Petrogenesis and Tectonic Implications of the Latest Cretaceous Intrusive Rocks from the Eastern Gangdese Belt, Southeast Tibet

The latest Cretaceous magmatic activity in the eastern segment of the Lhasa terrane provides important insights for tracking the magma source and geodynamic setting of the eastern Gangdese batholith, eastward of eastern Himalayan Syntaxis. Detailed petrological, geochemical and geochronological studies of the intrusive rocks (monzodiorites and granodiorites) of the eastern Gangdese batholith are presented with monzodiorites and granodiorites giving zircon U–Pb crystallization dates of 70–66 Ma and 71–66 Ma with εHf(t) values of ?4.8 to +6.2 and ?1.9 to +5.3, respectively. These rocks are metaluminous to weakly peraluminous I-type granites showing geochemically arc-related features of enrichment in LREEs and some LILEs, e.g., Rb, Th, and U, and depletion in HREEs and some HFSEs, e.g., Nb, Ta, and Ti. The rocks are interpreted to be derived from partial melting of mantle material and juvenile crust, respectively, which are proposed to be triggered by Neo-Tethyan slab rollback during northward subduction, with both experiencing ancient crustal contamination. The studied intrusive rocks formed in a transitional geodynamic setting caused by Neo-Tethyan oceanic flat subduction to slab rollback beneath the eastern Gangdese belt during the latest Cretaceous.     

扬子地块西南缘大面积低温成矿时代

中国西南地区(川、滇、黔、桂、湘)发育有世界上很典型的低温成矿域,其面积之大(约90万km2)、包含的矿种之多(Au、Hg、Sb、As、P、Pb-Zn、U、Ni-Mo-PGE、重晶石、冰州石和分散元素等)、矿床组成和组合之复杂,在全球十分鲜见。扬子地块西南缘是中国西南大面积低温成矿域的重要组成部分。近年来,作者采用Rb-Sr、Sm-Nd、Ar-Ar等多种同位素定年方法,对扬子地块西南缘产出的磷矿、金矿、锑矿等低温矿床的成矿时代进行了较系统的研究。文章总结了这些研究成果,并结合前人的资料,初步拟定出该区存在三期大规模低温成矿作用,它们分别相当于晚元古代—早古生代(晚震旦世—早寒武世)、晚加里东期(晚志留世—早泥盆地)和燕山期(晚侏罗世—中白垩世)。该区的磷矿、重晶石矿和黑色页岩中的镍钼铂矿主要形成于晚元古代—早古生代,同位素年龄主要为585～540Ma;赋存于前寒武纪浅变质碎屑岩中的金-锑-钨矿床主要形成于晚加里东期,同位素年龄主要为435～380Ma;产于寒武系以后地层中的锑矿床主要是在中燕山期成矿,同位素年龄主要为160～140Ma;而该区的卡林型金矿和汞矿主要在燕山中晚期大规模成矿,同位素年龄主要为170～80Ma。     

Adsorption of phenanthrene on Al (oxy)hydroxides formed under the influence of tannic acid

Although there has been substantial research done on adsorption of metals/metalloids by Al (oxy)hydroxides, little is known regarding the adsorption of polyaromatic hydrocarbons (PAHs) on Al (oxy)hydroxides, especially those formed in the presence of organic acid. This paper investigated the adsorption of phenanthrene on Al (oxy)hydroxides formed with initial tannate/Al molar ratios (MRs) 0, 0.001, 0.01, and 0.1 (referred to MR0, MR0.001, MR0.01, and MR0.1, respectively) through batch adsorption experiments and FTIR study. The results showed that Al (oxy)hydroxides were important sorbents for phenanthrene. The adsorption kinetic data were fitted well with the pseudo-second-order equation. According to a modified Freundlich model, the adsorption capacities of Al (oxy)hydroxides followed a descending order of MR0.1 > MR0 ≥ MR0.01 > MR0.001, which was inconsistent with the organic carbon content in the Al (oxy)hydroxides. Adsorption capacity correlated with the specific surface area, micropore area, and micropore diameter of Al (oxy)hydroxides, yet the relationships were not statistically significant (P > 0.05). FTIR results showed that physical interaction was essential in phenanthrene adsorption onto the Al (oxy)hydroxides, which could be explained by an entropy-driven process. Surface hydrophobicity of Al (oxy)hydroxides played a key role in phenanthrene adsorption. Additional π–π electron donor–acceptor interaction of phenanthrene (acting as electron donor) with aromatic ring of tannic acid (electron acceptor) could be also important in phenanthrene adsorption by high MR Al (oxy)hydroxides, yet it needs further study. The findings obtained in the present study are of fundamental significance in understanding the mechanism of immobilization of PAHs in low organic matter but oxide-rich soils.     

黑河下游土壤和地下水盐分特征分析

根据405个土壤样品和101个水样,分析了黑河下游土壤盐分分布规律以及与地形地貌部位、地下水水化学的关系.结果表明:额济纳三角洲地区的土壤具有质地粗、含盐量高、盐分表聚性强的特征,该地区呈现盐碱化和沙漠化严重、可利用土地资源骤减、生态环境恶化的状况.在所有剖面上盐分的分布呈现漏斗型分布,土壤中盐分随地形变化较为复杂,但与地下水化学变化相一致.地下水矿化度普遍比较高,大多数地区的矿化度在800~3000 mg·L^-1之间变化;水化学类型主要有HCO₃·SO₄-Na、Cl·SO₄-Na(Ca)、HCO₃·Cl-Na(Ca)SO₄·Cl-Na和SO₄·Cl-Na(Ca-Mg).地下水矿化度的高低与补给源的距离远近密切相关,在河岸附近的矿化度变化幅度较小;在远离河道地区,随离岸距离的增减而升降,体现了矿化度的高低主要依赖于上游补给水量变化.     

烧变岩体特性及其注浆扩散行为研究

烧变岩是煤层自燃引起周围围岩变质而形成的特殊类岩石。通过现场取样,在实验室对烧变岩试样进行了物理力学性质测试,试验结果表明：烧变岩的含水率略有降低,而力学强度普遍增强,泊松比略变小,烧变岩体裂隙发育。注浆压力作用下,分析了裂隙尖端的劈裂情况,在此基础上,利用宾汉浆液扩散模型编制了浆液在裂隙网络中的流动扩散程序,可以模拟浆液在非贯通裂隙网络内的流动扩散范围。最后对柠条塔井田烧变岩体进行注浆试验,利用浆液流动模拟程序进行了注浆压力的优化选择,并将实际浆液扩散范围与程序模拟浆液扩散范围进行对比,二者结果较吻合,该程序可以用来指导现场注浆工程参数设计和施工,同时烧变岩体注浆试验也为类似工程注浆施工提供一定的参考依据。     

青藏高原低涡活动的统计研究

利用1980-2004年5～9月逐日08时、20时(北京时,下同)两个时次的500 hPa天气图资料,统计分析了夏季青藏高原低涡(简称高原低涡)的活动特征.结果表明:夏季高原低涡的发生频次具有明显的年代际、年际和季节内变化特征,20世纪90年代以后低涡出现频次较之80年代有下降趋势,7月份是夏季高原低涡的活跃期;青藏高原上产生低涡的四个源地分别为:申扎-改则之间、那曲东北部地区、德格东北部和松潘附近;移出青藏高原的高原低涡在青藏高原上主要有四个涡源:那曲东北部、曲麻莱地区、德格附近和玛沁附近,也存在季节内变化,与青藏高原上产生低涡的涡源不同;部分高原低涡形成后,能在高原上生存36 h以上并发展东移,移动路径主要有东北、东南和向东三条,其中向东北移动的低涡数量最多;而低涡移出青藏高原后的路径与在高原上的移动路径并不相同,移出高原后的低涡多数是向东移动的,其次才向东北、东南移动;高原低涡移出高原时主要有两条路径:一条为东北路径,主要移向河西、宁夏和黄土高原一带;另一条是东南路径,主要移向四川盆地附近,其中,移向黄土高原的低涡最多;移出低涡也表现出一定的年际变化和季节内变化特征;高原低涡移出青藏高原后,多数在12 h内减弱消亡,有些可持续60 h,极少数能存活100 h以上,最长可达192 h,不仅影响我国东部广大地区的降水,甚至可能影响朝鲜半岛和日本;高原低涡在青藏高原上初生时,暖性涡比斜压涡多近两倍,而移出青藏高原后12 h内的低涡性质却发生了很大改变,以斜压涡居多;与60、70年代相比,80年代中期以后高原低涡的发生源地、移动路径和性质等特征都有所改变.     

原油族组分成气的化学动力学模型及其标定

利用等温密封热解实验技术及恒速升温热解实验与PY—GC分析技术的结合,本文分别建立并标定了原油中各族组分,即饱和烃、芳烃、非烃和沥青质成气的化学动力学模型。结果表明,原油中不同族组分成气的过程均可用平行一级反应描述,但不同组分在平均活化能及活化能分布上有明显的差异。各族组分在地史过程中成气的过程可由各自的化学动力学模型来描述。这将使原油成气过程的定量、动态描述成为可能。     

Delineating the Source of Lead in the Urban Atmospheric Dust Based on Stable Isotopic Ratio: A Case Study from Panzhihua City of Southwest China

正Objective Atmospheric lead pollution is a global problem. Mining, coal mining, iron and steel smelting, and chemical and coal-fired power plants are major industries in Panzhihua City of southwest China. Many toxic and harmful heavy metals, including Pb, are emitted in production activities. Pb seriously affects human health and natural ecosystems. Thus, Pb source tracing is important for Pb pollution     

日本虎斑猛水蚤在抑食金球藻中存活、发育和繁殖的实验研究

抑食金球藻(Aureococus anophagefferens)可以形成褐潮, 并对贝类、浮游动物等多种生物均能造成不利影响。为进一步探究抑食金球藻对浮游动物的影响, 本文以日本虎斑猛水蚤(Tigriopus japonicus)为实验生物, 研究抑食金球藻对日本虎斑猛水蚤摄食、存活、生长发育以及繁殖的影响。日本虎斑猛水蚤具有易于在实验室培养、生长周期短、雌雄异体等优点, 是海洋毒性污染物检测的模式生物。实验利用高效液相色谱分析方法, 在日本虎斑猛水蚤体内色素中检测到了抑食金球藻的特征色素19’-丁酰氧基岩藻黄素(But-fuco), 表明日本虎斑猛水蚤能够摄食抑食金球藻。当微藻生物量(相对碳含量)分别同为0.7 μg/mL和7.2 μg/mL时, 在抑食金球藻中无节幼体发育至桡足幼体及成体的存活率均高于以青岛大扁藻为饵料的对照组, 但无显著差异, 并且在前者中无节幼体的发育时间显著低于后者, 12 d内雌体的产卵次数与产卵量显著高于后者。结果表明, 日本虎斑猛水蚤在抑食金球藻中能进行正常的生命活动, 并且是首次报导的一种能够在抑食金球藻中正常摄食、生存、生长发育和繁殖的浮游动物。因此, 当褐潮发生时, 由于贝类幼体等生物会受到显著的不利影响, 日本虎斑猛水蚤等抗性较强的生物可能会成为优势种, 从而会影响浮游动物群落结构的组成, 进而可能会使整个海洋生态系统发生变化。本研究有助于全面了解褐潮对海洋生态系统的影响。     

赞比亚西北省索卢韦齐县铜钴多金属矿地质特征

赞比亚西北省索卢韦齐县铜钴多金属矿主要存在三种矿化类型,第一种是层控型铜矿,矿石矿物为黄铜矿、黝铜矿、辉铜矿,多呈条带状、透镜状等形态,平行黑云石英片岩和二云石英片岩的片理展布;第二种为沉积型铜矿,受到背斜和穹窿的控制,含矿岩系主要为加丹加超群(Katanga)下部罗安组(Roan)页岩、砂岩,金属矿物主要为水胆石、孔雀石、蓝铜矿,多呈星点状、浸染状、斑杂状、团块状等分布在含矿页岩、砂岩中;第三种是热液型铜矿,充填在加丹加超群及其更老的地层中,矿化类型为黄铜矿黄铁矿石英脉型,一般为小型脉状矿床。该类型矿床可与前两类矿床叠加,使矿石品位提高。