Experimental Study of Factors Controlling Sorption of Heavy Metals on Ariake Clay and Implication for Practice

A series of batch tests have been presented to investigate the effects of solid-solution contact time, solid:solution ratio, and pH of solution on sorption of Cd²⁺ and Pb²⁺ on Ariake clay from Kyushu region of Japan. The results show that, among the three investigated factors, solid:solution ratio (SD/SN) seems to be the crucial controlling factor. The Freundlich sorption parameters determined from the batch tests were applied to a typical field landfill in which the Ariake clay was used as soil barrier. The impacts of the landfill were assessed by numerical analysis. Based on the analysis result, the significance of selecting proper solid:solution ratio for determining sorption parameters from batch test has been discussed.     

Angular fluctuations in the cosmic microwave background owing to initial perturbations in the radiation temperature

A new method is proposed to account for multiple scattering by electrons in calculations of the correlation functions describing the angular fluctuations in the cosmic microwave background radiation (CMBR). The apparatus of the theory of radiative transport with Rayleigh scattering is used. The problem is reduced to solving an integral equation for the vector source function (dependent only on time), along with differential equations for the other quantities (scalar potentials, baryon velocities, etc.) which show up in the problem. The quantities which describe the angular fluctuations in the CMBR (in the temperature and in the polarization) are then calculated by integrating the vector source function along the line of sight. As an illustration, the correlation functions and power spectra are calculated for the case where the fluctuations are produced by some initial gaussian perturbations of the CMBR. __________ Translated from Astrofizika, Vol. 50, No. 4, pp. 621–631 (November 2007).     

On the multi-century Southern Hemisphere response to changes in atmospheric CO2-concentration in a Global Climate Model

Summary The transient response of the Southern Hemisphere to climate change is examined using an intermediate complexity climate model. Unlike previous studies, the Southern Ocean response on the centennial to multi-centennial time-scale is assessed in some detail. It is shown that changes in atmospheric CO₂-concentrations lead to an increase in the strength of the Antarctic Circumpolar Current (ACC) by ∼20 Sv by 2750 for an atmospheric CO₂-concentration of 750 ppm. This increase is predominantly the result of an enhanced steric height gradient. The increase in the strength of the ACC induces changes in its steering around topographic features. This change in ACC pathway causes increased surface flow of colder waters into some regions (reducing the rate of warming) and increased surface flow of warmer waters into others (increasing the rate of warming). This meridional shifting of the ACC causes changes in atmospheric temperature in the Southern Hemisphere to be nonuniform. It is also shown that the strength and location of the Antarctic Bottom Water (AABW) overturning cell is affected by increased atmospheric CO₂. For a CO₂-concentration scenario increasing gradually to 750 ppm, AABW production initially decreases, then recovers and eventually increases. New production zones form, which extend AABW production all the way from the Weddell Sea eastward into the Ross Sea. These new production zones are the result of increased areas of atmosphere-ocean interactions, due to decreased sea-ice coverage, although the overturned waters are now warmer and fresher due to climate change. A new production zone of Antarctic Intermediate water is also established in the Southeast Pacific Ocean, poleward of its present-day location.     

Exhumation of high-pressure rocks of the Kokchetav massif: facts and models

The exhumation of ultrahigh-pressure (UHP) metamorphic units from depths more than 100-120 km is one of the most intriguing questions in modern petrology and geodynamics. We use the diamondiferous Kumdy-Kol domain in the Kokchetav Massif to show that exhumation models should take into consideration initially high uplift velocities (from 20 down to 6 cm/year) and the absence of the deformation of UHP assemblages. The high rate of exhumation are indicated by ion microprobe (SHRIMP) dating of zircons from diamondiferous rocks and supported by the low degree of nitrogen aggregation in metamorphic diamonds.Diamondiferous rocks in the Kumdy-Kol domain occur as steeply dipping (60°-80°) thin slices (few hundred metres) within granite-gneiss. Using geological, petrological and isotopic-geochemical data, we show that partial melting of diamondiferous metamorphic rocks occurred; a very important factor which has not been taken into account in previous models.Deformation of diamondiferous rocks at Kumdy-Kol is insignificant; diamond inclusions in garnet are often intergrown with mica crystals carrying no traces of deformation. All these facts could be explained by partial melting of metapelites and granitic rocks in the Kumdy-Kol domain. The presence of melt is responsible for an essential reduction of viscosity and a density difference (Δρ) between crustal rocks and mantle material and reduced friction between the upwelling crustal block, the subducting and overriding plates. Besides Δρ, the exhumation rate seems to depend on internal pressure in the subducting continental crustal block which can be regarded as a viscous layer between subducting continental lithosphere and surrounding mantle.We construct different models for the three stages of exhumation: a model similar to “corner flow” for the first superfast exhumation stage, an intermediate stage of extension (most important from structural point of view) and a very low rate of exhumation in final diapir+erosional uplift.     

Marine mammals from northeast Atlantic: relationship between their trophic status as determined by delta13C and delta15N measurements and their trace metal concentrations

The relationship between trophic position through delta13C and delta15N and trace metal concentrations (Zn, Cd, Cu and Hg) was investigated in the tissues of six marine mammal species from the Northeast Atlantic: striped dolphin Stenella coeruleoalba, common dolphin, Delphinus delphis, Atlantic white-sided dolphin Lagenorhynchus acutus, harbour porpoise Phocoena phocoena, white beaked-dolphin Lagenorhynchus albirostris, grey seal Halichoerus grypus stranded on French Channel and Irish coasts. White-beaked dolphins, harbour porpoises, white-sided dolphins, common and striped dolphins display the same relative and decreasing trophic position, as measured by delta15N values, along both the Irish and French channel coasts, reflecting conservative trophic habits between these two places. Hepatic and renal Cd concentrations were significantly correlated to muscle delta13C and delta15N values while Hg, Zn and Cu did not. These results suggest that Cd accumulation is partly linked to the diet while other factors such as age or body condition might explain Hg, Zn or Cu variability in marine mammals. Combined stable isotope and trace metal analyses appear to be useful tools for the study of marine mammal ecology.     

Geochemical Stratigraphy and Microvertebrate Assemblage Sequences across the Silurian/Devonian Transition in South China

Carbon isotope (δ13Corg) analyses of non-marine clastic rocks and neritic carbonates and black shales spanning the Silurian/Devonian transition are compared from two richly fossiliferous sequences in Qujing of East Yunnan and Zoige of Sichuan, South China. The two sections, Xishancun and Putonggou sections in South China, reveal positive δ13Corg shifts happening in the Upper Pridoli and Lower Devonian and reaching peak values as heavy as ?25.2‰ (Xishancun) and ?19.9‰ (Putonggou) in the lowermost Lochkovian following the first occurrence of the thelodont Parathelodus and the conodont Icriodus woschmidti woschmidti (only in Putonggou Section and together with Protathyris-Lanceomyonia brachiopod fauna). These results replicate a globally known positive shift in δ13Corg from the uppermost Silurian to the lowermost Devonian. The δ13Corg variations across the Silurian/Devonian Boundary (SDB) at the two sections in South China exhibit a shift in carbon isotopic composition similar to the detailed SDB curves from the borehole Klonk-1 drilled at top of the Klonk Global Standard Stratotype-Section and Point (GSSP) in the Prague Basin, Czech Republic. In addition, four microvertebrate assemblages, including the Liaojiaoshan, Xishancun, Yanglugou and Xiaputonggou assemblages, are recognized from the Silurian/Devonian transition exposed in the Xishancun and Putonggou sections, respectively. The results from both carbon isotope stratigraphy and microvertebrate assemblage sequences suggest that the SDB in South China is located at the base of the Xishancun Formation (between sample QX-20 and sample QX-21) in the Xishancun Section and the lower part of the Xiaputonggou Formation (between sample ZP-09 and sample ZP-10) in the Putonggou Section. The isotopic trend for organic carbon together with the changes of microvertebrate remains across the SDB can offer an approach to a potential correlation of the SDB from different sedimentary facies, which help to correlate the marine with non-marine deposits.     

Generation and hydrocarbon entrapment within Gondwanan sediments of the Mandapeta area, Krishna-Godavari Basin, India

The discovery of hydrocarbons (mainly gas) in commercial quantities from Gondwanan sediments in the Mandapeta field of Krishna-Godavari Basin, India, provided impetus for intensified exploration in Mandapeta and the adjoining Kommugudem, Draksharama and Endamuru fields. Both oil and gas have been found in the reservoirs of Mandapeta (Triassic) and Golapalli (Early Cretaceous) formations. Mature, localised, basal shales (1.0–1.1% Ro) in the Mandapeta formation have sourced the oils from the Mandapeta Sandstone reservoir (Triassic). The oils being produced from Golapalli Sandstone reservoir (Early Cretaceous) are relatively less mature and have been sourced by the underlying shales in the Mandapeta Formation at a maturity level of 0.80–0.85% Ro. The source and maturity data preclude liquid hydrocarbon sourcing from the Kommugudem (Permian) sequence. Permian coals and shales of the Kommugudem Formation are the major source rocks for gaseous hydrocarbons in this area. The hydrocarbon generation started in Early Cretaceous in the Kommugudem Formation, but the intermittent tectonic activity (with associated structural developments) has resulted in reorientation and redistribution of the then existing trap configurations. The present day maturity level of the Permian sediments in the Mandapeta field is 1.2% Ro or greater, capable of generating gas dominantly. The Raghavapuram shale in the Mandapeta area is adequately mature and has good hydrocarbon potential for oil generation. The probability of finding hydrocarbon reserves in the sands of Raghavapuram shales and other suitable traps is high. Modern seismic information together with geologic models can give new exploration leads.     

Migration of supermassive black holes in galactic nuclei

The migration of central black holes in galactic nuclei through their encounters with galactic globular clusters is studied. The black hole moves in the field of the galactic bulge with a fixed potential. The dependences of the black-hole drift amplitude on orbital parameters of the globular cluster, its mass, and bulge parameters have been found. The drift amplitude of the central black hole can reach several parsecs in our Galaxy and several tens of parsecs in early-type (Sa) and late-type (Sc) spiral galaxies.     

山区谷底沉陷预测模型及其参数反演

我国西部地区地势复杂,沟壑纵横,地下开采极易导致边坡失稳,引发采动滑坡。在地下采动沉降与滑坡体挤压上升的叠加影响下,谷底区域地表沉降值明显小于类似地质采矿条件下的平原地区。为准确预测山区谷底区域地表沉降值,基于简支梁的弹性变形理论,并借助概率密度函数建立了山区谷底区域地表沉陷预计修正模型,明确模型参数物理意义及其取值方法。依据修正模型,以实测值和预测值之差平方和最小为原则构建适应值函数,基于模拟退火粒子群算法提出新的模型参数反演方法,借助MATLAB语言编制了相应的参数反演程序。最后将研究成果应用于山西某矿,得到谷底区域预测结果中误差为73 mm,与实测值基本一致,取得了较好的工程实践效果。