Chlorohydrocarbon pesticides in the Australian marine environment after banning in the period from the 1970s to 1980s

The chlorohydrocarbon pesticides (CHPs) (principally DDT, dieldrin, hexachlorocyclohexane (HCH) including lindane, chlordane, heptachlor and heptachlorepoxide, aldrin and hexachlorobenzene (HCB)) were used extensively in Australia during the 1960s and 1970s. These were progressively banned from the 1970s with DDT being totally banned in 1987. The levels in marine waters are believed to have progressively declined as indicated by water in the Brisbane River, which consistently fell from maximum concentrations of about 1.7 μg/l in 1972–1973 to not detectable in 1986–1987. In some urban areas sediment concentrations, up to 1700 μg/kg dry weight, were recorded in the early 1990s which may reflect the reworking and exposure of older more contaminated material. Fish exhibited consistent occurrence of DDT, HCH, dieldrin and HCB through the 1970s to the 1990s. Maximum concentrations of DDT and dieldrin occurred generally in the 1970s at 40.3 and 8.8 μg/g wet weight, and minimums in the 1990s at 2.4 and 0.041 μg/g wet weight respectively. Inputs of dialdrin from sewage and DDT from the broad environment, reflected by the calculated daily human uptake in the diet, were shown to decline with half-lives of 1.1–1.5 and about 3 years respectively. This evidence suggests that banning of the CHPs has greatly reduced the inputs into the marine environment with consequent reductions in concentrations in biota but there is the occasional occurrence of relatively high concentrations.     

The scientific legacy of Harold Edwin Hurst (1880–1978)

ABSTRACT

Emanating from his remarkable characterization of long-term variability in geophysical records in the early 1950s, Hurst’s scientific legacy to hydrology and other disciplines is explored. A statistical explanation of the so-called “Hurst Phenomenon” did not emerge until 1968 when Mandelbrot and co-authors proposed fractional Gaussian noise based on the hypothesis of infinite memory. A vibrant hydrological literature ensued where alternative modelling representations were explored and debated, e.g. ARMA models, the Broken Line model, shifting mean models with no memory, FARIMA models, and Hurst-Kolmogorov dynamics, acknowledging a link with the work of Kolmogorov in 1940. The diffusion of Hurst’s work beyond hydrology is summarized by discipline and citations, showing that he arguably has the largest scientific footprint of any hydrologist in the last century. Its particular relevance to the modelling of long-term climatic variability in the era of climate change is discussed. Links to various long-term modes of variability in the climate system, driven by fluctuations in sea surface temperatures and ocean dynamics, are explored. Several issues related to the Hurst Phenomenon in hydrology remain as a challenge for future research.

Editor M. Acreman; Associate editor A. Carsteanu     

Possible ice-rafted erratics in late Early to early Middle Pleistocene shallow marine and coastal deposits in northeast Norfolk, UK

Erratic clasts with a mass of up to 15 kg are described from preglacial shallow marine and coastal deposits (Wroxham Crag Formation) in northeast Norfolk. Detailed examination of their petrology has enabled them to be provenanced to northern Britain and southern Norway. Their clustered occurrence in coastal sediments in Norfolk is believed to be the product of ice-rafting from glacier incursions into the North Sea from eastern Scotland and southern Norway, and their subsequent grounding and melting within coastal areas of what is now north Norfolk. The precise timing of these restricted glaciations is difficult to determine. However, the relationship of the erratics to the biostratigraphic record and the first major expansion of ice into the North Sea suggest these events occurred during at least one glaciation between the late Early Pleistocene and early Middle Pleistocene (c. 1.1–0.6 Ma). In contrast to the late Middle (Anglian) and Late Pleistocene (Last Glacial Maximum) glaciations, where the North Sea was largely devoid of extensive marine conditions, the presence of far-travelled ice-rafted materials implies that earlier cold stage sea-levels were considerably higher.     

Prediction of bioconcentration and related lethal and sublethal effects with aquatic organisms

It is now well established that the octanol/water partition coefficient (K_0W) can be used to estimate bioconcentration of persistent organic compounds, such as the chlorohydrocarbons as well as PAHs and other hydrophobic substances. However, while these relationships are well established in the laboratory, use in the field often poses a number of problems. In recent studies of contaminants in fish from Australia, bioconcentration has been described using additional information on specimen size, lipid content and fish movement patterns.The use of internal biotic concentration provides an additional new and different perspective on toxicant behaviour as compared to the conventional ambient aqueous concentration-based toxicity measures. The internal lethal concentration for persistent organic compounds approaches a constant value for many compounds, and at these concentrations lethal effects are observed. This constant internal lethal concentration provides a basis for predicting toxicity and its relationship to exposure period. In addition, sublethal effects can be successfully related to the internal biotic concentration.     

Devensian glacial events in Buchan (NE Scotland): A progress report on new OSL dates and their implications

Optically stimulated luminescence (OSL) dating of a series of glaciofluvial/glaciodeltaic sediments in central Buchan and Aberdeen has recently been undertaken. The aims of this project are to test the chronological model proposed by the most recent regional review and the suggestion that parts of Buchan may have remained ice-free during the last glacial maximum (late marine isotope stage (MIS) 3 and MIS 2 29–15 ka). The preliminary results indicate that during the Devensian (ca. 116–12 ka), extensive areas of Buchan may have been glaciated earlier than previously believed (possibly during MIS 4, 72–60 ka), but parts of the region show no depositional evidence of later glaciation. Some waterlain sediments from the Ugie Valley have yielded OSL ages indicating deposition during MIS 5d to MIS 5a (116–72 ka). We discuss whether the absence of overlying glaciogenic sediments at these locations raises questions about the reliability of the OSL ages or about existing models of the Devensian glaciation of Buchan.     

Long-term declines in two apex predators,bull sharks (<Emphasis Type="Italic">Carcharhinus leucas</Emphasis>) and alligator gar (<Emphasis Type="Italic">Atractosteus spatula</Emphasis>), in Lake Pontchartrain,an oligohaline estuary in southeastern Louisiana

We analyzed historic and current fishery independent data to determine if the abundance of two apex predators, bull sharks (Carcharhinus leucas) and alligator gar (Atractosteus spatula), in Lake Pontchartrain had changed significantly over the last half century. Lake Pontchartrain is an environmentally degraded oligohaline estuary in southeastern Louisiana that has experienced considerable changes in fish assemblage composition over this interval. Using gillnet, beach seine, and trawl data collected during three time periods (1953–1955, 1977–1978, and 1996–2005), we analyzed trends in abundance forC. leucas andA. spatula using generalized linear models with a negative binomial error structure and a log link. Lake Pontchartrain data were divided into four spatial locations (northwest, northeast, southwest, southeast) since each region represents a unique combination of anthropogenic and natural influences that could affect catches. For each species and gear type, we produced log-likelihood profiles for the instantaneous rate of change in relative abundance through time. Raw catches were generally lower for both species in the later surveys.C. leucas were not captured in beach seines since the 1950s andA. spatula were rarely captured in trawls or seines since the 1970s. Likelihood profiles of changes in abundance forC. leucas andA. spatula showed very large declines in both species since 1953.C. leucas declined by 98.6% (95% CI: 73.4–99.9%) in gillnets and became functionally extirpated in beach seines with a decline of 99.9% (95% CI: 23–99.9%). Among all gears,C. leucas declined by the same rate as in gillnets. The decline inA. spatula was also large with a decrease of 98.6% (95% CI: 73.4–99.9%) in beach seines and a decline of 99.2% (95% CI: 54.8–99.9%) in trawls since 1953. Catches ofA. spatula in gillnets did not show a significant change over the study period. The continued decline of these two apex predators could seriously affect efforts to restore this degraded estuarine ecosystem.     

A theoretical model for gas adsorption-induced coal swelling

Swelling and shrinkage (volumetric change) of coal during adsorption and desorption of gas is a well-known phenomenon. For coalbed methane recovery and carbon sequestration in deep, unminable coal beds, adsorption-induced coal volumetric change may cause significant reservoir permeability change. In this work, a theoretical model is derived to describe adsorption-induced coal swelling at adsorption and strain equilibrium. This model applies an energy balance approach, which assumes that the surface energy change caused by adsorption is equal to the elastic energy change of the coal solid. The elastic modulus of the coal, gas adsorption isotherm, and other measurable parameters, including coal density and porosity, are required in this model. Results from the model agree well with experimental observations of swelling. It is shown that the model is able to describe the differences in swelling behaviour with respect to gas species and at very high gas pressures, where the coal swelling ratio reaches a maximum then decreases. Furthermore, this model can be used to describe mixed-gas adsorption induced-coal swelling, and can thus be applied to CO₂-enhanced coalbed methane recovery.     

Structural controls on sulphide deposition at the dyke–lava boundary, slow-spreading ocean crust, Macquarie Island

Ocean Drilling Program hole 504B revealed an ocean crust hydrothermal sulphur anomaly on the dyke–lava transition, with implications for global sulphur sinks. Here we confirm the presence of the anomaly sporadically along 7.5 km of dyke–basalt contact on the Macquarie Ridge at Macquarie Island, a 39–9.7 Ma slow‐spreading setting. Background contact‐zone pyrite S contents average 1845 p.p.m. across ～50 m. However, zones of small‐scale brittle faulting that commonly occur on and above the dyke–basalt contact average between 5000 and 11 000 p.p.m. S (20–30 m widths). These consist of steep ridge‐parallel faults and fault splays on the contact, overlain by up to 50 m of linked pyritic fault trellis. The contact zone faults are haloed by disseminated pyrite–chlorite, cross‐cut by quartz–chlorite–sphalerite and epidote‐cemented breccias, containing evidence of turbulent flow. The structural control on sulphur deposition is attributed to the active extensional slow spreading setting. With increasing extension, diffuse mixing across the contact was replaced by channellized flow and dynamic mixing in fault arrays. The magnitude of the dyke–lava transition sulphur sink must be reassessed to take account of this heterogeneity.     

Marine Isotope Stage 7–6 transition age for beach sediments at Morston,north Norfolk,UK: implications for Pleistocene chronology,stratigraphy and tectonics

Optically stimulated luminescence age estimates for the Pleistocene beach at Morston, north Norfolk, UK, obtained by the single‐aliquot regenerative‐dose protocol, indicate a Marine Isotope Stage (MIS) 7–6 transition date. The view that the beach is of Ipswichian (MIS 5e) age, held virtually unanimously for the last 75 years, may now be discarded. The extant beach sequence lies up to ～5 m OD, yet global models suggest that MIS 7–6 sea levels were typically substantially below that of today. The explanation may lie with poorly understood regional tectonic movements. The MIS 7–6 date helps to constrain the ages of glacial deposits that bracket the beach sediments at Morston. The underlying Marly Drift till cannot be younger than MIS 8; this may also be true for the complex assemblage of glaciogenic landforms and sediments, including the Blakeney esker, in the adjacent lower Glaven valley. The well‐established Late Devensian (MIS 2) age of the Hunstanton Till is not compromised by the date of the Morston beach. There is no indication of a proposed Briton's Lane glaciation during MIS 6 times. Copyright © 2009 John Wiley & Sons, Ltd.     

Kerosene-like tainting in Australian mullet

A preliminary report on the chemical composition of substances causing a kerosene-like taint in mullet. These substances are kerosene-like in composition and may originate from similar substances isolated from aquatic areas.