Influence of the spatial resolution of satellite-derived vegetation parameters on the biogenic Volatile Organic Compounds (VOC) emission modeling

Vegetation is a natural source of Volatile Organic Compounds (VOC) that plays an important role in atmospheric chemistry. The main objective of the current study is to implement a model to quantify process-based VOC emissions from plants that focuses on the relationship between the sensitivity of VOC emission estimates to spatial resolution data, based on scientific knowledge and vegetation dynamics derived from satellite observations. The Normalized Difference Vegetation Index (NDVI) and Leaf Area Index (LAI) were elected to examine this issue using different resolutions of satellite-derived products: 22m from the DEIMOS-1 satellite, and 250m and 1000m provided by MODIS. The study is focused on an area of 80×80km² in Portugal for 2011. Detailed land cover and meteorological data are also included in the emission quantification algorithm. The primary outcomes were determined using a multi-scale analysis showing spatial and temporal variations in the vegetation parameters and modeling results. The results confirm that the emissions model is highly sensitive to the spatial resolution of the satellite-derived data, resulting in about a 30% difference in total isoprene emissions for the study area.     

OPTIMUM DIGITAL FILTERING AND INVERSE FILTERING IN THE FREQUENCY DOMAIN*

Two distinct filters are developed in the frequency domain which represent an attempt to increase the resolution of fine structure contained in the signal whilst keeping the expected filtered noise energy within reasonable bounds. A parameter termed the White Noise Amplification is defined and used together with a measure of the deconvolved pulse width in order to provide a more complete characterisation of the filters. Each of the two main types of frequency domain filters discussed varies in properties with respect to a single adjustable parameter. This may be contrasted with a time domain Wiener filter which in general has three variables: length, delay and an adjustable noise parameter or weight. The direct frequency domain analogue of the Wiener filter is termed a gamma-Fourier filter, and is shown to have properties which span the range from those of a spiking filter with zero least square error at one extreme, to those of a matched filter at the other extreme of its variable parameter's range. The second type of filter considered—termed the modulated Gaussian filter—is similarly shown to be a perfect spiking filter at one extreme of its parameter range, but adopts the properties of an output energy filter at the other extreme.     

Simulation Of Salt-Water Encroachment In A Multi-Layer Groundwater System,Bangkok, Thailand

Salt-water encroachment in the multi-layer groundwater system underlying the Bangkok metropolitan area was simulated with a quasi-three-dimensional flow and solute-transport model. The quasi-three-dimensional model used in this study is based on the model SUTRA. Accurate conceptualization of the initial state of the system with regard to the distribution of salt-water concentration is very important for modeling, especially in areas where localized zones of high salt concentration exist in the groundwater. Data adequacy and model results were evaluated by a geostatistical analysis. The model is capable of simulating the regional trend of potentiometric levels and salt concentration. However, lack of monitoring data in areas where localized zones of high salt concentration exist resulted in large model residuals. RÉSUMÉ: L'empiétement des eaux salées dans le système hydrologique multi-couche sous-jacent la zone métropolitaine de Bangkok a été simulé à l'aide d'un modèle quasi-tridimensionnel représentant l'écoulement des eaux et le transport d'éléments en solution. Le modèle quasi-tridimensionnel utilisé dans cette étude est basé sur le modèle SUTRA. Une conceptualisation exacte de l'état initial du système en ce qui concerne la répartition de la concentration des eaux salines est très important, particulièrement dans les endroits localisés où l'eau souterraine presente une forte concentration en sel. La qualité des donnés et des résultats a été estimée à l'aide d'une analyse géostatistique. Le modèle est capable de simuler la tendance régionale des niveaux potentiométriques et de la concentration en sel. Cependant, le manque de données de contrôle dans les endroits à forte concentration a donné lieu à des résiduels importants. RESUMEN: La intrusión de agua salina en el sistema multicapa bajo el área metropolitana de Bangkok se simuló mediante un modelo de flujo y transporte de solutos casi-tridimensional, basado en el modelo SUTRA. La conceptualizacián precisa de la distribución inicial de concentraciones de agua salina es muy importante para el modelo, especialmente en áreas donde existen zonas locales de alta concentración salina en el agua subterránea. La exactitud de los datos y del modelo se evaluaron mediante un análisis geoestadístico. El modelo permite simular la tendencia regional de los niveles piezométricos y la concentración de sales. Sin embargo, la falta de datos de muestreo en las zonas locales de alta salinidad resultaron en valores altos de los residuos calculados por el modelo.     

Estimation of Above Ground Biomass for Central Indian Deciduous Forests Using ALOS PALSAR L-Band Data

Reliable and accurate estimates of tropical forest above ground biomass (AGB) are important to reduce uncertainties in carbon budgeting. In the present study we estimated AGB of central Indian deciduous forests of Madhya Pradesh (M.P.) state, India, using Advanced Land Observing Satellite – Phased Array type L-band Synthetic Aperture Radar (ALOS-PALSAR) L-band data of year 2010 in conjunction with field based AGB estimates using empirical models. Digital numbers of gridded 1?×?1° dual polarization (HH & HV) PALSAR mosaics for the study area were converted to normalized radar cross section (sigma naught - σ⁰). A total of 415 sampling plots (0.1 ha) data collected over the study area during 2009–10 was used in the present study. Plot-level AGB estimates using volume equations representative to the study area were computed using field inventory data. The plot-level AGB estimates were empirically modeled with the PALSAR backscatter information in HH, HV and their ratios from different forest types of the study area. The HV backscatter information showed better relation with field based AGB estimates with a coefficient of determination (R²) of 0.509 which was used to estimate spatial AGB of the study area. Results suggested a total AGB of 367.4 Mt for forests of M.P. state. Further, validation of the model was carried out using observed vs. predicted AGB estimates, which suggested a root mean square error (RMSE) of ±19.32 t/ha. The model reported robust and defensible relation for observed vs. predicted AGB values of the study area.     

The October 4, 1994 Shikotan (Kurile Islands) Tsunamigenic Earthquake: An Open Problem on the Source Mechanism

—On October 4, 1994, an earthquake of magnitude M _w = 8.2 occurred in the western part of the Kurile Islands, generating a tsunami that has been well recorded along the entire coast of Japan. Previous works have shown that this earthquake does not represent a low angle thrust event, normally expected in a subduction zone, rather an intra-plate event rupturing through the slab. On the basis of the accepted mechanism, two fault models, representative of the nodal plane ambiguity, have been suggested. The goal of this work is to verify whether the tsunami simulations are able to rule out one of the two proposed fault models. Taking into account both fault models together with a heterogeneous slip along the fault, we have performed numerical simulations of the tsunami. All source models produce tide-gauge records in agreement with the observed ones. The limit of resolution of the performed simulations, estimated by means of a perturbed bathymetry, does not allow us to distinguish the best source model.     

Occurrence of hypogenic caves in a karst region: Examples from central Italy

The caves of the Umbria and Marche regions in central Italy are made up of three-dimensional maze systems that display different general morphologies due to the various geological and structural contexts. At the same time, the internal morphologies of the passages, galleries, and shafts present some similarity, with solutional galleries characterized by cupolas and blind pits, anastamotic passages, roof pendants, and phreatic passages situated at different levels. Some of these caves are still active, as is the case for Frassassi Gorge, Parrano Gorge, and Acquasanta Terme, with galleries that reach the phreatic zone, where there is a rising of highly mineralized water, rich in hydrosulfydric acid, and with erosion of limestone walls and the formation of gypsum. Elsewhere there are fossil caves, such as Monte Cucco and Pozzi della Piana, where large speleothems of gypsum are present 500 m or more above the regional water table. In all of these important karst systems it is possible to recognize basal input points through fracture and intergranular porosity networks at the base of the oxidizing zone in the core of the anticline, where mineralized water rises up from the Triassic evaporitic layers in small hydrogeological circuits. Different underground morphologies can derive from the presence of a water table related to an external stream or from the confined setting of the carbonate rocks, underlying low permeable sedimentary cover, where artesian conditions can occur.     

Mn-oxides and sequestration of heavy metals in a suburban catchment basin of the Chesapeake Bay watershed

The Chesapeake Bay is greatly impacted by numerous pollutants including heavy metals and understanding the controls on the distribution of heavy metals in the watershed is critical to mitigation and remediation efforts in controlling this type of pollution. Clasts from a stormwater catchment basin draining a subdivision near George Mason University, Fairfax VA (38°50.090°N 78°19.204°W) were investigated using X-ray diffraction (XRD), Scanning electron microcopy (SEM) and energy dispersive spectroscopy (EDS) to determine the nature of Mn-oxide coatings and relationship to bound heavy metals. Mn-oxides are poorly crystalline and occur as subhedral to anhedral platy particles and more rarely as euhedral plates. Micronodules are a commonly observed texture. Chemical compositions of coatings are variable with average major constituent concentrations being Mn (33.38 wt%), Fe (11.88 wt%), Si (7.33 wt%), Al (5.03 wt%), and Ba (0.90 wt%). Heavy metals are found in the coatings with Zn being most prevalent, occurring in approximately 58% of analyses with an average concentration of (0.66 wt%). Minor amounts of Co, Ni, Pb, and Cl are observed. Heavy metals and Cl are interpreted as being derived from road pollution. Mn-oxides can serve as a sequestration mechanism for pollution but may also release heavy metals. Field and laboratory observations indicate Mn-oxides occurring on the surface of the clasts can be mechanically mobilized. This is a mechanism for transporting heavy metals into the Chesapeake Bay watershed. Deicing agents may serve as a mechanism to release heavy metals through cation exchange and increased ionic strength. This is the first detailed mineralogical investigation of Mn-oxides and the roles they may play in pollution in the Chesapeake Bay.     

Analysis of vertical crustal movements in the period of the Kaliningrad earthquake of September 21, 2004 (from sea level data)

The paper analyzes data of leveling and meteorological observations conducted in the Kaliningrad region in the second half of September 2004, i.e., during a period including the few moderate seismic shocks of September 21, 2004. The analysis of long observation series and comparison of sea level variations recorded from September 15 through 30, 2004, with meteorological data have led to the conclusion that, most probably, the Sambiiskii Peninsula subsided tectonically by 25–30 cm over 12–24 h and a new sequence of seismic shocks occurred five to eight hours after the beginning of the subsidence. The geodynamic and prognostic aspects of the results obtained in this work are discussed.     

Community‐Derived Standards for LA‐ICP‐MS U‐(Th‐)Pb Geochronology – Uncertainty Propagation,Age Interpretation and Data Reporting

The LA‐ICP‐MS U‐(Th‐)Pb geochronology international community has defined new standards for the determination of U‐(Th‐)Pb ages. A new workflow defines the appropriate propagation of uncertainties for these data, identifying random and systematic components. Only data with uncertainties relating to random error should be used in weighted mean calculations of population ages; uncertainty components for systematic errors are propagated after this stage, preventing their erroneous reduction. Following this improved uncertainty propagation protocol, data can be compared at different uncertainty levels to better resolve age differences. New reference values for commonly used zircon, monazite and titanite reference materials are defined (based on ID‐TIMS) after removing corrections for common lead and the effects of excess ²³⁰Th. These values more accurately reflect the material sampled during the determination of calibration factors by LA‐ICP‐MS analysis. Recommendations are made to graphically represent data only with uncertainty ellipses at 2s and to submit or cite validation data with sample data when submitting data for publication. New data‐reporting standards are defined to help improve the peer‐review process. With these improvements, LA‐ICP‐MS U‐(Th‐)Pb data can be considered more robust, accurate, better documented and quantified, directly contributing to their improved scientific interpretation.