Stability and solubility of arsenopyrite, FeAsS, in crustal fluids

The stability and solubility of natural arsenopyrite (FeAsS) in pure water and moderately acid to slightly basic aqueous solutions buffered or not with H₂ and/or H₂S were studied at temperatures from 300 to 450°C and pressures from 100 to 1000 bar. The solubilities of FeAsS in pure water and dilute HCl/NaOH solutions without buffering are consistent with the formation of the As(OH)₃⁰(aq) species and precipitation of magnetite. At more acid pH (pH ≤2), arsenopyrite dissolves either stoichiometrically or with formation of the As-FeAsS assemblage. In H₂S-rich and H₂-rich aqueous solutions, arsenopyrite dissolution results in the formation of pyrrhotite (±pyrite) and iron arsenide(s), respectively, which form stable assemblages with arsenopyrite.Arsenic concentrations measured in equilibrium with FeAsS in slightly acid to neutral aqueous solutions with H₂ and H₂S fugacities buffered by the pyrite-pyrrhotite-magnetite assemblage are 0.0006 ± 0.0002, 0.0055 ± 0.0010, 0.07 ± 0.01, and 0.32 ± 0.03 mol/kg H₂O at 300°C/400 bar, 350°C/500 bar, 400°C/500 bar, and 450°C/500 bar, respectively. These values were combined with the available thermodynamic data on As(OH)₃⁰(aq) (Pokrovski et al., 1996) to derive the Gibbs free energy of FeAsS at each corresponding temperature and pressure. Extrapolation of these values to 25°C and 1 bar, using the available heat capacity and entropy data for FeAsS (Pashinkin et al., 1989), yields a value of −141.6 ± 6.0 kJ/mol for the standard Gibbs free energy of formation of arsenopyrite. This value implies a higher stability of FeAsS in hydrothermal environments than was widely assumed.Calculations carried out using the new thermodynamic properties of FeAsS demonstrate that this mineral controls As transport and deposition by high-temperature (>∼300°C) crustal fluids during the formation of magmatic-hydrothermal Sn-W-Cu-(Au) deposits. The equilibrium between As-bearing pyrite and the fluid is likely to account for the As concentrations measured in modern high- and moderate-temperature (150 ≤ T ≤ 350°C) hydrothermal systems. Calculations indicate that the local dissolution of arsenopyrite creates more reducing conditions than in the bulk fluid, which is likely to be an effective mechanism for precipitating gold from hydrothermal solutions. This could be a possible explanation for the gold-arsenopyrite association commonly observed in many hydrothermal gold deposits.     

Research and application of roadway backfill coal mining technology in western coal mining area

In China’s western coal mining area, the traditional room mining technology is facing coal pillar instability, mine earthquake, large-area roof subsidence in the goaf, surface subsidence, water and soil loss, vegetation deterioration, and other environmental problems. To solve the aforementioned problems and to improve coal recovery, the roadway backfill coal mining (RBCM) method was proposed as a solution and its technical principle and key equipment were presented in this paper. In addition, the microstructure and mechanical behavior (strain-stress relation in confined compressive test) of aeolian sand and loess backfill materials were studied for a rational backfill design for underground mines. Further, coal pillar stress, plastic zone change, and surface deformation of the RBCM schemes were studied using the FLAC^3D numerical simulation software, and a reasonable mining scheme of “mining 7 m and leaving 3 m” was determined. The engineering application in Changxing Coal Mine shows that the RBCM method with loess and aeolian sand as backfill materials allows a stable recovery of coal pillars with a recovery ratio of more than 70 %. The maximum accumulated surface subsidence and the maximum horizontal deformation were measured to be 15 mm and 0.8 mm/m respectively, indicating that the targeted backfilling effect can help protect the environment and also control surface subsidence.     

Connectivity and stock composition of loggerhead turtles foraging on the North African continental shelf (Central Mediterranean): implications for conservation and management

The loggerhead turtle, Caretta caretta, is a highly migratory species with a complex life cycle that involves a series of ontogenetic habitat shifts and migrations. Understanding the links amongst nesting populations and foraging habitats is essential for the effective management of the species. Here we used mixed stock analysis to examine the natal origin of loggerhead turtles foraging on the North African continental shelf off Tunisia, one of the most important Mediterranean neritic habitats. An 815‐bp fragment of the mitochondrial DNA control region was sequenced from 107 individuals sampled from 2007 to 2009. No temporal variation in haplotype frequencies was detected. Juveniles (n = 87) and adults (n = 23) exhibited weak but significant genetic differentiation that resulted in different stock compositions. Libya was the main source population but the proportion of turtles from this rookery was higher in adults (median = 80%) than in juveniles (median = 35%). Western Greece was the second most important contributing population. Juvenile stock composition derived from mixed stock analysis and the estimates produced by numerical simulation of hatchling dispersion in the Mediterranean Sea were significantly correlated, supporting the recent theory that loggerheads imprint on possible future neritic habitats during the initial phase of their life. This association was not significant for adults, suggesting that other factors contribute to shaping their distribution. Overall, our results show that human activities on the South Tunisian continental shelf pose an immediate threat to the survival of the Libyan rookery.     

A New Approach for Regional Groundwater Level Simulation: Clustering,Simulation, and Optimization

Natural Resources Research - In this study, a new 3-stage approach that consists of clustering, simulation, and optimization stages is proposed for the simulation of groundwater level (GWL) in an...     

Geometrical properties of perfect breaking waves on composite breakwaters

The experimental results have so far shown that when a wave breaks on a vertical wall with an almost vertical front face at the instant of impact that is called perfect breaking or perfect impact, the greatest impact forces are produced on the wall. Therefore, the configuration of breaking waves is important in the design considerations of coastal structures. The present study is concerned with determining the geometrical properties of oscillatory waves that break perfectly on the vertical wall of composite-type breakwaters. The laboratory tests for perfect breaking waves on composite breakwaters are conducted with base slopes of 1/2, 1/4 and 1/6, and with berm widths of 0.00, 0.10, 0.20, 0.30 and 0.40 m. The shape and the dimensions of waves at the instant of perfect breaking on the wall are determined using a video camera. The experimental results for the geometrical properties of the breakers are presented non-dimensionally. Within the range of present experimental conditions, it is found that the dimensionless breaker crest height, h_b/d_w, and dimensionless breaker height, H_b/d_w, decrease; and, dimensionless breaker depth, d_w/H₀, increases with increasing relative berm width, B/D. The breaker height index, H_b/H₀, is almost unaffected by B/D. The deep-water wave steepness and the base slope of the breakwater do not seem to influence the geometrical properties of the breakers at wall systematically.     

Seismicity assessment of Fukushima region,fault kinematics and calculation of PGA value for Idosawa fault in Hamadori area,Japan

Natural Hazards - In depth assessment of seismicity distribution for a particular region like Fukushima, prefecture is key towards reliable seismic hazard analysis for the area. Assessment of...     

Fluid inclusion and carbon, oxygen, and strontium isotope study of the Polaris Mississippi Valley-type Zn–Pb deposit, Canadian Arctic Archipelago: implications for ore genesis

The Polaris deposit is one of the largest Mississippi Valley-type deposits in the world, with 22 million tonnes of ore at 14% Zn and 4% Pb contained in a single, compact orebody surrounded by dolomitized host rocks. Using detailed sampling of carbonates in the orebody and the dolostone halo, this paper aims to characterize the temporal and spatial evolution of the mineralizing system, and to understand the mechanisms that controlled the accumulation of this large, compact Zn–Pb deposit. Five types of dolomite have been distinguished, including three replacement (RD) and two pore-filling dolomites (PD). The paragenetic order is RD1, RD2, RD3, PD1, and PD2. Pore-filling calcite (PC) postdates all other minerals. In most cases, sulfides and dolomite did not co-precipitate, but sphalerite and galena largely overlap with RD3 and PD1. Various dolomites are dissolved or replaced by sulfide-precipitating fluids; sulfides in turn can be overgrown by dolomites. Colloform texture in sphalerite is widespread. Fluid inclusions were studied in RD3, PD1, PD2, sphalerite, and PC. The overall ranges of homogenization temperatures (T _h) and last ice-melting temperatures (T _m-ice) for fluid inclusions in dolomites and sphalerite are from 67 to 141 °C and from −46.7 to −27.0 °C, respectively, consistent with warm basinal brines with high salinities and Ca/Na ratios. Gas chromatographic analysis of these fluid inclusions indicates low concentrations of hydrocarbons (<0.06 mol%). C, O, and Sr isotopes were analyzed for all dolomites and PC, as well as for the fine-grained host limestone and early diagenetic calcite (SC–RC). The isotopic values of RD2, RD3, PD1, and PD2 cluster tightly and form largely overlapping domains. With respect to the host limestone, they are depleted in ¹⁸O, similar in δ¹³C, and slightly enriched in ⁸⁷Sr. There are no regular spatial variations for fluid inclusion and isotope data, indicating an overall geochemical homogeneity in the hydrothermal system. However, certain samples close to the fracture zones in the orebody with slightly elevated T _h and ⁸⁷Sr/⁸⁶Sr values and depleted δ¹⁸O values suggest that the fracture zone was the conduit for the hot brines. Based on the geological and geochemical characteristics of the deposit, we propose that sulfide precipitation at Polaris was caused by mixing of a reduced, metal-rich, sulfur-poor fluid with a reduced, metal-poor, sulfur-rich fluid at the site of mineralization. The metal-carrying fluid ascended along fractures from below the deposit and was hotter than the host rocks, whereas the reduced sulfur-carrying fluid was delivered to the site of mineralization laterally and was in thermal equilibrium with the host rocks. This model can readily explain the dissolution of dolomite during sulfide precipitation and the abundance of colloform sphalerite, as well as the low concentrations of hydrocarbons in fluid inclusions. Accepted: 20 December 1999