Fluid infiltration during contact metamorphism of interbedded marble and calc-silicate hornfels, Twin Lakes area, central Sierra Nevada, California

Abstract In the Twin Lakes area, central Sierra Nevada, California, most contact metamorphosed marbles contain calcite + dolomite + forsterite ± diopside ± phlogopite ± tremolite, and most calc-silicate hornfelses contain calcite + diopside + wollastonite + quartz ± anorthite ± K-feldspar ± grossular ± titanite. Mineral-fluid equilibria involving calcite + dolomite + tremolite + diopside + forsterite in two marble samples and wollastonite + anorthite + quartz + grossular in three hornfels samples record P± 3 kbar and T± 630° C. Various isobaric univariant assemblages record CO₂-H₂O fluid compositions of χCO₂= 0.61–0.74 in the marbles and χCO₂= 0.11 in the hornfelses. Assuming a siliceous dolomitic limestone protolith consisting of dolomite + quartz ° Calcite ± K-feldspar ± muscovite ± rutile, all plausible prograde reaction pathways were deduced for marble and hornfels on isobaric T-XCO₂ diagrams in the model system K₂O-CaO-MgO-Al₂O₃-SiO₂-H₂O-CO₂. Progress of the prograde reactions was estimated from measured modes and mass-balance calculations. Time-integrated fluxes of reactive fluid which infiltrated samples were computed for a temperature gradient of 150 °C/km along the fluid flow path, calculated fluid compositions, and estimated reaction progress using the mass-continuity equation. Marbles and hornfelses record values in the range 0.1–3.6 × 10⁴ cm³/cm² and 4.8–12.9 × 10⁴ cm³/cm², respectively. For an estimated duration of metamorphism of 10⁵ years, average in situ metamorphic rock permeabilities, calculated from Darcy's Law, are 0.1–8 × 10^?6 D in the marbles and 10–27 × 10^?6 D in the hornfelses. Reactive metamorphic fluids flowed up-temperature, and were preferentially channellized in hornfelses relative to the marbles. These results appear to give a general characterization of hydrothermal activity during contact metamorphism of small pendants and screens (dimensions ± 1 km or less) associated with emplacement of the Sierra Nevada batholith.     

A laboratory test of the soil chemical submodels of two models of catchment acidification

Parameters for ion exchange selectivity and aluminium hydroxide dissolution in the soil chemical submodels used in applications of the Birkenes model and of MAGIC are compared and several discrepancies identified for organic soils. A laboratory column simulation of the soil chemical submodels is proposed and applied to soils from the Loch Dee area in Galloway. Experimental results were well predicted by a simplified version of MAGIC, with ion exchange selectivity parameters similar to those used in a previous simulation of one subcatchment of Loch Dee. The aluminium hydroxide dissolution parameter used previously was found to be too low for the organic soil materials, where a value of 106 predicted the experimental results more closely. The model developed also included a simple silicate weathering reaction to release base cations into the system. It is concluded that such simple laboratory simulations are useful for independent calibration of the soil chemical submodel of catchment models.     

P-T-t-deformation paths recorded by kinzigites during diapirism in the western Variscan belt (Golfe du Morbihan, southern Brittany, France)

Abstract The high-grade metamorphic rocks of southern Brittany underwent a complex tectonic evolution under various P-T conditions (high-P, high-T), related to stacking of nappes during Palaeozoic continentcontinent collision. The east to west thrusting observed in the whole belt is strongly perturbed by vertical movements attributed to the ascent of anatectic granites in the high-T area. The field reconstruction of subvertical, closed elliptical structures in gneisses and migmatites, associated with the subhorizontal, doubly radial pattern of stretching lineation in the mica schists, suggests the existence of an elliptical diapiric body buried at depth beneath the present erosion level. Deformation is associated with a complex P-T evolution partly recorded in aluminous gneisses (kinzigites, e.g. morbihanites). A chronology of successive episodes of mineral growth at different compositions is established by detailed studies of the mineral-microstructure relationships in X-Z sections, using the deformation-partitioning concept (low- and high-strain zones). Several thermometric and barometric calibrations are applied to mineral pairs either in contact or not in contact but in equivalent microstructiiral positions with respect to the deformation history. This methodology provides a continuous microstructural control of P-T variations through time and leads to three P-T-t-d paths constructed from numerous successive P-T estimations. Path 1 is a clockwise retrograde path preserved in low-strain zones, which records general exhumation movements after crustal thickening. Paths 2 and 3 are clockwise prograde/retrograde paths from high-strain zones; they are interpreted and discussed in the light of models of crustal anatexis and upward movement of magma (diapirism). Deformation and P-T effects induced by diapirism can be distinguished from the general deformation-metamorphic history of a belt, and would seem to be produced during a late stage of its history. The present microstructural-petrological approach to defining successive mineral equilibria in relation to progressive deformation steps provides a far more accurate evaluation of the metamorphic evolution than is possible by ‘standard’thermobarometry.     

Deglaciation of the younger dryas or Loch Lomond Stadial ice-field in the northern Highlands,Scotland

When viewed from the air, Scottish ‘hummocky moraine’ can be resolved into a series of linear ridges that resemble those found at the margins of actively retreating glaciers today. Recent work has supported the interpretation of these linear ridges as ice-marginal landforms and the authors believe that the majority of ‘hummocky moraine’ deposits can be interpreted in this way. Consequently the pattern of deglaciation can be established fairly precisely from the pattern of linear ridges. This approach is applied to the landforms of the northern part of the Loch Lomond Stadial ice-field in order to reconstruct the regional pattern of deglaciation. This leads to important inferences about the significance of topographic control during deglaciation and more importantly it provides fresh insight into the environment of the British Isles during the Loch Lomond Stadial.     

Basic phase relations of polybaric batch, percolative and critical melting

Summary ?Partial melting of the mantle is polybaric which implies that the phase relations change during partial melting. In addition to the pressure the composition of the melt depends on the melting mode. Various melting models have been suggested. Here the basic phase relations of polybaric batch, percolative, and critical melting are considered, using a simple ternary system. The percolative melts are in equilibrium with their residua, but differ somewhat in composition from those of batch melting. Critical melting is a fractional type of melting where the residuum contain interstitial melt. The critical melts differ in composition from batch melts. The linear trends of peridotites from ophiolites show that the extracted melts had nearly constant compositions, and therefore were extracted within a small pressure interval. A comparison between the trends of mantle peridotite and experimental batch melts suggests strongly that the melt extracted from the peridotites are in equilibrium with their residua. This could suggest that either batch or percolative melting are relevant melting modes for the mantle. However, isotopic disequilibria favor instead a critical mode of melting. This inconsistency can be avoided if the ascending melts are accumulated within a source region and equilibrate with the residuum before the melt is extracted from the source region. The evidence for equilibrium suggests that multisaturation of tholeiitic compositions in PT-diagrams is relevant for estimating pressure and temperature of generation of primary tholeiitic magmas. Received September 2, 2001; revised version accepted March 20, 2002     

Contribution of storms to groundwater recharge in the semi‐arid region of Karnataka,India

This paper describes the application of environmental isotopes and injected tracer techniques in estimating the contribution of storms as well as annual precipitation to groundwater recharge and its circulation, in the semi‐arid region of Bagepalli, Kolar district, Karnataka. Environmental isotopes ²H, ¹⁸O and ³H were used to study the effect of storms on the hydrological system, and an isotope balance was used to compute the contribution of a storm component to the groundwater. Some of the groundwater samples collected during the post‐storm periods were highly depleted in stable isotope content with higher deuterium excess relative to groundwater from the pre‐storm periods. Significant variation in deuterium excess in groundwater from the same area, collected in two different periods, indicates the different origin of air masses. The estimated recharge component of a storm event of 600 mm to the groundwater was found to be in the range of 117–165 mm. There was no significant variation in environmental tritium content of post‐storm and pre‐storm groundwater, indicating the fast circulation of groundwater in the system. After completion of the environmental isotope work, an injected radiotracer ³H technique was applied to estimate the direct recharge of total precipitation to the groundwater. The estimated recharge to the groundwater is 33 mm of the 550 mm annual precipitation during 1992. Copyright © 2003 John Wiley & Sons, Ltd.     

Himalayan magmatism and porphyry copper–molybdenum mineralization in the Yulong ore belt, East Tibet

Summary ?The NW–SE-trending Yulong porphyry Cu–Mo ore belt, situated in the Sanjiang0 area of eastern Tibet, is approximately 400 km long and 35 to 70 km wide. Complex tectonic and magmatic processes during the Himalayan epoch have given rise to favorable conditions for porphyry-type Cu–Mo mineralization. Porphyry masses of the Himalayan epoch in the Yulong ore belt are distributed in groups along regional NW–SE striking tectonic lineaments. They were emplaced mainly into Triassic and Lower Permian sedimentary-volcanic rocks. K–Ar und U–Pb isotopic datings give an intrusion age range of 57–26 Ma. The porphyries are mainly of biotite monzogranitic and biotite syenogranitic compositions. Geological and geochemical data indicate that the various porphyritic intrusions in the belt had a common or similar magma source, are metaluminous to peraluminous, Nb–Y–Ba-depleted, I-type granitoids, and belong to the high-K calc-alkaline series. Within the Yulong subvolcanic belt a number of porphyry stocks bear typical porphyry type Cu–Mo alteration and mineralization. The most prominent porphyry Co–Mo deposits include Yulong, Malasongduo, Duoxiasongduo, Mangzong and Zhanaga, of which Yulong is one of the largest porphyry Cu (Mo) deposits in China with approximately 8 × 10⁶ tons of contained Cu metal. Hydrothermal alteration at Yulong developed around a biotite–monzogranitic porphyry stock that was emplaced within Upper Triassic limestone, siltstone and mudstone. The earliest alteration was due to the effects of contact metamorphism of the country rocks and alkali metasomatism (potassic alteration) within and around the porphyry body. The alteration of this stage was accompanied by a small amount of disseminated and veinlet Cu–Mo sulfide mineralization. Later alteration–mineralization zones form more or less concentric shells around the potassic zone, around which are distributed a phyllic or quartz–sericite–pyrite zone, a silicification and argillic zone, and a propylitic zone. Fluid inclusion data indicate that three types of fluids were involved in the alteration–mineralization processes: (1) early high temperature (660–420 °C) and high salinity (30–51 wt% NaCl equiv) fluids responsible for the potassic alteration and the earliest disseminated and/or veinlet Cu–Mo sulfide mineralization; (2) intermediate unmixed fluids corresponding to phyllic alteration and most Cu–Mo sulfide mineralization, with salinities of 30–50 wt% NaCl equiv and homogenization temperatures of 460–280 °C; and (3) late low to moderate temperature (300–160 °C) and low salinity (6–13 wt% NaCl equiv) fluids responsible for argillic and propylitic alteration. Hydrogen and oxygen isotopic studies show that the early hydrothermal fluids are of magmatic origin and were succeeded by increasing amounts of meteoric-derived convective waters. Sulfur isotopes also indicate a magmatic source for the sulfur in the early sulfide mineralization, with the increasing addition of sedimentary sulfur outward from the porphyry stock. Received August 29, 2001; revised version accepted May 1, 2002 Published online: November 29, 2002