Interpretation of subhorizontal crustal reflections by metamorphic and rheologic effects in the eastern part of the Pannonian Basin

The geologic origin of subhorizontal reflections, often observed in crustal seismic sections, was investigated by establishing metamorphic facies and strength of rocks in depth, and correlating these properties to seismic reflection sections from eastern Hungary. Estimation of the depths of metamorphic mineral stability zones utilized the principles developed by Fyfe et al. and known geothermal data of the area. The strength versus depth profile was derived by relating local seismic P -wave interval velocities to Meissner et al. 's activation energy. The results show that the series of subhorizontal reflections, observed in the Pannonian Basin, are a consequence of combined metamorphic and rheologic changes in depths. The synthesis of the integrated data set suggests that the retrograde alteration of the pre-Tertiary basement above the percolation threshold was made possible by the softening effect of shear zones and their water-conducting capacity. The subhorizontal reflections of highest energy, of the consolidated crust below the percolation threshold, originate in the depths of greenschist, amphibolite and granulite metamorphic mineral facies, which were formed in geothermal and pressure conditions similar to those existing today. These results imply the overprint of earlier (Variscan) metamorphic sequences of the crust by more recent retrograde metamorphic processes.     

Patterns in the Turkish reinsurance claim data, 1998–2002: An application of the extreme value theory

The devastating 1999 Marmara and Düzce earthquakes led to a significant increase in the earthquake studies in Turkey in geological, engineering and financial aspects. Extreme Value Theory (EVT) has a range of applications from stock market changes to natural disasters like floods and hurricanes. Here EVT is fitted to the ordinary and earthquake reinsurance claims of Turkey.     

The Removal of Dissolved Metals by Hydroxysulphate Precipitates during Oxidation and Neutralization of Acid Mine Waters, Iberian Pyrite Belt

This study examines the removal of dissolved metals during the oxidation and neutralization of five acid mine drainage (AMD) waters from La Zarza, Lomero, Esperanza, Corta Atalaya and Poderosa mines (Iberian Pyrite Belt, Huelva, Spain). These waters were selected to cover the spectrum of pH (2.2–3.5) and chemical composition (e.g., 319–2,103 mg/L Fe; 2.85–33.3 g/L SO₄⁼) of the IPB mine waters. The experiments were conducted in the laboratory to simulate the geochemical evolution previously recognized in the field. This evolution includes two stages: (1) oxidation of dissolved Fe(II) followed by hydrolysis and precipitation of Fe(III), and (2) progressive pH increase during mixing with fresh waters. Fe(III) precipitates at pH < 3.5 (stages 1 and 2) in the form of schwertmannite, whereas Al precipitates during stage 2 at pH 5.0 in the form of several hydroxysulphates of variable composition (hydrobasaluminite, basaluminite, aluminite). During these stages, trace elements are totally or partially sorbed and/or coprecipitated at different rates depending basically on pH, as well as on the activity of the SO₄⁼ anion (which determines the speciation of metals). The general trend for the metals which are chiefly present as aqueous free cations (Pb²⁺, Zn²⁺, Cu²⁺, Cd²⁺, Mn²⁺, Co²⁺, Ni²⁺) is a progressive sorption at increasing pH. On the other hand, As and V (mainly present as anionic species) are completely scavenged during the oxidation stage at pH < 3.5. In waters with high activities (> 10⁻¹) of the SO ₄⁼ ion, some elements like Al, Zn, Cd, Pb and U can also form anionic bisulphate complexes and be significantly sorbed at pH < 5. The removal rates at pH 7.0 range from around 100% for As, V, Cu and U, and 60–80% for Pb, to less than 20% for Zn, Co, Ni and Mn. These processes of metal removal represent a significant mechanism of natural attenuation in the IPB.     

Superdense CO2 inclusions in Cretaceous quartz–stibnite veins hosted in low-grade Variscan basement of the Western Carpathians, Slovakia

CO₂ inclusions with density up to 1,197 kg m⁻³ occur in quartz–stibnite veins hosted in the low-grade Palaeozoic basement of the Gemericum tectonic unit in the Western Carpathians. Raman microanalysis corroborated CO₂ as dominant gas species accompanied by small amounts of nitrogen (<7.3 mol%) and methane (<2.5 mol%). The superdense CO₂ phase exsolved from an aqueous bulk fluid at temperatures of 183–237°C and pressures between 1.6 and 3.5 kbar, possibly up to 4.5 kbar. Low thermal gradients (∼12–13°C km⁻¹) and the CO₂–CH₄–N₂ fluid composition rule out a genetic link with the subjacent Permian granites and indicate an external, either metamorphogenic (oxidation of siderite, dedolomitization) or lower crustal/mantle, source of the ore-forming fluids.According to microprobe U–Pb–Th dating of monazite, the stibnite-bearing veins formed during early Cretaceous thrusting of the Gemeric basement over the adjacent Veporic unit. The 15- to 18-km depth of burial estimated from the fluid inclusion trapping PT parameters indicates a 8- to 11-km-thick Upper Palaeozoic–Jurassic accretionary complex overlying the Gemeric basement and its Permo-Triassic autochthonous cover.     

Geometry and accuracy of reflecting points in bistatic satellite altimetry

The analysis of the time and space distribution of specular (reflecting) points in bistatic altimetry between GPS and CHAMP satellites or SAC-C (taken as examples) is extended from Wagner and Klokočník (2003 J. Geod 77: 128–138). We demonstrate a significantly higher number and density of reflecting points in bistatic altimetry in comparison with traditional monostatic altimetry. After an outline of our older accuracy assessment for the vertical position of the reflecting point, we add a new independent derivation and compare both approaches. We account for orbit errors of both the transmitters (GPS) and receiver (CHAMP) satellites, and the measurement (delay) error. We found that the accuracy of the vertical position of the reflecting point decreases only slowly with increasing off-nadir angle and that the orbit errors must be accounted for if decimeter and better accuracy is required. In this paper, we do not study errors such as state of the ocean, technical parameters of the receiving system, and atmospheric corrections.     

A powder diffraction quantification method (ALJOR) for atmospheric particulate matter

The percentage calculation of crystalline phases in atmospheric particulate matter samples by means of an adiabatic approach of the matrix-flushing method with preferred preparations that avoids preferential orientations, should never be interpreted as absolute values. On the contrary, it should be seen as an indicator of the significant differences between each and every analyzed sample. Factors such as the application of constants, which are only useful for preparations of polycrystalline samples free of preferential orientation, and/or like the deficient resolution shown by the diffraction diagrams for certain phyllosilicate phases, bring a high degree of uncertainty to these percentage calculations. An alternative method of crystalline and amorphous phase quantification is presented below. Once the majority phases in the samples were identified, appropriate pure phases corresponding to each of them were selected. Then, the corresponding calibration curves were built using corundum (number 676 NIST) as a reference pattern phase. After validating the obtained calibration curves, the constants corresponding to each phase and selected spacing were calculated. The ALJOR method has been used for the quantification of five samples.     

U–Pb evidence for a polyorogenic evolution of the HP–HT units of the NW Iberian Massif

. A isotope dilution thermal ionisation mass spectrometry U-Pb geochronological study was carried out on the high-pressure and high-temperature units (HP-HT units) overlying the oceanic suture in the Allochthonous Complexes of the NW Iberian Variscan Belt. The rocks investigated are seven granulite- to eclogite-facies paragneisses and one leucosome within mafic high-pressure granulites in the Ordenes and Cabo Ortegal Complexes of NW Spain. U-Pb dating of zircon, monazite, titanite and rutile reveal the presence of a pervasive Early Ordovician metamorphic event at ca. 500-480 Ma and a later Early Devonian event at ca. 400-380 Ma. The U-Pb ages, in conjunction with petrological and structural data, indicate that the high-pressure event recorded by these rocks is Early Ordovician in age. Monazite ages in the paragneisses suggest that peak metamorphic conditions were reached at ca. 500-485 Ma. Subsequently, the rock ensemble underwent exhumation accompanied by partial melting and zircon growth at ca. 485-470 Ma. Melting of mafic granulites was coeval with this latter episode as indicated by zircon crystallisation age in the leucosomes dated at ca. 486 Ma. Based on these data and on the general features of magmatism and metamorphic evolution, it is proposed that this process took place at a convergent plate boundary within a peri-Gondwanan oceanic domain. Monazite, titanite and rutile data in some of the samples studied show evidence of a second metamorphic episode that took place between ca. 400 and 380 Ma (with a peak at ca. 390-385 Ma). This Early Devonian event, at variance with the previous one, was not pervasive, but, rather, was localised in areas of intense Variscan tectonothermal reworking. It is claimed that this later metamorphic event was recorded by the U-Pb system in areas where monazite and titanite growth was enhanced by fluid circulation in highly strained rocks (Variscan shear zones). According to previous structural studies and Ar-Ar dating of fabrics, this Early Devonian episode took place as the HP-HT units were deformed and thrusted upon the ophiolitic units in the early stages of the Variscan collision.     

Al hematites prepared by homogeneous precipitation of oxinates: material characterization and determination of the Morin transition

A novel method for synthesis of aluminium hematites, based upon the homogeneous precipitation of Fe and Al oxinates in various proportions, is presented. The precursor precipitates are heated in air at 700?°C. X-ray diffraction, thermal analyses, BET, FTIR, optical reflection analysis, TEM and Mössbauer spectroscopy at room temperature and 80?K of the resulting products indicate that single-phase hematites are formed with structural Al substitution of up to 10 at%. Interestingly, the particle size (>100?nm) is not substantially reduced by the Al content. Although it remains difficult to obtain a homogeneously distributed Al substitution in the final hematite, this processing line offers a unique opportunity to separate the effects of grain size and Al substitution on the Morin transition temperature (T _M) of Al hematite. From the comparison between the present hematites and a series of Al-substituted hematites with lepidocrocite as precursor, it could be shown that the effect on T _M, associated with a change of a factor 10 in grain size, is about 1/3 of the effect caused by a change of 10 in the degree of substitution. Finally, it is suggested that proper thermal treatments under different conditions of the same precursors are likely to produce spinel phases.