Perspectives in Modelling Climate–Hydrology Interactions

Various land–atmosphere coupling mechanisms exist that may lead to large-scale impacts on climate and hydrology. Some of them are still less understood and not adequately represented in state-of-the-art climate modelling. But, as the current generation of climate models enables consideration and implementation of important coupling processes, the present study provides perspectives for the modelling of relevant climate–hydrology interactions. On a more short-term perspective, these comprise anthropogenic land use and especially irrigation, which has been shown that it may even affect remote regions. On a long-term perspective, the coupling of hydrology to carbon cycle and vegetation becomes important, specifically the dynamics of permafrost and wetlands. Here, we present a review of current knowledge combined with some exemplary studies from a large-scale point of view. Therefore, we focus on climate–hydrology interactions that are relevant on scales utilized in the current or forthcoming global and regional climate modelling exercises.     

Local Ionospheric Modeling Using the Localized Global Ionospheric Map and Terrestrial GPS

global ionosphere maps are generated on a daily basis at CODE using data from about 200 GPS/GLONASS sites of the IGS and other institutions. The vertical total electron content is modeled in a solargeomagnetic reference frame using a spherical harmonics expansion up to degree and order 15. The spherical Slepian basis is a set of bandlimited functions which have the majority of their energy concentrated by optimization inside an arbitrarily defined region, yet remain orthogonal within the spatial region of interest. Hence, they are suitable for decomposing the spherical harmonic models into the portions that have significant strength only in the selected areas. In this study, the converted spherical harmonics to the Slepian bases were updated by the terrestrial GPS observations by use of the least-squares estimation with weighted parameters for local ionospheric modeling. Validations show that the approach adopted in this study is highly capable of yielding reliable results.     

Study of near bed stochastic turbulence and sediment entrainment over the ripples at the bed of open channel using image processing technique

In this study, the coherent structure in near bed bursting events over the ripples and mechanism of sediment bed load transport were investigated experimentally. The experiments in this study were carried out in the laboratory flume, in two parts; fixed bed ripple and mobile bed ripple. Tow artificial ripples, were built and used for making both fixed and mobile bed. For the fixed bed part, velocity fluctuations were measured using an Acoustic Doppler Velocimeter. In order to apply bursting analysis for obtained data, a computer program was written in visual basic language. Then, variation of turbulence shear stress associated with different bed form geometries was determined and mechanism of sediment transport by ripple shape at the bed of open channel was investigated. For the mobile bed part, artificial ripples were used as mould to make ripples. An image processing technique was used to record amount of sediment particles which are entrained and deposited over the same selected points at the fixed bed part. Results of mobile bed part, confirmed the results of shear stress analysis of fixed bed part.     

Cloud Point Extraction for the Preconcentration of Silver and Palladium in Real Samples and Determination by Atomic Absorption Spectrometry

A cloud point extraction procedure is presented for the preconcentration and simultaneous determination of Ag⁺ and Pd²⁺ in various samples. After complexation with 2‐((2‐((1H‐benzo[d]imidazole‐2‐yl)methoxy)phenoxy)methyl)‐1H‐benzo[d]imidazol (BIMPI), which was used as a new chelating agent, analyte ions were quantitatively extracted to a phase rich in Triton X‐114 following centrifugation, and determination was carried out by flame atomic absorption spectrometry (FAAS). Under the optimum experimental conditions (i. e., pH = 7.0, 15.0·10^–5 mol/L BIMPI and 0.036% (w/v) Triton X‐114), calibration graphs were linear in the range of 28.0–430.0 μg/L and 57.0–720.0 μg/L with detection limits of 10.0 and 25.0 μg/L for Ag⁺ and Pd²⁺, respectively. The enrichment factors were 35.0 and 28.0 for Ag⁺ and Pd²⁺, respectively. The method has been successfully applied to evaluate these metals in some real samples, including waste water, soil and hydrogenation catalyst samples.     

Spectroscopic-based assessment of the content and geochemical behaviour of arsenic in a highly heterogeneous sulphide-rich mine waste dump

Soil pollution by arsenic is a serious environmental problem in many mining areas. Quick identification of the amount and extent of the pollution is an important basis for developing appropriate remediation strategies. In a case study, 55 soil samples were collected from a highly heterogeneous waste dump around the Sarcheshmeh copper mine, south east Iran. Samples’ visible and near-infrared (VNIR) reflectance spectra were measured, transformed to absorbance and then pre-processed using Savitzky–Golay first-derivative (FD) and Savitzky–Golay second-derivative (SD) transformation methods. The obtained spectra were then subjected to three regression models including principal component regression (PCR), partial least squares regression (PLSR) and support vector regression (SVR) for predicting arsenic concentration. The best prediction accuracies were obtained by SVR and PLSR methods applied on first-derivative pre-processed spectra with R ² values of 0.81 and 0.69, respectively. It was found that VNIR spectroscopy is a successful method for predicting As concentration in contaminated soils of the dumpsites. Study of the prediction mechanism showed that the intercorrelation between arsenic and spectral features of soil including iron oxy/hydroxides and clay minerals was the major mechanism enabling the prediction of arsenic concentration. However, higher values of correlation coefficients at ~460, ~560 and ~590 nm suggested the internal association between arsenic and iron minerals as the more important mechanism for prediction. This conclusion supported previous speciation studies conducted in the same waste dump using improved correlation analysis and chemical sequential extraction method.     

Sedimentological and geoenvironmental evaluation of the coastal area between Al-Khowkhah and Al-Mokha,southeastern Red Sea,Republic of Yemen

The increasing anthropogenic activities (e.g., constructing touristic resorts) have led to notable changes in the Yemeni Red Sea coastal regions. In this context, recent sediments have been investigated to infer possible natural and man-induced processes on these coastal areas. The target area lies between longitudes 43°13′–43°30′E and latitudes 13°15′–13°55′N. It extends about 90 km along the coastline as a part of the Tihama plain. Geomorphologically, it forms a long-curved stretch with pronounced headlands, embayments and bays. Generally, it is covered by recent sediments (wadi, lagoon, beach and spit deposits along with sabkha, coastal dunes and mangrove). Textural studies reveal that most of the studied sediments are mainly poorly to moderately sorted and are composed mainly of sandy fractions with few gravel and mud, mostly bimodal with minor unimodal patterns. The igneous (granites) as well as basic (basalt, andesite and andesitic pyroclastics) and acidic (dacite and rhyolite) volcanic rocks of Tertiary age, which are exposed to the east of the study area, are believed to be the source of pyroxenes, amphiboles, epidotes, biotite, sphene, zircon, tourmaline and rutile, in a decreasing order of abundance. Moreover, smectite, kaolinite, chlorite, illite and palygorskite are the predominant clay minerals, mainly of detrital origin. The total carbonate content fluctuates from 37.41% (lagoon sediments) to 53.74% (sabkha sediments). The high amount of sea grasses, which covers the tidal flat zone and relates to the fine-grained sediments, accounts for the high organic matter content. The mineralogy of the source rocks has controlled the general distribution of major elements (Fe, Mg, Na, K and Mn) in the beach sediments. In such sediments, the concentrations of the heavy metals (Cu, Zn, Cd, Ni, Pb and Co) may reflect the sediment pollution using different approaches. The enrichment factors (EFs) of the trace metals for most samples reveal values that are greater than 1, referring to three groupings, which are: moderate to moderately severe (Zn, Cu and Mn), minor to moderate (Pb and Co) and zero to minor (Cd and Ni) enrichment. The EFs for Pb, Cd, Ni and Co metals (<5) may be attributed to the crustal materials and/or natural weathering processes. But, those for Zn, Cu and Mn (>5), especially in Al-Khowkhah–Abu-Zahr, Moushij–Zahari–Ruays, Yokhtol and Mokha localities, are possible of anthropogenic contributions.     

Textures and compositions of cobalt pentlandite and cobaltian mackinawite from the Madan-Kudan copper deposit,Khetri Copper Belt,Rajasthan, India

The Khetri Copper Belt (KCB), a part of the Proterozoic Delhi–Aravalli fold belt in western India, hosts several Cu deposits, which are known to contain considerable Au, Ag, Co and Ni. Although many Co-bearing phases have been reported from the KCB and adjacent areas, detailed textural and geochemical data are either unavailable or scant except for mackinawite. In this study, we describe the textures and compositions (determined by EPMA) of two very rare Co-rich phases, namely cobaltian mackinawite (containing up to 12.68 wt.% Co, 1.90 wt.% Ni and 2.52 wt.% Cu) and cobalt-pentlandite (containing up to 49.30 wt.% Co and 10.19 wt.% Ni), identified based on composition, from the Madan-Kudan deposit. To the best of our knowledge, neither cobalt-pentlandite nor such highly Co-rich mackinawite have previously been reported from this area. The common sulphide minerals viz. chalcopyrite, pyrrhotite and rare pyrite occur in chalcopyrite-pyrrhotite ± pyrite-magnetite-chlorite-blue amphibole (Cl-rich hastingsite-pargasite-sadanagaite) ± marialitic scapolite ± allanite ± uraninite veins in amphibole-bearing feldspathic quartzite and garnetiferous chlorite schist. Cobaltian mackinawite is invariably associated with chalcopyrite and occurs as exsolution and inclusion within chalcopyrite or outside, but at the contact of chalcopyrite. On the other hand, cobalt-pentlandite is invariably associated with pyrrhotite and shows similar textural relation with pyrrhotite as that of mackinawite with chalcopyrite. Mineralogically diverse undeformed sulphide veins comprising Cl-rich amphibole and locally Cl-rich marialitic scapolite suggests epigenetic hydrothermal mineralization involving Cl-rich saline fluid in the Madan-Kudan deposit. Transport of metals, derived from a mafic source rock with high intrinsic Ni:Co ratio, by Cl-rich fluid can suitably explain the high Co:Ni ratio of the studied ore minerals. Presence of such highly Co-rich phases and other circumstantial evidences, enumerated in this work, are consistent with variants of Fe oxide (–Cu–Au) (IOCG) style mineralization, at least for some stages of mineralization in the Madan-Kudan deposit.     

Erosion potential assessment of watersheds through GIS<Emphasis Type="Bold">-</Emphasis>based hypsometric analysis: a case study of Kurram Tangi Dam

Sediment discharge due to soil and rock erosion within the watersheds is the major cause of siltation in water reservoirs. Siltation in reservoirs reduces the capacity for power production, irrigation water supply, and other domestic purposes. Hypsometric analysis has widely been used to identifying the geomorphic development stages (stabilized, equilibrium, and un-stable) to assess the erosion proneness of watersheds. In this study, watershed of Kurram Tangi Dam and its four sub-watersheds (SWs) were considered to determine their sediment discharge capacity through hypsometric analysis. The boundaries of watershed and sub-watersheds were delineated from Digital Elevation Model (DEM). The hypsometric parameters i.e., hypsometric integral (HI) and curves were generated using Geographic Information System (GIS) techniques. The HI values of SW-1 (0.41) and SW-2 (0.36) indicated that these two SWs were relatively more prone to erosion and contributed higher sediment discharge in Dam siltation. The results were validated through sampling the main drainage channel (Kurram River) to determine the sediment concentration at 12 sites during summer, winter, and spring seasons. Comparison of HI and sediment concentration of SWs presented high correlation (R²?=?0.87). The results emphasized the effective watershed management, extensive afforestation, and construction of silt-control structures at appropriate locations in sub-watersheds. This will ultimately maintain the water and power generation capacity as well as extending the life span of the Dam.     

Estimating width of the stable channels using multivariable mathematical models

Predicting behavior and the geometry of the channels and alluvial rivers in which the erosion and sediment transport are in equilibrium is one of the most important topics in river engineering. Various researchers have proposed empirical equations to estimate stable river width (W). In this research, empirical equations were examined and tested with a comprehensive available data set consisting of 1644 points collected from 29 stable rivers in various parts of the world. The data set covers a wide range of flow conditions, river geometry, and bed sediments. This data set is classified in two groups (W < 600 m and W ≥ 600 m) for presenting the new models. The new linear and nonlinear multivariable equations were fitted to these two groups, and the best models were selected by preliminary tests and diagnostic determined for each group. The determination coefficient of these models ranged from 0.87 to 0.96. The results show that the models presented in this paper are more accurate with respect to the previously presented models. In the second part, “Artificial neural networks,” perceptron was used and a new methodology for estimating stable channel width was developed. Comparison of the statistical methods presented in this paper and the results of perceptron neural network revealed preferential recent method.