The Latnenskoe refractory clay deposit (Central Russia)

This paper reports the results of our recent studies and generalizes previously known data on the geology, mineralogy, geochemistry, and genesis of the Russia’s largest Latnenskoe refractory clay deposit. It is shown that conditions of its localization were defined by regional and local factors. The regional factors controlled the distribution of the clay raw material in the region, while the local factors were responsible for the genesis and composition of refractory clays of the Latnenskoe deposit. Our studies showed that the formation of refractory clays is not only related to terrigenous but also to authigenic processes of sedimentation. The terrigenous component of clays was formed by the erosion of kaolin weathering crusts of the Voronezh anteclise crystalline basement and Paleozoic sedimentary hydromica–kaolinite rocks. Authigenic processes were significantly contributed by organic matter, which determined the environmental pH and Eh parameters. It is established that the mineral matter of clays of the deposit is represented by three morphological modifications (crystalline, amorphous, and biomorphic), which were formed subsequently and (or) simultaneously and could be transformed into each other. Application of a complex of modern precision methods allowed us to reveal a previously unknown biomorphic modification of kaolinite, the major rock-forming mineral, as well as mixed-layer kaolinite-smectite in the clays. It is shown that the distribution of major and trace elements and the sulfur isotope composition in different technological types of clay depend mainly on the facies conditions of their formation. Technological properties of clay raw material are considered.     

Chemical analysis of natural objects by ion chromatographic method in combination with a priori calculations using IONCHROM software

This paper briefly describes original developments in the theoretical and practical ion chromatography. It is demonstrated that new methods may be applied for the highly-selective analysis of complex natural objects. The determination of different species of sulfur and other ions in the condensates of fumarolic gases is considered in detail as an example.     

Separation of concentrated acid and salt solutions in nanoporous media as the basis for a new technology of processing of phosphorus-containing raw materials

The physical and mathematical models were used to study the method of acid retardation for separating acids from their salts in concentrated multicomponent solutions using nanoporous sorption materials. A combined mechanism of separation relies on the fact that in the sorption phase having a low dielectric permittivity, smaller-sized acid particles, namely, the molecules or strongly bound and weakly hydrated ion pairs, can penetrate the nanopores and are retained within these pores due to molecular sorption or competitive solvation forces. The dissolved salts presented by highly hydrated ions or weakly bound ion pairs can easily pass through the porous medium with a flow of concentrated solution, which is pumped through the column packed with the granulated bed of gel-type ion exchange resins or hypercrosslinked polymers. In conventional cyclic AR processes, purified acid is desorbed by water according to the mechanism of competitive solvation. However, such processes can be successfully used only when the salts separated from acids are highly soluble, as is the case with chloride and nitrate solutions free of components that may form compounds insoluble in neutral medium. At the separation in real sulfate and phosphate media, which normally contain alkaline earth metals and other components, conventional AR- based technologies proved to be unsuccessful. The new modified version of acid retardation is based on the previously discovered effect of stabilization of colloidal systems and supersaturated solutions in porous ion exchange media. A distinctive feature of the proposed technique is the use of weakly acidic aqueous solutions, instead of water, at the stages of acid displace in the cyclic AR processes. The proposed technique of WPA purification using strong-base gel-type ion exchangers in the phosphate form opens up the possibility of stable and feasible processes of acid separation and purification with simultaneous extraction of valuable components, e.g., REE concentrate.     

Heterogeneity of grain-size fractions of nanodiamonds from the Orgueil C1 meteorite

A model for the composition of meteoritic nanodiamonds is suggested based on analysis of the concentrations and isotopic compositions of C, N, and Xe in the nanodiamond-rich grain-size fractions, which were separated for the first time from the Orgueil CI chondrite. According to the model, meteoritic nanodiamond consists of two populations of grains (denoted C_HL and C_N). The size distributions of grains in populations in the C_HL and C_N populations are different: the C_HL population is finer grained than C_N. The grains of the C_HL population are characterized by a radial gradient in the carbon isotopic composition, and they contain implanted anomalous noble gases (HL component) and the heavy nitrogen isotope ¹⁵N. Following (Clayton et al., 1995), the probable astrophysical source of this population of nanodiamond grains is thought to be the mixing helium and hydrogen shells of a Type-II supernova, and the mechanism that produced these grains was the slow CVD process. The C_N population grains have homogeneous isotopic compositions of carbon (δ¹³C ≡–100‰) and nitrogen (δ¹⁵N ≡–400‰) and contain almost all nitrogen of the nanodiamond-rich fractions. This population of nanodiamond grains was likely formed by a fast unequilibrated process, when shock waves affected organic compounds or gas rich in C- and N-bearing compounds during the early evolution of the protosolar nebula. Calculations within the framework of the model show that the nanodiamond-rich fractions separated from the Orgueil meteorite have the C_N/C_HL ratios varying from 1 in the finest grained fraction to 10 in the coarse-grained one. At these proportions of the populations, weighted mean δ¹³C values of C_HL grains in the fractions lie within the range of 42 to 394‰, and the concentrations of ¹³²Xe-HL and ¹⁵N are (49–563) × 10^–8 cm³/gC and (1.1–6.2) × 10^–5 cm³/gC, respectively.     

The subsidence and thermal history of the Baikit anteclise sedimentary basin

The Riphean rocks of the Baikit anteclise have been examined using pyrolysis Rock–Eval 6 to evaluate the subsidence history and erosion level. The studied Riphean rocks have the МK₃–МK₄ catagenesis grade. Based on the catagenesis of organic matter we propose a model of maximum burial before the beginning of the accumulation of Vendian deposits. Estimated calculations of subsidence and erosion have shown that the assessed catagenesis grade could be reached at a depth of 7 km, while the erosion level was approximately 5–7 km.     

Fracturing in the high-carbon formation of the northern flank of the South-Tatar arch

The problem of studying the Domanik deposits and their reservoir potential is among the most important ones. The discovery of hydrocarbon deposits in similar rocks at various depths, the considerable variability of reservoir properties, and ambiguity in establishing the values of the effective thickness set the task for researchers to estimate them more reliably. The high-carbon kerogenic-carbonate-siliceous stratum that is characterized by the development of differently-oriented systems of fractures is of outstanding interest.     

The upper Bajocian of the Crimean Mountains: Paleogeography and sedimentation conditions from palynological data

Based on the spore-pollen data, the mineral composition of clay rocks, analyzed structures and facies, and a general paleogeographic analysis, the sedimentation conditions and landscapes of islands located during the Late Bajocian in the region of the present-day the Crimean Mountains have been reconstructed. It is shown that the sublatitudinally elongated insular land zone had a width of 30 km, the heights of the islands were no more than 1 km, with steep mudflow-affected northern slopes and with an extensive river system on the southern slopes.