Geology and geochemistry of lavas at Nekoma volcano: Implications for origin of Quaternary low-K andesite in the north-eastern Honshu arc, Japan

Abstract Nekoma volcano forms part of the arc axis volcanic array of the North-eastern Honshu arc, Japan, which is commonly characterized by medium-K lava suites. However, Nekoma is exceptional because many of its lavas are low-K. This anomaly has been a matter of debate. Nekoma was active from 1.1 to 0.35 Ma. The volcano consists of thick andesite flows and domes associated with block and ash flow deposits produced during lava dome formation. A horseshoe-shaped collapse caldera was formed at the summit and small lava domes extruded into the caldera. Stratigraphy, published K–Ar ages, and tephrochronology define three stages of volcanic activity, about 1.1 Ma (Stage 1), 0.8–0.6 Ma (Stage 2) and 0.45–0.35 Ma (Stage 3; post caldera stage). Low-K andesites occur in all stages. Extremely low-K andesite was also associated in Stage 2 and medium-K andesite was dominant in Stage 3. In general, lavas changed from low-K to medium-K after caldera formation. Geochemical study of the Nekoma lavas shows that both low-K and medium-K lavas are isotopically similar and were derived from a common source. Adatara and Azuma volcanoes, which lie close to Nekoma, also have both low-K and medium-K andesites. However, Sr isotope ratios or temporal-spatial variations in K-level lava classification vary between the three centers. Comparisons of K suites and Sr isotope ratios with frontal arc volcanoes in North-east–Honshu suggest source heterogeneity existed in both medium- and low-K suites. The K contents of lavas and their Sr isotopes are not simply related. This requires re-examination of models for chemical variation of andesites in arcs.     

Crystallization of chondrules in ordinary chondrites

The process of crystallization and the origin of chondrules are discussed, in terms of the phase relations of the minerals in chondrules in six ordinary chondrites of the Yamato-74 meteorites, especially the Yamato-74191 (L3).Chondrules are classified into six types. The bulk compositions of chondrules projected onto the MgO-FeO-SiO₂ system show that the compositions of chondrules vary widely. Investigations by means of the MgO-Al₂O₃-SiO₂ system indicate that porphyritic chondrules can be regarded as products of supercooling crystallization. The growth rates of crystals in porphyritic chondrules were fairly small. The difference between types of chondrules is interpreted in terms of the compositions of chondrules and the nucleation temperatures of the supercooled droplets.All these observations and estimations must be taken into account for discussing the origin of chondrules. The impact and dust fusion theories do not appear to be plausible. Molten droplets due to these mechanisms will be glassy spherules, or crystallize at equilibrium. Only a liquid condensation theory can well explain the characteristic features and the process of the crystallization of chondrules.     

Cretaceous episodic growth of the Japanese Islands

Abstract The Japanese Islands formed rapidly in situ along the eastern Asian continental margin in the Cretaceous due to both tectonic and magmatic processes. In the Early Cretaceous, huge oceanic plateaus created by the mid-Panthalassa super plume accreted with the continental margin. This tectonic interaction of oceanic plateau with continental crust is one of the significant tectonic processes responsible for continental growth in subduction zones. In the Japanese Islands, Late Cretaceous-Early Paleogene continental growth is much more episodic and drastic. At this time the continental margin uplifted regionally, and intra-continent collision tectonics took place in the northern part of the Asian continent. The uplifting event appears to have been caused by the subduction of very young oceanic crust (i.e. the Izanagi-Kula Plate) along the continental margin. Magmatism was also very active, and melting of the young oceanic slab appears to have resulted in ubiquitous plutons in the continental margin. Regional uplift of the continental margin and intra-continent collision tectonics promoted erosion of the uplifted area, and a large amount of terrigenous sediment was abruptly supplied to the trench. As a result of the rapid supply of terrigenous detritus, the accretionary complexes (the Hidaka Belt in Hokkaido and the Shimanto Belt in Southwest Japan) grew rapidly in the subduction zone. The rapid growth of the accretionary complexes and the subduction of very young, buoyant oceanic crust caused the extrusion of a high-P/T metamorphic wedge from the deep levels of the subduction zone. Episodic growth of the Late Cretaceous Japanese Islands suggests that subduction of very young oceanic crust and/or ridge subduction are very significant for the formation of new continental crust in subduction zones.     

Effect of the contraction of Zn-O bonds on X-ray emission spectra

Physics and Chemistry of Minerals - The X-ray emission spectra were measured for tetrahedrally coordinated Zn ion in several synthetic compounds. Intensity ratios of L β and L α spectral...     

Blocking in periodic valleys

Results are presented from a study of blocked flow (practically stagnant or recirculating light winds) in periodic valleys in thermally stably stratified ambient conditions. Inviscid and turbulent diffusion cases were modelled numerically to clarify the effects of turbulence on the blocking. The reflection of gravity waves from the top boundary of the hydrostatic model atmosphere was avoided by employing the radiation condition given by Klemp and Durran (1983). The dissipative numerical results are compared with new laboratory experiments which utilized the technique of Baines and Hoinka (1985) to simulate a semi-infinitely deep region.A criterion for the occurrence of blocked flow cannot be defined for the inviscid case except when the Froude number, Fr, based on the peak-to-trough ridge amplitude is less than about 0.4: then blocking is clearly identifiable before wave-breaking occurs. Breaking of waves is evident for Fr as large as 0.75, in agreement with analytical results given by Lilly and Klemp (1979).At small Froude number (Fr 0.5) in the dissipative flow simulations, blocked flow (stagnation) is present in the valleys, but a lee rotor (complete stagnation) is not evident. For order unity Froude numbers, blocking is a wave phenomenon, resulting from wave steepening and overturning or turbulent mixing. A finite thickness is brought to rest or participates in a recirculating flow when it first appears. A strong upward flow appears ahead of the rotor in the valleys, and the downslope wind over the windward side of the valleys is strengthened. Thus the present study shows that conditions for the onset of a rotor, and of stagnant flow, in periodic valleys are different.When blocked flow exists, the amplitudes of gravity waves in the upper layer are only 15% (Fr = 0.3) to 80% (Fr = 1.5) of those given by linear theory; this is supported by observations.     

Estimation of electron temperature by VLF waves propagating in directions near the resonance cone

A ray tracing computer program for non-ducted whistler mode waves in a warm plasma in the magnetosphere is developed, where electron temperature effects are taken into account. The refractive index is calculated from the warm-plasma approximation and is used in the ray tracing after its accuracy has been checked by comparison with the hot-plasma solution without approximation. The ray paths do not depend appreciably on electron temperature. However, there are regions where the waves are heavily damped by Landau damping. By paying attention to this damping region, the electron temperature can be estimated from a satellite observation of the Doppler shift and damping of a ground-based VLF signal.     

Pan-African Alkali Granitoids from the Sør Rondane Mountains, East Antarctica

Alkali granitoids (500-550 Ma) representing a prominent Pan-African magmatic event are widely distributed in the Sør Rondane Mountains, Dronning Maud Land, East Antarctica. Geochemically, they are granitic to syenitic in composition and show an alkaline affinity of A-type granites. They are characterized by high K₂O+Na₂O (7-13 wt%) and K₂O/Na₂O (1-2), low to intermediate Mg#, wide ranges of SiO₂ (45-78 wt%), Sr (20-6500 ppm) and Ba (40-13000 ppm) and have Nb and Ti depletion in the primitive mantle normalized diagram. The granitoids are subdivided into Group I granites, Group II granites, Lunckeryggen Syenitic Complex and Mefjell Plutonic Complex. The Group I granites have higher Mg#, Sr/Ba, Sr/Y, (La/Yb)_N and LREE/HREE, lower A/CNK, SREE and initial ⁸⁷Sr/⁸⁷Sr ratios and lack Eu anomalies compared to those with negative Eu anomalies in the Group II granites. The syenitic rocks from the Mefjell Plutonic Complex are higher in alkali, Ga, Zr, Ba, and have lower Mg#, Rb, Sr, Nb, Y, F and LREE/HREE with positive Eu anomaly, whereas the granites from the Mefjell Plutonic Complex have high LREE/HREE ratios with negative Eu anomaly. The Lunckeryggen syenitic rocks have intermediate Mg#, higher K₂O, P₂O₅, TiO₂, Fe₂O₃/FeO, Ba, Sr/Y and LREE/HREE ratios with lack of Eu anomalies and are lower in Al₂O₃, Ga, Y, Nb and Rb/Sr ratios. Based on chemical characteristics combined with isotopic data, we suggest that the Lunckeryggen syenitic body and Group I granitic bodies may be derived from the mantle-derived hot basic magma by fractional crystallization with minor assimilation. We also suggest that the Group II granites may be derived from assimilation with crustal rocks to varing degrees and then fractional crystallization in higher crustal levels (ACF model). The Mefjell Plutonic Complex seems to be derived from a heterogenetic magma source compared with other granitoids from the Sør Rondane Mountains. The syenitic rocks in the Mefjell Plutonic complex have a unique source (iron-enriched) and have a chemical affinity with the charnockites in Gjelsvikjella and western Mühlig-Hofmannfjella, but not like the Yamato syenites in adjacent areas.