Soil metal pollution from former Zn–Pb mining assessed by geochemical and magnetic investigations: case study of the Bou Caid area (Tissemsilt,Algeria)

Former zinc and lead mines that have been operating for half a century are located in the massif of Bou Caid (Tissemsilt, Algeria). Hazardous heavy metals emitted from the mines are abundant in the surrounding soil and cause strong metal pollution in the region. This paper investigates the extent of lead and zinc mine activity derived pollution by characterizing both magnetic and geochemical properties of samples collected in the vicinity of the mines. The results of the magnetic study show the coexistence of magnetic minerals such as magnetite, hematite and goethite. Analyses on surface soils and weathered rocks suggest that hematite and goethite have ore-related lithogenic origins. Magnetic susceptibility shows a positive correlation with lead content when present in low-to-medium concentrations (< ~500 mg/kg). At higher lead concentrations, there is no correlation with magnetic susceptibility. The relationship between magnetic susceptibility and zinc content is not straightforward. These observations are explained by the higher affinity of Pb to iron oxides at lower pollution levels and their preferential bonding to carbonates when Pb and Zn contents are extremely high, as demonstrated by Iavazzo et al. (J Geochem Explor 113:56–67, 2012) in a study of former Zn–Pb mine in Morocco. Based on the general features of the spatial maps of field-measured magnetic susceptibility, mass-specific magnetic susceptibility, Pb and Zn contents, it is concluded that field magnetic measurements provide a good qualitative proxy of pollution spread out of the mining galleries, while laboratory measurements afford a more detailed investigation of the links between iron oxides and the main heavy metals in the ore.     

Late Viséan–Serpukhovian foraminiferans and calcareous algae from the Adarouch region (central Morocco), North Africa

Three Upper Viséan to Serpukhovian limestone formations from the Adarouch region (central Morocco), North Africa, have been dated precisely using foraminiferans and calcareous algae. The lower and middle part of the oldest formation, the Tizra Formation (Fm), is assigned to the latest Asbian (upper Cf6γ Subzone), and its upper part to the Early Brigantian (lower Cf6δ Subzone). The topmost beds of this formation are assigned to the Late Brigantian (upper Cf6δ Subzone). The lower part of the succeeding Mouarhaz Fm is also assigned to the Late Brigantian (upper Cf6δ Subzone). The Akerchi Fm is younger than the other formations within the region, ranging from the latest Brigantian (uppermost Cf6δ Subzone) up to the Serpukhovian (E₁–E₂). The base of the Serpukhovian (Pendleian Substage, E₁) is repositioned, to coincide with the appearance of a suite of foraminiferans including Archaediscus at tenuis stage, Endothyranopsis plana, Eostaffella pseudostruvei, Loeblichia ukrainica, Loeblichia aff. minima and Biseriella? sp. 1. The upper Serpukhovian (Arnsbergian Substage, E₂) is marked by the first appearance of Eostaffellina ex. gr. paraprotvae and Globoomphalotis aff. pseudosamarica. The biostratigraphical scheme used for the reassessment of the foraminiferal zones and subzones in the Adarouch area closely compares with that for the British succession in northern England (Pennine Region), where the stratotypes of the Upper Viséan (Asbian and Brigantian) and Early Serpukhovian (Pendleian) substages are located. Thus, a succession equivalent to an interval from the Melmerby Scar Limestone to the Great (or Little) Limestone is recognized. These assemblages are also compared to other foraminiferal zones proposed in other regions of Morocco. Several foraminiferans have been identified that are proposed as potential Serpukhovian markers for other basins in Western Europe, and compared to sequences in Russia and the Donets Basin, Ukraine. Copyright © 2008 John Wiley & Sons, Ltd.     

Geochemical process regulating groundwater quality in a coastal region with complex contamination sources: Barka,Sultanate of Oman

An investigation was carried out to evaluate the geochemical processes regulating groundwater quality in a coastal region, Barka, Sultanate of Oman. The rapid urban developments in Barka cause depletion of groundwater quantity and deterioration of quality through excessive consumption and influx of pollutants from natural and anthropogenic activities. In this study, 111 groundwater samples were collected from 79 wells and analysed for pH, EC, DO, temperature, major ions, silica and nutrients. In Barka, water chemistry shows large variation in major ion concentrations and in electrical conductivity, and implies the influence of distinguished contamination sources and hydrogeochemical processes. The groundwater chemistry in Barka is principally regulated by saline sources, reverse ion exchange, anthropogenic pollutants and mineral dissolution/precipitation reactions. Due to ubiquitous pollutants and processes, groundwater samples were classified into two groups based on electrical conductivity. In group1, water chemistry is greatly influenced by mineral dissolution/precipitation process and lateral recharge from upstream region (Jabal Al-Akdar and Nakhal mountains). In group 2, the water chemistry is affected by saline water intrusion, sea spray, reverse ion exchange and anthropogenic pollutants. Besides, high nitrate concentrations, especially in group 2 samples, firm evidence for impact of anthropogenic activities on groundwater quality, and nitrate can be originated by the effluents recharge from surface contamination sources. Ionic ratios such as SO₄/Cl, alkalinity/Cl and total cation/Cl indicate that effluents recharged from septic tank, waste dumping sites and irrigation return flow induce dissolution of carbonate minerals, and enhances solute load in groundwater. The chemical constituents originating from saline water sources, reverse ion exchange and mineral dissolution are successfully differentiated using ionic delta, the difference between the actual concentration of each constituent and its theoretical concentration for a freshwater–seawater mix calculated from the chloride concentration of the sample, and proved that this approach is a promising tool to identify and differentiate the geochemical processes in coastal region. Hence, both regular geochemical methods and ionic delta ensured that groundwater quality in Barka is impaired by natural and human activities.     

Distribution and Influence of Iron Phases on the Physico—Chemical Properties of Phyllosilicates

Clay minerals from different Cretaceous stratigraphic successions of Egypt were investigated using XRD,DTA,dissolution analysis(DCB),IR,Moessbauer and X-band Electron Spin Resonance(ESR) spectroscopies.The purity of the samples and the degree of structural order were determined by XRD.The location of Fe in the octahedral sheet is characterized by absorption bands at-875cm^-1 assigned as Al-OH-Fe which is present after chemical dissolution of free iron.The Moessbauer spectra of these clays sow two doublets with isomer shift and quadrupole splitting typical of octahedral coordinated Fe^3 ,in addition to third doubler with hyperfine parameter typical of Fe^2 in the spectra of Abu-Had kaolinite (H)sample.6-lines magnetic hyperfine components which are consistent with those of hematite are confirmed in the spectra of both Isel and Rish kaolinite samples.Goethite was confirmed by both IR and DTA.Multiple nature of ESR of these clays suggested structural Fe in distorted octaedral symmetry and as non-structural Fe.Little dispersion and low swelling indices as well as incomplete activaiton of investigated montmorillonite samples by NaCO3 appear to be due to incomplete disaggregation of montmorillonite particles.This can be explained by the ability of Fe-gel to aggregate the montmorillonite into pseudo-particles and retard the rigid-gel structure.However,extraction of this ferric amorphous compound by dithonite treatment recovers the surface properties of the montmorillonite samples.On the other hand,amounts and site occupation of Fe associated with kaolinite samples show a negative correlation with the parameters used to describe the degree of crystalline perfection,color,brightness and vitrification range of these kaolinite samples.     

Incidences of water-rock interaction on natural resources characters,Oum Er-Rabia Basin (Morocco)

The Oum Er-Rabia Basin provides important water resources from a multi-layer aquifer system of which the Turonian limestone aquifer constitutes the main potential resource. The same basin is also known by its wealth in phosphates and comprises the Ouled Abdoun Series, the largest Moroccan phosphate occurrence. The present work attempts to characterize the interaction of natural resources with their impacts on water and phosphates quality. Hydrogeochemical data on waters of the Turonian and the Eocene aquifers, as well as their petrographical analyses, by optical and electronic microscopes and by the X-ray diffraction method on weathered and non-weathered rocks of relative aquifers, have shown that water-rock interaction has a large influence on the quality of water and phosphate resources in the Oum Er-Rabia Basin.     

Structural boundaries delimitation from geomagnetic data using the continuous wavelet transform. Application to Hoggar (Algeria)

The main goal of the proposed work is to delineate structural boundaries in a very complex geology environment using the spatial and statistical properties of the potential field data. The analysis is performed using magnetic anomaly of the total field data over In Ouzzal, an Archaean north–south elongated block belonging to the Hoggar (Algeria). This region is geologically and geophysically very poorly known except some localized areas. The intrinsic properties of high-frequency signals and the related causative sources are explored, thanks to two-dimensional continuous wavelet transform. The obtained results, represented by spatial distribution of the maxima of the modulus of the wavelet transform at each scale, clearly show that the major magnetic singularities of the field may be related to geological features. Comparison with the Euler’s deconvolution solutions exhibits a very good correlation. Even though where geological structures are known, our method shows better resolution and accuracy. The proposed multiscale method proves to be more powerful, easy to use, and versatile where classical methods of potential field interpretation fail or are very constraining. However, work is still ongoing to try to better and fully characterize the causative sources of the potential fields.     

Hornblende gabbros of Wadi Az Zarib area,Central Eastern Desert,Egypt: opaque mineralogy,geochemistry, tectonic setting,and petrogenesis

A small intrusive fresh gabbroic mass intrudes the Neoproterozoic metasediments and Dokhan volcanics of Wadi Az Zarib area, Central Eastern Desert. It is composed of hornblende gabbros and leuco-hornblende gabbros. Their petrography, opaque mineralogy, and geochemistry are addressed to elucidate their tectonic setting and petrogenesis. They represent a subduction-related calc–alkaline magma that evolved in an island arc setting. In terms of maturity, the supposed arc represents an intermediate stage between continental arc and active continental margin. Thermobarometry and physical–chemical data of the parent magma as deduced from compositions of amphiboles, biotite, and plagioclase indicate crystallization temperatures of 931–825 °C at pressures of 6.16–4.01 kbar and H₂O_melt of 6.4–5.2 wt%. Data, as presented, argue in favor of fractional crystallization mechanism to be accounted to the present suite to interpret the observed variations. The evolution of the suite from hornblende gabbros to leuco-hornblende gabbros was accompanied by decreasing of MgO, CaO, Cr, and Ni with simultaneous increasing of Al₂O₃, TiO₂, Na₂O, K₂O, Ba, Rb, Sr, La, and Ce. Residuals calculated during mass balance fractional crystallization modeling suggest that brown and green hornblendes are the main fractionated phases which derived the melt composition towards the leuco-hornblende gabbros.     

Modelling the effect of temperature on unsaturated soil behaviour

A simple thermohydromechanical (THM) constitutive model for unsaturated soils is described. The effective stress concept is extended to unsaturated soils with the introduction of a capillary stress. This capillary stress is based on a microstructural model and calculated from attraction forces due to water menisci. The effect of desaturation and the thermal softening phenomenon are modelled with a minimal number of material parameters and based on existing models. THM process is qualitatively and quantitatively modelled by using experimental data and previous work to show the application of the model, including a drying path under mechanical stress with transition between saturated and unsaturated states, a heating path under constant suction and a deviatoric path with imposed suction and temperature. The results show that the present model can simulate the THM behaviour in unsaturated soils in a satisfactory way.