Characteristics of spectral aerosol optical depths over India during ICARB

Spectral aerosol optical depth (AOD) measurements, carried out regularly from a network of observatories spread over the Indian mainland and adjoining islands in the Bay of Bengal and Arabian Sea, are used to examine the spatio-temporal and spectral variations during the period of ICARB (March to May 2006). The AODs and the derived Ångström parameters showed considerable variations across India during the above period. While at the southern peninsular stations the AODs decreased towards May after a peak in April, in the north Indian regions they increased continuously from March to May. The Ångström coefficients suggested enhanced coarse mode loading in the north Indian regions, compared to southern India. Nevertheless, as months progressed from March to May, the dominance of coarse mode aerosols increased in the columnar aerosol size spectrum over the entire Indian mainland, maintaining the regional distinctiveness. Compared to the above, the island stations showed considerably low AODs, so too the northeastern station Dibrugarh, indicating the prevalence of cleaner environment. Long-range transport of aerosols from tshe adjoining regions leads to remarkable changes in the magnitude of the AODs and their wavelength dependencies during March to May. HYSPLIT back-trajectory analysis shows that enhanced long-range transport of aerosols, particularly from the west Asia and northwest coastal India, contributed significantly to the enhancement of AOD and in the flattening of the spectra over entire regions; if it is the peninsular regions and the island Minicoy are more impacted in April, the north Indian regions including the Indo Gangetic Plain get affected the most during May, with the AODs soaring as high as 1.0 at 500 nm. Over the islands, the Ångström exponent (α) remained significantly lower (～1) over the Arabian Sea compared to Bay of Bengal (BoB) (～1.4) as revealed by the data respectively from Minicoy and Port Blair. Occurrences of higher values of α, showing dominance of accumulation mode aerosols, over BoB are associated well with the advection, above the boundary layer, of fine particles from the east Asian region during March and April. The change in the airmass to marine in May results in a rapid decrease in α over the BoB.     

Integrated approach for identification of potential groundwater zones in Seethanagaram Mandal of Vizianagaram District,Andhra Pradesh,India

Identifying a good site for groundwater exploration in hard rock terrain is a challenging task. In hard rocks, groundwater occurs in secondary porosity developed due to weathering, fracturing, faulting, etc., which is highly variable within short distance and contributing to near-surface inhomogeneity. In such situations topographic, hydrogeological and geomorphological features provide useful clues for the selection of suitable sites. Initially, based on satellite imagery, topographical, geomorphological and hydrogeological features, an area of about 149 km² was demarcated as a promising zone for groundwater exploration in the hard rock tract of Seethanagaram Mandal, Vizianagaram District, Andhra Pradesh, India. A total of 50 Vertical Electrical Soundings (VES) were carried out using Wenner electrode configuration. An interactive interpretation of the VES data sharpened the information inferred from geomorphological and hydrogeological reconnaissance. Ten sites were recommended for drilling. Drilling with Down-The-Hole Hammer (DTH) was carried out at the recommended sites down to 50 to 70 m depths. The interpreted VES results matched well with the drilled bore well lithologs. The yields of bore wells vary from 900 to 9000 liters per hour (lph).     

The WRF model performance for the simulation of heavy precipitating events over Ahmedabad during August 2006

The summer monsoon season of the year 2006 was highlighted by an unprecedented number of monsoon lows over the central and the western parts of India, particularly giving widespread rainfall over Gujarat and Rajasthan. Ahmedabad had received 540.2mm of rainfall in the month of August 2006 against the climatological mean of 219.8mm. The two spells of very heavy rainfall of 108.4mm and 97.7mm were recorded on 8 and 12 August 2006 respectively. Due to meteorological complexities involved in replicating the rainfall occurrences over a region, the Weather Research and Forecast (WRF-ARW version) modeling system with two different cumulus schemes in a nested configuration is chosen for simulating these events. The spatial distributions of large-scale circulation and moisture fields have been simulated reasonably well in this model, though there are some spatial biases in the simulated rainfall pattern. The rainfall amount over Ahmedabad has been underestimated by both the cumulus parameterization schemes. The quantitative validation of the simulated rainfall is done by calculating the categorical skill scores like frequency bias, threat scores (TS) and equitable threat scores (ETS). In this case the KF scheme has outperformed the GD scheme for the low precipitation threshold.     

Intriguing climatic shifts in a 90 kyr old lake record from northern Russia

A 22 m long sediment core from Lake Yamozero on the Timan Ridge in northern Russia has provided evidence of intriguing climatic shifts during the last glacial cycle. An overall shallowing of the lake is reflected in the lower part of the cores, where pollen indicates a transition from glacial steppe vegetation to interstadial shrub-tundra. These beds are capped by a well-defined layer of compact clay deposited in relatively deep water, where pollen shows surrounding spruce forests and warmer-than-present summer temperatures. The most conservative interpretation is that this unit represents the last interglacial period. However, a series of Optical Stimulated Luminescence (OSL) dates suggests that it corresponds with the Early Weichselian Odderade interstadial (MIS 5a). This would imply that the Odderade interstadial was just as warm as a normal interglacial in this continental part of northern Europe. If correct, then pollen analysis, as a correlation tool, is less straightforward and the definition of an interglacial is more complex than previously thought. We discuss the validity and possible systematic errors of the OSL dates on which this age model is based, but conclude they really indicate a MIS 5a age for the warm period. Above the clay is an unconformity, most likely reflecting a period of subaerial exposure implying dry conditions. Deposition of silt under fluctuating cold climates in the Middle Weichselian continued until a second gap in the record at c . 40 kyr BP. The lake basin started to fill up again around 18 kyr BP.     

Three-dimensional discontinuous deformation analysis (3-D DDA) using a new contact resolution algorithm

This paper presents a new contact calculating algorithm for contacts between two polyhedra with planar boundaries in the three-dimensional discontinuous deformation analysis (3-D DDA). In this algorithm, all six type contacts in 3-D (vertex-to-face, vertex-to-edge, vertex-to-vertex, face-to-face, edge-to-edge, and edge-to-face) are simply transformed into the form of point-to-face contacts. The presented algorithm is a simple and efficient method and it can be easily coded into a computer program. In this paper, formulations of normal contact, shear contact and frictional force submatrices based on the new method are derived and the algorithm has been programmed in VC⁺⁺. Examples are provided to demonstrate the new contact rule between two blocks.     

Deciphering potential groundwater zone in hard rock through the application of GIS

Remote Sensing and Geographic Information System has become one of the leading tools in the field of hydrogeological science, which helps in assessing, monitoring and conserving groundwater resources. It allows manipulation and analysis of individual layer of spatial data. It is used for analysing and modelling the interrelationship between the layers. This paper mainly deals with the integrated approach of Remote Sensing and geographical information system (GIS) to delineate groundwater potential zones in hard rock terrain. The remotely sensed data at the scale of 1:50,000 and topographical information from available maps, have been used for the preparation of ground water prospective map by integrating geology, geomorphology, slope, drainage-density and lineaments map of the study area. Further, the data on yield of aquifer, as observed from existing bore wells in the area, has been used to validate the groundwater potential map. The final result depicts the favourable prospective zones in the study area and can be helpful in better planning and management of groundwater resources especially in hard rock terrains.     

The relationship between hydrodynamic properties and weathering of soils derived from volcanic rocks,Galapagos Islands (Ecuador)

The aim of this interdisciplinary study is to examine a component of the hydrological cycle in Galapagos by characterizing soil properties. Nine soil profiles were sampled on two islands. Their physical and hydrodynamic properties were analyzed, along with their mineralogical composition. Two groups of soils were identified, with major differences between them. The first group consists of soils located in the highlands (>350 m a.s.l.), characterized by low hydraulic conductivity (<10⁻⁵ m s⁻¹) and low porosity (<25%). These soils are thick (several meters) and homogeneous without coarse components. Their clay fraction is considerable and dominated by gibbsite. The second group includes soils located in the low parts of the islands (<300 m a.s.l.). These soils are characterized by high hydraulic conductivity (>10⁻³ m s⁻¹) and high porosity (>35%). The structure of these soils is heterogeneous and includes coarse materials. The physical properties of the soils are in good agreement with the variations of the rainfall according to the elevation, which appears as the main factor controlling the soil development. The clayey alteration products constrain soils physical and hydrodynamic properties by reducing the porosity and consequently the permeability and also by increasing water retention.     

Chrome-spinels in serpentinites and talc carbonates of the El Ideid-El Sodmein District, central Eastern Desert, Egypt: their metamorphism and petrogenetic implications

Serpentinites and talc-carbonate rocks of El Ideid-El Sodmein District (ISD), central Eastern Desert, Egypt, contain variably altered chrome-spinels. Back-scattered electron images and electron microprobe analyses of chrome-spinels and associated silicates are made to evaluate their textural and compositional variations with metamorphism. In most cases the chrome-spinel crystals are concentrically zoned with unaltered cores through transitional zone of ferritchromit to Cr-magnetite toward the rims. In talc-carbonate rocks chrome-spinels are extensively altered to Cr-magnetite. Compared to cores, the metamorphic rims are enriched in Cr# (0.83–1.0 vs. 0.58–0.63 for rims and cores, respectively) and impoverished in Mg# (0.05–0.29 vs. 0.57–0.63), due to Mg–Fe and Al(Cr)–Fe³⁺ exchange with the surrounding silicates during regional metamorphism rather than serpentinization process. Textural and compositional features of the chrome-spinels suggest transitional greenschist-amphibolite up to lower amphibolite facies metamorphism (at 500–600 °C), which is isofacial with the country rocks. The common preservation of unaltered chrome-spinel cores in the serpentinites, contrary to talc-carbonate rocks, implies that full equilibration has not been attained due to small metamorphic fluid–rock ratio. Microprobe analyses profile across a concentrically zoned grain confirms the presence of two compositional (miscibility?) gaps; one between chrome-spinel core and ferritchromit zone; and another one between ferritchromit zone and Cr-magnetite outer rim.Chrome-spinel cores do not appear to have re-equilibrated completely with the metamorphic spinel rims and surrounding silicates, indicating relic magmatic composition not affected by metamorphism. Core compositions suggest an ophiolitic origin and derivation by high degrees of melting of reduced, depleted harzburgite to dunite mantle peridotites in an oceanic supra-subduction zone (marginal-basin) tectonic environment.     

Application of precise 142Nd/144Nd analysis of small samples to inclusions in diamonds (Finsch,South Africa) and Hadean Zircons (Jack Hills,Western Australia)

¹⁴⁶Sm–¹⁴²Nd and ¹⁴⁷Sm–¹⁴³Nd systematics were investigated in garnet inclusions in diamonds from Finsch (S. Africa) and Hadean zircons from Jack Hills (W. Australia) to assess the potential of these systems as recorders of early Earth evolution. The study of Finsch inclusions was conducted on a composite sample of 50 peridotitic pyropes with a Nd model age of 3.3 Ga. Analysis of the Jack Hills zircons was performed on 790 grains with ion microprobe ²⁰⁷Pb/²⁰⁶Pb spot ages from 3.95 to 4.19 Ga. Finsch pyropes yield 100 × ?¹⁴²Nd = ? 6 ± 12 ppm, ?¹⁴³Nd = ? 32.5, and ¹⁴⁷Sm/¹⁴⁴Nd = 0.1150. These results do not confirm previous claims for a 30 ppm ¹⁴²Nd excess in South African cratonic mantle. The lack of a ¹⁴²Nd anomaly in these inclusions suggests that isotopic heterogeneities created by early mantle differentiation were remixed at a very fine scale prior to isolation of the South African lithosphere. Alternatively, this result may indicate that only a fraction of the mantle experienced depletion during the first 400 Myr of its history. Analysis of the Jack Hills zircon composite yielded 100 × ?¹⁴²Nd = 8 ± 10 ppm, ?¹⁴³Nd = 45 ± 1, and ¹⁴⁷Sm/¹⁴⁴Nd = 0.5891. Back-calculation of this present-day ?¹⁴³Nd yields an unrealistic estimate for the initial ?¹⁴³Nd of ? 160 ?-units, clearly indicating post-crystallization disturbance of the ¹⁴⁷Sm–¹⁴³Nd system. Examination of ^146,147Sm–^142,143Nd data reveals that the Nd budget of the Jack Hills sample is dominated by non-radiogenic Nd, possibly contained in recrystallized zircon rims or secondary subsurface minerals. This secondary material is characterized by highly discordant U–Pb ages. Although the mass fraction of altered zircon is unlikely to exceed 5–10% of total sample, its high LREE content precludes a reliable evaluation of ¹⁴⁶Sm–¹⁴²Nd systematics in Jack Hills zircons.     

A transdisciplinary analysis of water problems in the mountainous karst areas of Morocco

Water management and engineering in the karstic High Atlas of Morocco are difficult tasks under the prevailing geological, hydrogeological, geomorphological, vegetational and climatic conditions. It is important to be able to understand and predict the characteristics and availability of water for future water planning in the region under changing climatic and agricultural conditions. An interdisciplinary analysis of problems and adequate hydrological modelling tools developed by geologists, hydrologists and biologists are necessary. The karst areas of the High Atlas Mountains are characterised by impermeable triassic basalt underlying substantial subsurface reservoirs with high potential discharge rates. The karst groundwater aquifers are extensive but largely unknown in dimension, probably with a hierarchical network of groundwater flow paths. It is estimated that approximately 70% of the surface water is directly lost to groundwater. Steep landslide- and debris flow prone slopes exist next to coarse-grained, highly porous river beds. Infrequent, high intensity rainfall or snowmelt causes a particularly high flood risk to these karst areas. In addition, agriculture and land use changes have degraded the karst areas. The most important driving forces for degradation include permanent overgrazing even during droughts and the use of firewood by a continually growing population. Large scale degradation of vegetation has occurred in the oro-mediterranean (mountainous Mediterranean) zone, between 2600 and 3400 m which coincides with the most important zone for karstic groundwater creation. The combination of high amounts of groundwater flow and rapid surface flow due to sparse vegetation has increased the problems of flood flow.