Precise U-Pb Zircon Constraints on the Earliest Magmatic History of the Carolina Terrane

The early magmatic and tectonic history of the Carolina terrane and its possible affinities with other Neoproterozoic circum-Atlantic arc terranes have been poorly understood, in large part because of a lack of reliable geochronological data. Precise U-Pb zircon dates for the Virgilina sequence, the oldest exposed part, constrain the timing of the earliest known stage of magmatism in the terrane and of the Virgilina orogeny. A flow-banded rhyolite sampled from a metavolcanic sequence near Chapel Hill, North Carolina, yielded a U-Pb zircon date of 632.9 +2.6/-1.9 Ma. A granitic unit of the Chapel Hill pluton, which intrudes the metavolcanic sequence, yielded a nearly identical U-Pb zircon date of 633 +2/-1.5 Ma, interpreted as its crystallization age. A felsic gneiss and a dacitic tuff from the Hyco Formation yielded U-Pb zircon dates of 619.9 +4.5/-3 Ma and 615.7 +3.7/-1.9 Ma, respectively. Diorite and granite of the Flat River complex have indistinguishable U-Pb upper-intercept dates of 613.9 +1.6/-1.5 Ma and 613.4 +2.8/-2 Ma. The Osmond biotite-granite gneiss, which intruded the Hyco Formation before the Virgilina orogeny, crystallized at 612.4 +5.2/-1.7 Ma. Granite of the Roxboro pluton, an intrusion that postdated the Virgilina orogeny, yielded a U-Pb upper intercept date of 546.5 +3.0/-2.4 Ma, interpreted as the time of its crystallization. These new dates both provide the first reliable estimates of the age of the Virgilina sequence and document that the earliest known stage of magmatism in the Carolina terrane had begun by 633 +2/-1.5 Ma and continued at least until 612.4 +5.2/-1.7 Ma, an interval of approximately 25 m.yr. Timing of the Virgilina orogeny is bracketed between 612.4 +5.2/-1.7 Ma and 586+/-10 Ma (reported age of the upper Uwharrie Formation). The U-Pb systematics of all units studied in the Virgilina sequence are simple and lack any evidence of an older xenocrystic zircon component, which would indicate the presence of a continental-type basement. This observation, together with the juvenile Nd isotopic character of the Virgilina volcanic arc sequence, suggests that the oldest part of the Carolina terrane was built on oceanic crust away from a continental crustal influence.     

东海瓯江凹陷下第三系层序地层学研究

运用威尔(P. R. Val)等人层序地层学的新慨念,对瓯江凹陷下第三系进行了层序地层分析和研究,确定了四个区域不整合面,三套层序,每一套层序又可划分出低水位体系域,海进体系域,高水位体系域。每个体系域,在钻井上可以发现相应的各种沉积相和生物化石。沉积环境的变化,生物化石带的演变反映了海平面变化的控制作用,并能同全球海平面变化对比。     

北海断层封闭性分析

多数北海构造圈闭至少需要一条断层来充当封闭性断层。在北海进行区域研究时，从１０１个勘探目标和２５个油气田中选择了４００多个断层加以分析，这些断层切穿了来自多种沉积环境（海相、海陆过渡相、陆相）碎屑岩沉积层序。本次研究的重点是地质历史时期中可以起到压力或运移遮挡的断层封闭性。通过绘制多种参数，如断层走向、断距、储层厚度、深度、有效厚度与总厚度比值、孔隙度、砂岩有效连通性等与断层封闭性能的关系图，确定各种参数间的分布趋势和相关关系。以预测断层封闭特点、断层分布方向与封闭性之间存在着某种相关关系，断距经过校正到占储层厚度一定比例之后，与断层封闭性之间存在着比例关系，大多数断距大于储层厚度的断层都是封闭性断层。在断层封闭性预测中最有用的参数是断距，有效厚度与总厚度的比伍（净／总）和砂岩有效连通性。本次研究的结论对在北海盆地碎屑岩沉积层序中进行油气勘探和开发时的断层封闭性预测有广泛的适用性，或许也可以应用于其它地区。     

Monitoring the sea change: preliminary assessment of the conservation value of nearshore reefs, and existing impacts, in a high-growth, coastal region of subtropical eastern Australia

In northern NSW, Australia, coastal populations are forecast to increase dramatically over the next 25 years (the "sea change"). However, management of the effects of development on marine communities is hampered by the lack of data on key habitats. Consequently, we developed a protocol to assess the biodiversity and current human impacts on nearshore reefs, habitats that will be readily affected by coastal development. We assessed four reefs adjacent to each of three population centres targeting fish, mollusc and sessile benthic communities, and debris loads. Community structure was highly variable over all spatial scales indicating that reefs should not be considered equivalent within the planning framework. While, debris loads were relatively low on most reefs, those with highest conservation value also had the highest debris loads suggesting potential conflict between human use and long-term sustainability of reefal communities. Without intervention, this situation will be exacerbated in the future.     

Hydrogen peroxide production in marine bathing waters: Implications for fecal indicator bacteria mortality

Hydrogen peroxide concentrations [H(2)O(2)] have been measured over the last two decades in multiple studies in surface waters in coastal, estuarine and oceanic systems. Diurnal cycles consistent with a photochemical production process have frequently being observed, with [H(2)O(2)] increasing by two orders of magnitude over the course of the day, from low nM levels in the early morning to 10(2)nM in late afternoon. Production rates range from <10 for off-shore ocean waters to 20-60nMh(-1) for near-shore coastal and estuarine environments. Slow night-time loss rates (<10nMh(-1)) have been attributed to biological and particle mediated processes. Diurnal cycles have also frequently been observed in fecal indicator bacteria (FIB) levels in surf zone waters monitored for microbial water quality. Measured peak peroxide concentrations in surface coastal seawaters are too low to directly cause FIB mortality based on laboratory studies, but likely contribute to oxidative stress and diurnal cycling. Peroxide levels in the surf zone may be increased by additional peroxide production mechanisms such as deposition, sediments and stressed marine biota, further enhancing impacts on FIB in marine bathing waters.     

Marine debris: A proximate threat to marine sustainability in Bootless Bay, Papua New Guinea

Surveys of stranded marine debris around Motupore Island, a small island in Bootless Bay, Papua New Guinea, revealed exceptionally high loads (up to 78.3itemsm(-2)), with major concentrations in mangrove-dominated, depositional areas. The worst affected, 50-m stretch of shore was estimated to contain >37.000 items with a combined weight of 889kg. Consistent with studies elsewhere, plastics comprised by far the majority of debris across all sites (89.7%). The lack of centralised waste collection and limited village-based resources, coupled with an increasing population, suggests that this issue is a long way from solution. High debris loads thwart attempts to rehabilitate depleted mangrove forests through smothering of seedlings, perpetuating run-off and water quality issues in the bay. Addressing marine debris is thus of fundamental importance for the sustainability of Bootless Bay and its resources, and a critical step in promoting ecosystem resilience.     

Semipermeable membrane devices link site-specific contaminants to effects: Part 1 - Induction of CYP1A in rainbow trout from contaminants in Prince William Sound, Alaska

Extracts from semi-permeable membrane devices (SPMDs) deployed on beaches in Prince William Sound (PWS), Alaska, were used to evaluate if complex contaminant mixtures from different sources can be distinguished by the resulting cytochrome P450 1A (CYP1A) activity in exposed test animals. Deployment sites included canneries, salmon hatcheries, and beaches where lingering oil remains from discharges during the 1964 earthquake or the 1989 Exxon Valdez oil spill. Other sites were selected at random to evaluate region-wide contaminant inputs or were located in salmon streams to evaluate contaminants carried and released by migrating salmon carcasses following reproduction. Following standard deployments of approximately 28 d, an aliquot of the accumulated contaminants was intraperitoneally injected without cleanup into juvenile rainbow trout (Oncorhynchus mykiss). After 2 d and 7 d, the activity of CYP1A was measured by the ethoxyresorufin-o-deethylase (EROD) assay. Exposure to extracts from the oiled sites and one hatchery site with numerous creosote pilings elicited strong EROD responses, whereas fish exposed to salmon stream extracts elicited weak but significant responses during late summer compared to late spring. Responses from the other sites were not significant, indicating contaminants from these sources are unlikely to cause CYP1A induction in resident biota. Rather than simply assessing extant contaminants, this method evaluates the potency of the different sites for bringing about aryl hydrocarbon receptor responses in resident biota.     

Semipermeable membrane devices link site-specific contaminants to effects: PART II - A comparison of lingering Exxon Valdez oil with other potential sources of CYP1A inducers in Prince William Sound, Alaska

We deployed semipermeable membrane devices (SPMDs) on beaches for 28 days at 53 sites in Prince William Sound (PWS), Alaska, to evaluate the induction potential from suspected sources of cytochrome P450 1A (CYP1A)-inducing contaminants. Sites were selected to assess known point sources, or were chosen randomly to evaluate the region-wide sources. After deployment, SPMD extracts were analyzed chemically for persistent organic pollutants (POPs) and polycyclic aromatic hydrocarbons (PAH). These results were compared with hepatic CYP1A enzyme activity of juvenile rainbow trout injected with the same extracts prior to clean-up for the chemical analyses. Increased CYP1A activity was strongly associated with PAH concentrations in extracts, especially chrysene homologues but was not associated with POPs. The only apparent sources of chrysene homologues were lingering oil from Exxon Valdez, asphalt and bunker fuels released from storage tanks during the 1964 Alaska earthquake, creosote leaching from numerous pilings at one site, and PAH-contaminated sediments at Cordova Harbor. Our results indicate that PWS is remarkably free of pollution from PAH when nearby sources are absent as well as from pesticides and PCBs generally.