Sorption of lead by chemically modified rice bran

In this work, the effectiveness of native and chemically modified rice bran to remove heavy metal Pb(II) ions from aqueous solution was examined. Chemical modifications with some simple and low-cost chemicals resulted in enhancement of the adsorption capacities and had faster kinetics than native rice bran. Experiments were conducted in shake flasks to monitor the upshot of parameters over a range of pH, initial Pb(II) concentrations and contact times using a batch model study. The sorption capacities q (mg g^?1) increased in the following order: NaOH (147.78), Ca(OH)₂ (139.08), Al(OH)₃ (127.24), esterification (124.28), NaHCO₃ (118.08), methylation (118.88), Na₂CO₃ (117.12) and native (80.24). The utmost uptake capacity q (mg g^?1) was shown by NaOH-pretreated rice bran. The results showed that, using NaOH-modified rice bran, the chief removal of Pb(II) was 74.54 % at pH 5, primary Pb(II) concentration 100 mg L^?1 and contact time 240 min. Equilibrium isotherms for the Pb(II) adsorption were analyzed by Langmuir and Freundlich isotherm models. The Langmuir isotherm model, showing Pb(II) sorption as accessible through the high value of the correlation coefficient (R ² = 0.993), showed a q _max value of 416.61 mg g^?1. The kinetic model illustrated adsorption rates well, depicted by a second order, which gives an indication concerning the rate-limiting step. Thermodynamic evaluation of the metal ion ?G ^o was carried out and led to the observation that the adsorption reaction is spontaneous and endothermic in nature. NaOH chemically modified rice bran was a superb biosorbent for exclusion of Pb(II) and proved to be excellent for industrial applications.     

Optimal design of structures for earthquake loads by a hybrid RBF-BPSO method

The optimal seismic design of structures requires that time history analyses （THA） be carried out repeatedly. This makes the optimal design process inefficient, in particular, if an evolutionary algorithm is used. To reduce the overall time required for structural optimization, two artificial intelligence strategies are employed. In the first strategy, radial basis function （RBF） neural networks are used to predict the time history responses of structures in the optimization flow. In the second strategy, a binary particle swarm optimization （BPSO） is used to find the optimum design. Combining the RBF and BPSO, a hybrid RBF-BPSO optimization method is proposed in this paper, which achieves fast optimization with high computational performance. Two examples are presented and compared to determine the optimal weight of structures under earthquake loadings using both exact and approximate analyses. The numerical results demonstrate the computational advantages and effectiveness of the proposed hybrid RBF-BPSO optimization method for the seismic design of structures.     

Flood frequency analysis based on simulated peak discharges

Flood frequency approaches vary from statistical methods, directly applied on the observed annual maximum flood series, to adopting rainfall–runoff simulation models that transform design rainfalls to flood discharges. Reliance on statistical flood frequency analysis depends on several factors such as the selected probability distribution function, estimation of the function parameters, possible outliers, and length of the observed flood series. Through adopting the simulation approach in this paper, watershed-average rainfalls of various occurrence probabilities were transformed into the corresponding peak discharges using a calibrated hydrological model. A Monte Carlo scheme was employed to consider the uncertainties involved in rainfall spatial patterns and antecedent soil moisture condition (AMC). For any given rainfall depth, realizations of rainfall spatial distribution and AMC conditions were entered as inputs to the model. Then, floods of different return periods were simulated by transforming rainfall to runoff. The approach was applied to Tangrah watershed in northeastern Iran. It was deduced that the spatial rainfall distribution and the AMCs exerted a varying influence on the peak discharge of different return periods. Comparing the results of the simulation approach with those of the statistical frequency analysis revealed that, for a given return period, flood quantiles based on the observed series were greater than the corresponding simulated discharges. It is also worthy to note that existence of outliers and the selection of the statistical distribution function has a major effect in increasing the differences between the results of the two approaches.     

Thermal comfort evaluation in Tehran metro using Relative Warmth Index

Underground railway systems, can generate heat from their operations to raise the temperatures of carriages and the station substantially. This may lead to passenger discomfort and complain especially in warm weather conditions that prevail in Tehran if underground environment is not cooled. Transportation air conditioning Committee of American Society of Heating, Refrigerating and air-conditioning Engineers proposed the Relative Warmth Index for thermal comfort design and investigation in subway environment. In this research, thermal comfort at Tehran metro stations and carriages of lines 1 and 2 has been studied using this index. The measurements were taken during two periods of September 2006 and July 2007 at different zones of stations. For this purpose, temperature, relative humidity and air velocity were measured at different times. The status of the air-conditioning systems together with passenger traffic was also recorded. A total number of 231 measurements including 114 and 117 measurements were carried out in September 2006 and in July 2007 respectively. The measurements in September 2006 did not exceed the thermal limit. However, it did exceed in July 2007. In comparison, with thermal comfort level of metros all over the world, Tehran Metro stands in an acceptable condition, while the maximum capacity of air-conditioning systems was not used, if so the thermal comfort condition would be better.     

Prediction of rainfall using artificial neural networks for synoptic station of Mashhad: a case study

In this paper, we have utilized ANN (artificial neural network) modeling for the prediction of monthly rainfall in Mashhad synoptic station which is located in Iran. To achieve this black-box model, we have used monthly rainfall data from 1953 to 2003 for this synoptic station. First, the Hurst rescaled range statistical (R/S) analysis is used to evaluate the predictability of the collected data. Then, to extract the rainfall dynamic of this station using ANN modeling, a three-layer feed-forward perceptron network with back propagation algorithm is utilized. Using this ANN structure as a black-box model, we have realized the complex dynamics of rainfall through the past information of the system. The approach employs the gradient decent algorithm to train the network. Trying different parameters, two structures, M₅₃₁ and M₇₄₁, have been selected which give the best estimation performance. The performance statistical analysis of the obtained models shows with the best tuning of the developed monthly prediction model the correlation coefficient (R), root mean square error (RMSE), and mean absolute error (MAE) are 0.93, 0.99, and 6.02 mm, respectively, which confirms the effectiveness of the developed models.     

Role of early warning systems for sustainable agriculture in Iran

Drought is a complex phenomenon in meteorology and can affect agriculture. Its impacts vary greatly since they depend not only on the magnitude, timing, duration, and frequency of rainfall deficits but also on the differing responses of various plants to water stress. The essence of good drought management is to use this range of responses to the best advantage. Iran is one of the world’s largest and most productive suppliers of food and fiber. The objective of this study was, therefore, to gather and analyze standardized information on the Role of Early Warning Systems for Sustainable Agriculture for cereals and leguminous and industrial crops in Iran environmental zones. Annual average rainfall (mm year^?1) and ET_O (mm year^?1) are 76.56 and 3001, respectively, in stations with very dry climate; 195.41 and 2249, respectively, in stations with dry climate; 343.9 and 1351, respectively, in stations with semi-dry climate; 583.8 and 1153, respectively, in stations with semi-humid climate; and 1272 and 949, respectively, in stations with humid climate. The maximum and minimum of annual average rainfall happened in Rasht (1337 mm year^?1) and Zabol (57 mm year^?1) stations, and the maximum and minimum for annual average ET_O happened in Chabahar (3909.15 mm year^?1) and Anzali harbor (890.6 mm year^?1), respectively. Therefore, 13.63 % of stations have suitable conditions for crop productions and 86.37 % are in critical conditions.     

Storage dam’s locality placing by MCDM techniques (case study: three dams in Iran)

MCDM (multi-criteria decision making) techniques are used to choose the best alternative among the relevant ones and rank the others. In this research, MCDM techniques were used to choose and rank the best places for constructing storage dams in Iran. To achieve this goal, the relevant information and data about dam construction situations were collected. Then, the recommended places for constructing storage dams were ranked by using MCDM techniques and according to the most suitable criteria which have been chosen based on experts’ opinions. To rank dam constructing project, three MCDM techniques, i.e., TOPSIS, AHP, and DEMATEL, were used. The results showed that the application of MCDM models by putting emphasis on economic, social, political, and technical criteria enables government and watershed managers to choose the best alternative(s) for constructing a storage dam.     

Predicting the Isotropic Volumetric Compression Response of Hydrating Cemented Paste Backfill (CPB)

Geotechnical and Geological Engineering - Deep and high-stress mining results in stress transfers onto the previously placed backfill, and mines have recorded several MPa induced backfill stresses....