Monitoring of rapid salt weathering in the central Namib Desert using limestone blocks

Pre-weighed blocks of a Jurassic Limestone were exposed on the ground surface in the coastal Namib Desert for a period of 2 years. The environment is both salty and foggy. Some of the blocks suffered extensive disintegration, and laboratory analyses (including geochemistry, XRD and SEM) indicate that the weathered samples have a high halite (sodium chloride) content. Cycles of wetting and drying associated with the frequent fog events of the area cause cycles of halite crystallization. Rocks exposed at the surface absorb salts from the surrounding desert surface and then disintegrate, contributing to planation of the landscape.     

Seismic anisotropy within the uppermost mantle of southern Germany

This paper presents an updated interpretation of seismic anisotropy within the uppermost mantle of southern Germany. The dense network of reversed and crossing refraction profiles in this area made it possible to observe almost 900 traveltimes of the P_n phase that could be effectively used in a time-term analysis to determine horizontal velocity distribution immediately below the Moho. For 12 crossing profiles, amplitude ratios of the P_n phase compared to the dominant crustal phase were utilized to resolve azimuthally dependent velocity gradients with depth. A P -wave anisotropy of 3–4 per cent in a horizontal plane immediately below the Moho at a depth of 30 km, increasing to 11 per cent at a depth of 40 km, was determined. For the axis of the highest velocity of about 8.03 km s⁻¹ at a depth of 30 km a direction of N31°F was obtained. The azimuthal dependence of the observed P_n amplitude is explained by an azimuth-dependent sub-Moho velocity gradient decreasing from 0.06 s⁻¹ in the fast direction to 0 s⁻¹ in the slow direction of horizontal P -wave velocity. From the seismic results in this study a petrological model suggesting a change of modal composition and percentage of oriented olivine with depth was derived.     

Multifractal analysis of the spatial distribution of earthquakes in southern Italy

We evaluate the complete spectrum of the generalized fractal dimension of the spatial pattern of microearthquakes in Southern Italy, revealing a multifractal distribution structure. Our analysis is focused on the dependence of the multifractal distribution on the size of the selected area and the kind of seismicity in the area. As the size of the window varies, we observe that the capacity, information and correlation dimensions vary significantly, while both d _∞ and d _−infin; remain unchanged within their errors limits. We interpret this result in terms of the observation that our data are mainly clustered around a linear fault (the Sisifo fault). When we restrict the selected windows around the fault, clustering around a line (the fault) is highlighted. The capacity dimension changes from about 1.8 to about 1.4 and the correlation dimension decreases because we observe in detail the clustering of the seismicity along the fault, which approximates the maximum intense clustering of the whole data set. Although our results are strongly influenced by the fact that the data are dominated by the epicentres located on the fault, we can conclude that multifractal analysis can be a very useful tool to discriminate the seismicity linked to a particular fault in a given area.     

Distribution and morphology of sinkholes triggered by flooding following Tropical Storm Alberto at Albany, Georgia, USA

Flooding of the Flint River in July 1994 triggered the collapse of at least 312 sinkholes in the karstic Dougherty Plain at Albany, Georgia. We examined the distribution and morphology of these new sinkholes to evaluate the mode of formation, to characterize early stages of the evolution of sinkhole form, and to estimate the lowering of the surface associated with the development of new sinkholes.Eighty-eight percent of sinkholes occur inside the limits of flooding, especially in areas of sandy overburden, and they often follow joint-controlled linear trends. Sinkhole dimensions are log-normally distributed with median values of circumference = 5.7 m, length = 1.8 m, width = 1.6 m, and depth = 0.7 m; asymmetry (L:W) = 1.2. Cross-sectional forms range from narrow cylinders to large bowls, with many sinkholes having undercut sides.Flooding triggered the formation of sinkholes by saturating and liquefying overburden, which caused soil arches to collapse and flow into cavities in bedrock. The prevalence of sinkholes near the periphery of flooding suggests that drainage and loss of buoyant support as flood waters subsided may also have contributed to failure. A volume ratio index is used to quantify the three dimensional geometric form of sinkholes. Initially, small cylindrical shafts open over a bedrock joint, followed by progressive slumping that leads to widening and increases in volume to a final bowl form. Estimates of the aggregate volume of overburden transported underground in flooded areas range from 7,990 to 11,130 m3. Averaged over flooded areas, this accounts for 0.26 to 0.37 mm/km² lowering of the surface. Based on a 500 year recurrence interval for the flood event, values for lowering of the surface range from 0.52 to 0.74 mm per 1,000 years. These values are an order of magnitude less than estimates of carbonate dissolution and suggest that transport of overburden underground is limited by triggering events.     

Experimental determination of the solubility of Au in silicate melts

Summary We report here new data on the solubility of Au in silicate melts of anorthite-diopside eutectic composition at a wide range of oxygen fugacities, from pure oxygen to 10^–8 atm, and at a temperature range of 1300 °C to 1480 °C. Because experiments were done with metal loops at temperatures above the Au-melting temperature, PdAu-metal-alloys had to be used. Pd-solubility data derived from the same set of experiments agree with earlier data obtained from experiments with pure Pd-metal (Borisov et al., 1994a). The results of the present experiments show that Pd-solubilities are by a factor of 2 to 6 higher than Au-solubilities. Both, Au and Pd solubilities decrease with decreasing oxygen fugacity. At oxygen fugacities below the iron-wiistite buffer (IW) Au solubility increases with decreasing fO₂ probably reflecting formation of Au-silicides at such reducing conditions. Compared to Pd, Au has higher activity coefficients in Fe-metal and lower solubility in silicate melts. This leads to similar metal-silicate partition coefficients for both elements. At a temperature of 1350 °C and an oxygen fugacity corresponding to IW-2 D^Au (met/sil) is about 2.5 · 10⁷ and D^Pd (met/sil) about 1.6 · 10⁷. Thus similar behavior is expected during metal separation in planetary bodies including core formation in the Earth. The metal/silicate partition coefficient of Ir is, however, by several orders of magnitudes higher (Borisov and Palme, 1995a). Equilibration with chondritic metal will therefore lead to grossly non-chondritic Pd/Ir or Au/Ir ratios in coexisting silicate phases. Chondritic ratios are thus indicative of the presence of unfractionated meteoritic components. Samples from the upper mantle of the Earth, for example, reflect the admixture of a late unfractionated (chondritic) veneer (e.g.,Kimura et al., 1974;Jagoutz et al., 1979).Solubilities of Pd and Au in silicate melts are much higher than the contents in terrestrial basalts implying that the abundances of these two elements are not buffered by residual PGE- and Au-containing alloys. The most likely process for fractionating PGEs in terrestrial magmas are mineral-melt (e.g., olivine/melt) equilibria.

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Experimentelle Bestimmung der Löslichkeit von Au in Silikatschmelzen

Zusammenfassung In der vorliegenden Arbeit wird über die Ergebnisse der Bestimmung der Löslichkeit von Au in Silikatschmelzen mit der Zusammensetzung des Anorthit-Diopsid Eutektikums berichtet. Die Versuche wurden mittels Metallschlaufe über einen weiten Sauerstoffpartialdruckbereich, von reinem Sauerstoff bis zu 10^–8 atm und in einem Temperaturbereich von 1300 °C bis 1480 °C, durchgeführt. Da diese Temperaturen jedoch den Au-Schmelzpunkt überschreiten, wurde mit AuPd-Legierungen gearbeitet. Die Ergebnisse der dadurch zusätzlich erhaltenen Pd-Versuche stimmen mit früher bestimmten, mit reinen Pd-Schlaufen durchgeführten Pd-Löslichkkeiten überein (Borisov et al., 1994a). Die auf reine Metalle zurückgerechneten Löslichkeiten von Pd sind um einen Faktor 2 bis 6 mal höher als die entsprechenden Au-Löslichkeiten. Die Löslichkeiten beider Metalle nehmen mit abnehmendem Sauerstoffpartialdruck ab. Unter noch stärker reduzierenden Bedingungen (Eisen-Wüstit Gleichgewicht) nimmt die Löslichkeit von Au jedoch zu. Dies könnte auf die Bildung von Au-Siliziden zurückzuführen sein.Im Vergleich zu Pd sind die Aktivitätskoeffizienten von Au in metallischem Eisen höher, die Löslichkeiten in Silikatschmelzen jedoch niedriger. Das führt zu ähnlichen Metall/Silikat Verteilungskoeffizienten von Au und Pd. Bei einer Temperatur von 1350 °C und einer Sauerstoffugazität von IW-2 ergeben sich für D^Au (met/sil) 2.5 · 10⁷ und für D^Pd (met/sil) 1.6* 10⁷. Der Metall/Silikat-Verteilungskoeffizient von Ir ist jedoch unter den gleichen Bedingungen um mehrere Größenordnungen höher (Borisov andPalme, 1995a). Ein chondritisches Pd/Ir- oder Au/Ir-Verhältnis kann also auf die Anwesenheit einer unfraktionierten chondritischen Komponente zurückgeführt werden. Dies gilt beispielsweise für Proben aus dem oberen Erdmantel. Hier handelt es sich vermutlich um Zumischung einer späten chondritischen Akkretionskomponente, die sich nicht mehr mit einer metallischen Phase (Kern) ins Gleichgewicht gesetzt hat (z.B.Kimura et al., 1974,Jagoutz et al., 1979).Die Löslichkeiten von Pd und Au in Silikatschmelzen sind wesentlich höher als ihre Gehalte in basaltischen und komatiitischen Laven. Dies bedeutet, daß Au und Pd in Schmelzen aus dem Erdmantel nicht durch residuale Au- und/oder Pd-haltige Metall phasen bestimmt sind. Gleichgewichte zwischen Schmelze und Mineralen (z.B. Olivin) sind die wahrscheinlichsten Fraktionierungsmechanismen für Platingruppenelemente in terrestrischen Magmen.

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With 5 Figures