocity and its effect on spatiotemporal changes of solute concentration. This experimental study was enabled by a microscale visualization technique of micro particle image velocimetry. With increasing flow velocity (Re ≤ 2.86), no eddies were generated, and solutes along the main streamlines transported rapidly, whereas those near the wall moved slowly. A larger amount of solutes remained trapped at all troughs at Re = 2.86 than Re < 1. For Re = 8.57, weak eddies started to be developed at the troughs on the lee side, which little contributed to overall solute flushing in the fracture. Accordingly, a large of amount of water was needed for solute flushing. The flow condition of 1 < Re < 10, before a full development of eddies, was least favourable in terms of time and amount of remediation fluid required to reach a target concentration. After large eddies were fully developed at troughs on the lee side for Re = 17.13, solutes were substantially reduced by eddies with less amount of water. Fully developed eddies were found to enhance solute transport and recovery, as opposed to a general consensus that eddies trap and delay solutes. Direct inflow into troughs on the stoss side also made a great contribution to solute flushing out of the troughs. This study indicates that fully developed eddies or strong inflows at troughs are highly possible to form for Re > 10 and this flow range could be favourable for efficient remediation.     

大别山超高压变质岩的退变质赤微构造：折返过程的启示

大别山超高压变质岩中发现了一系列退变质显微构造,其主要类型有：①由于出溶而产生的定一包裹物;②由于多型转变而产生的假像替代;③固→固反应产生的冠状体;④涉及流体的退变质反应产生的冠状体或后成合晶。借助显微构造关系,可以建立超高压变质岩的退变质演化阶段,从而构筑其ＰＴ演化趋势、识别出碰撞造山和超高压变质峰期之后的两阶段隆升历史;早期为“挤出”作用诱发的近等温减压退变质;晚期则是地壳伸展体制下的退变质     

Effects of natural and calcined poultry waste on Cd, Pb and As mobility in contaminated soil

The reuse of waste materials as soil additives could be a welcome development in soil remediation. The mobility of Cd, Pb and As in a contaminated soil was investigated using natural and calcined poultry wastes (eggshell and chicken bone), CaCO₃ and CaO at different application rates (0, 1, 3 and 5 %). The chemical composition accompanied with mineralogical composition indicated that CaCO₃ and CaO were the major components in natural and calcined eggshells, respectively, while hydroxyapatite (HAP) dominated the natural and calcined chicken bones. The results showed that soil pH tended to increase in response to increasing application rates of all soil additives. The effectiveness of the additives in reducing Cd, Pb and As mobility was assessed by means of chemical extractions with 0.1 N HCl for Cd and Pb or 1 N HCl for As, according to Korean Standard Test (KST) method. Both calcined eggshell and chicken bone were equally effective with CaO or CaCO₃ in reducing the concentration of 0.1 N HCl-extractable Cd from 6.17 mg kg^?1 to below warning level of 1.5 mg kg^?1, especially at the highest application rate. The application of calcined eggshell, CaO and CaCO₃ also decreased the concentration of 0.1 N HCl-extractable Pb from 1,012 mg kg^?1 to below warning level of 100 mg kg^?1. The Pb concentration decreased significantly with an increasing application rate of chicken bone, but remained above warning level even at the highest application rate. On the contrary, natural and calcined chicken bones led to a significant increase in the mobility of As when compared with the control soil. These findings illustrate that calcined eggshell in particular is equally effective as pure chemical additives in stabilizing Cd and Pb in a contaminated agricultural soil. The presence of As in metal-contaminated soils should be taken into consideration when applying phosphate-containing materials as soil additives, because phosphate can compete with arsenate on adsorption sites and result in As mobilization.     

煤层气生成与煤层气富集Ⅱ.有效生气阶段生气量的估算

煤层的生气条件主要通过有效阶段生气量来影响煤层气的富集。有效阶段生气量取决于有效生气阶段的起止煤级和煤中原始有机质的丰度及其组成。本文给出了估算有效阶段生气量的基本公式,重点讨论了煤中原始有机质的丰度和组成的恢复方法,并以沁水盆地南部主要矿区3号和15号煤层为例,对有效阶段生气量进行了估算。     

Cordierite breakdown under high-pressure hydrous conditions

Green and Vernon (1974) have experimentally determined a divariant field of cordierite-orthoamphibole-kyanite-quartz with a slope of 12±4 bars per °C occurring between 8.0 and 10.4 kbar at 750° C and between 9.5 and 11.3 kbar at 850° C. However, the writers' thermodynamic calculation of the divariant band indicates a more limited range of 0.65 and 0.7 kbar at 750° C and 850° C respectively, with an estimated error of ±0.2 kbar.     

Enhanced bioremoval of refractory compounds from dyeing wastewater using optimized sequential anaerobic/aerobic process

The upflow anaerobic sludge blanket process followed by the biological aerated filter process was employed to improve the removal of color and recalcitrant compounds from real dyeing wastewater. The highest removal efficiency for color was observed in the anaerobic process, at 8-h hydraulic retention time, seeded with the sludge granule. In the subsequent aerobic process packed with the microbe-immobilized polyethylene glycol media, the removal efficiency for chemical oxygen demand increased significantly to 75 %, regardless of the empty bed contact time. The average influent non-biodegradable soluble chemical oxygen demand was 517 mg/L, and the average concentration in effluent from the anaerobic reactor was 363 mg/L, suggesting the removal of some recalcitrant matters together with the degradable ones. The average non-biodegradable soluble chemical oxygen demand in effluent from the aerobic reactor was 87, 93, and 118 mg/L, with the removal efficiency of 76, 74, and 67 %, at 24-, 12-, and 8-h empty bed contact time, respectively. The combined anaerobic sludge blanket and aerobic cell-entrapped process was effective to remove the refractory compounds from real dyeing wastewater as well as in reducing organic loading to meet the effluent discharge limits. This integrated process is considered an effective and economical treatment technology for dyeing wastewater.     

冀北坝上地区深部地质构造特征及其对火山活动和铀成矿的控制作用

冀北坝上地区位于华北地台北缘。其深部地质构造有两个显著特征：一是全区性的莫霍面下拗，地壳增厚；二是软流圈部分伸入到下岩石图上部，造成局部地区地幔上隆，地壳减薄。火山喷发形成的沽源火山盆地和大滩火山盆地与两个地幔上隆，地壳减薄区，上下相互对应。铀矿床（点）沿地幔隆起周边构造活动带规律性分布。上述两事实有力地证明了深部地质构造对中新生代火山活动和铀成矿的控制作用。沿地幔隆起周边构造活动带是今后寻找铀及多金属矿产的有利地段。