Using chloride and other ions to trace sewage and road salt in the Illinois Waterway

Chloride concentrations in waterways of northern USA are increasing at alarming rates and road salt is commonly assumed to be the cause. However, there are additional sources of Cl⁻ in metropolitan areas, such as treated wastewater (TWW) and water conditioning salts, which may be contributing to Cl⁻ loads entering surface waters. In this study, the potential sources of Cl⁻ and Cl⁻ loads in the Illinois River Basin from the Chicago area to the Illinois River’s confluence with the Mississippi River were investigated using halide data in stream samples and published Cl⁻ and river discharge data. The investigation showed that road salt runoff and TWW from the Chicago region dominate Cl⁻ loads in the Illinois Waterway, defined as the navigable sections of the Illinois River and two major tributaries in the Chicago region. Treated wastewater discharges at a relatively constant rate throughout the year and is the primary source of Cl⁻ and other elements such as F⁻ and B. Chloride loads are highest in the winter and early spring as a result of road salt runoff which can increase Cl⁻ concentrations by up to several hundred mg/L. Chloride concentrations decrease downstream in the Illinois Waterway due to dilution, but are always elevated relative to tributaries downriver from Chicago. The TWW component is especially noticeable downstream under low discharge conditions during summer and early autumn when surface drainage is at a minimum and agricultural drain tiles are not flowing.     

Textural evolution and metamorphism of pillow basalts from the Franciscan Complex,western Marin County,California

Petrogenesis of Franciscan pillow basalts from the Franciscan Complex of western Marin County California entails both dynamic crystallization of tholeiitic magma and subsequent low-temperature metamorphism. Brittle deformation during tectonic emplacement of pillow basalts into a chert greywacke terrain is manifested by the shearing of interpillow matrix and polishing of pillow rims, but the igneous textures within pillows are well preserved.The cooling history of pillow basalts can be understood through analysis of morphologic variations of primary olivine and plagioclase from rim to core of the pillow. Crystal sizes and plagioclase dendrite spacings are consisted with a cooling rate which generally decreases inward. Some pillows show a marked asymmetry in plagioclase and olivine morphology suggesting lower cooling rates caused by asymmetric cooling of the pillows. Olivine morphologies, primarily hopper and chain forms, are consistent with cooling rates of 2–10 °C/h for pillow cores and 50–75 °C/h for pillow rims.Low temperature hydrothermal alteration has produced secondary minerals indicative of zeolite facies conditions. Pillow matrix is either chloritic or zeolitic (in part laumontized). Pillow rims display incomplete replacement of calcic palagonite by pumpellyite (Fe₂O₃=9–21 wt%), prehnite (Fe₂O₃=5–7 wt%), sphene and quartz. Metamorphism of pillow interiors, manifested by: (1) veins of quartz, pumpellyite, calcite, or harmotome (BaO=15 wt%); (2) amygdules containing analcime, chlorite or quartz; and (3) replacement of olivine by pumpellyite or smectite/illite, of plagioclase by albite (An3)+sericite, and of glassy groundmass by fine-grained chlorite. Primary augite (Wo3₃₉En₁₃Fs₄₈) was not altered. The described paragenesis may be attributed to oceanfloor and/or Franciscan-type metamorphism.     

Accelerated climate change and its potential impact on Yak herding livelihoods in the eastern Tibetan plateau

The Tibetan Plateau has experienced rapid warming like most other alpine regions. Regional assessments show rates of warming comparable with the arctic region and decreasing Asian summer monsoons. We used meteorological station daily precipitation and daily maximum and minimum temperature data from 80 stations in the eastern Tibetan Plateau of southwest China to calculate local variation in the rates and seasonality of change over the last half century (1960–2008). Daily low temperatures during the growing season have increased greatly over the last 24 years (1984–2008). In sites of markedly increased warming (e.g., Deqin, Yunnan and Mangya, Qinghai), daily and growing season daily high temperatures have increased at a rate above 5 °C/100 years. In Deqin, precipitation prior to the 1980s fell as snow whereas in recent decades it has shifted to rain during March and April. These shifts to early spring rains are likely to affect plant communities. Animals like yaks adapted to cold climates are also expected to show impacts with these rising temperatures. This region deserves further investigation to determine how these shifts in climate are affecting local biodiversity and livelihoods.     

Hydrogen and oxygen isotope ratios in nodular and bedded cherts

Hydrogen and oxygen isotopic compositions of cherts (δD for hydroxyl hydrogen in the chert, δ¹⁸O for the total oxygen) have been determined for a suite of samples from the central and western United States. When plotted on a δD-δ¹⁸O diagram, Phanerozoic cherts define domains parallel to the meteoric water line which are different for different periods of geologic time. The elongation parallel to the meteoric water line suggests that meteoric waters were involved in the formation of many cherts.The existence of different chert δ-values for different geologic times indicates that once the granular microcrystalline quartz of cherts crystallizes its isotopic composition is preserved with time. An explanation for the change with time of the isotopic composition of cherts involving large changes with time in the isotopic composition of ocean water is unlikely since δ¹⁸O of the ocean would have had to decrease by about 3‰between Carboniferous and Triassic time and then increase about 5%.` from Triassic to Cretaceous time. Such isotopic changes cannot be accounted for by extensive glaciation, sedimentation of hydrous minerals, or input of water from the mantle into the oceans.The variation with time of the chert δ-values can be satisfactorily explained in terms of past climatic temperature fluctuations if the chert-water isotope fractionation with temperature is approximated by 1000 lnα = 3.09 × 10⁶T^?2 – 3.29. Crystallization temperatures so inferred suggest that the average climatic temperatures for the central and western U.S. decreased from about 34 to 20°C through the Paleozoic, increased to 35–40°C in the Triassic, and then decreased through the Mesozoic to Tertiary values of about 17°C. A few data for the Precambrian suggest the possibility that Earth surface temperatures may have reached about 52°C at 1.3 b.y. and about 70°C at 3 b.y.     

Multidecadal trend analysis of hydrological drought along River Niger using the Streamflow Drought Index

Droughts affect human well-being and the economy of countries across the world. Understanding the long-term evolution of droughts within a particular region will help in drought mitigation and adaptation plans, thereby reducing drought impact on the environment. This study examined the multidecadal trends in hydrological droughts at two stations along River Niger using 3-month, 6-month, and annual time scales. Hydrological drought events were identified using the streamflow drought index (SDI) between 1915 and 1990 based on the Theil-Sen slope and Mann-Kendall approaches. Across the timescales, extreme and severe droughts occurred in 1982/84 and 1983/84 with -2 ≤ S_d < -1.5. On an annual scale, the results from the annual SDI further showed that the 7th and 8th decades (1971−1990) recorded more drought events of varying degrees ranging from mild to extreme drought in both stations than in other decades. The last two decades (7th and 8th) further revealed the most extended hydrological drought duration from 1974/75 to 1988/89 for Baro and from 1979/80 to 1988/89 for Lokoja. The highest severity recorded at Baro was -15.56 and -14.26 at Lokoja. The prolonged duration of drought events across the stations and their associated yearly intensities suggests that more proactive measures are needed to ameliorate the hydrological drought impact in the study area.