Clinopyroxene REE Geochemistry of the Red Hills Peridotite, New Zealand: Interpretation of Magmatic Processes in the Upper Mantle and in the Moho Transition Zone

The Red Hills peridotite in the Dun Mountain ophiolite of SouthIsland, New Zealand, is assumed to have been produced in a paleo-mid-oceanridge tectonic setting. The peridotite is composed mostly ofharzburgite and dunite, which represent residual mantle andthe Moho transition zone (MTZ), respectively. Dunite channelswithin harzburgite blocks of various scales represent the MTZcomponent. Plagioclase- and clinopyroxene-bearing dunites occursporadically within common dunites. These dunites representproducts of melt–wall-rock interaction. Chondrite-normalizedrare earth element (REE) patterns of MTZ clinopyroxenes showa wide compositional range. Clinopyroxenes in plagioclase dunitesare extremely depleted in light REE (LREE) ([Lu/La]_N >100),and are comparable with clinopyroxenes in abyssal peridotitesfrom normal mid-ocean ridges. Interstitial clinopyroxenes inthe common dunite have flatter patterns ([Lu/La]_N 2) comparablewith those for dunite in the Oman ophiolite. Clinopyroxenesin the lower part of the residual mantle harzburgites are evenmore strongly depleted in LREE ([Lu/La]_N = 100–1000) thanare mid-ocean ridge peridotites, and rival the most depletedabyssal clinopyroxenes reported from the Bouvet hotspot. Incontrast, those in the uppermost residual mantle harzburgiteand harzburgite blocks in the MTZ are less LREE depleted ([Lu/La]_N= 10–100), and are similar to those in plagioclase dunite.Clinopyroxenes in the clinopyroxene dunite in the MTZ are similarto those reported from mid-ocean ridge basalt (MORB) cumulates,and clinopyroxenes in the gabbroic rocks have compositions similarto those reported from MORB. Strong LREE and middle REE (MREE)depletion in clinopyroxenes in the harzburgite suggests thatthe harzburgites are residues of two-stage fractional melting,which operated initially in the garnet field, and subsequentlycontinued in the spinel lherzolite field. The early stage meltingproduced the depleted harzburgite. The later stage melting wasresponsible for the gabbroic rocks and dunite. Strongly LREE–MREE-depletedclinopyroxene in the lower harzburgite and HREE-enriched clinopyroxenein the upper harzburgite and plagioclase dunite were formedby later reactive melt migration occurring in the harzburgite. KEY WORDS: clinopyroxene REE geochemistry; Dun Mountain ophiolite; Moho transition zone; orogenic peridotite; Red Hills     

Chemical and Isotopic Characteristics of the Kuroko‐Forming Volcanism

The Miocene northeast Honshu magmatic arc, Japan, formed at a terrestrial continental margin via a stage of spreading in a back‐arc basin (23–17 Ma) followed by multiple stages of submarine rifting (19–13 Ma). The Kuroko deposits formed during this period, with most forming during the youngest rifting stage. The mode of magma eruption changed from submarine basalt lava flows during back‐arc basin spreading to submarine bimodal basalt lava flows and abundant rhyolitic effusive rocks during the rifting stage. The basalts produced during the stage of back‐arc basin spreading are geochemically similar to mid‐ocean ridge basalt, with a depleted Sr–Nd mantle source, whereas those produced during the rifting stage possess arc signatures with an enriched mantle source. The Nb/Zr ratios of the volcanic rocks show an increase over time, indicating a temporal increase in the fertility of the source. The Nb/Zr ratios are similar in basalts and rhyolites from a given rift zone, whereas the Nd isotopic compositions of the rhyolites are less radiogenic than those of the basalts. These data suggest that the rhyolites were derived from a basaltic magma via crystal fractionation and crustal assimilation. The rhyolites associated with the Kuroko deposits are aphyric and have higher concentrations of incompatible elements than do post‐Kuroko quartz‐phyric rhyolites. These observations suggest that the aphyric rhyolite magma was derived from a relatively deep magma chamber with strong fractional crystallization. Almost all of the Kuroko deposits formed in close temporal relation to the aphyric rhyolite indicating a genetic link between the Kuroko deposits and highly differentiated rhyolitic magma.     

Variability of surface characteristics and energy flux patterns of sunn hemp (Crotalaria juncea L.) under well-watered conditions

There is not much information in the literature about the energy partitioning and micrometeorological features of sunn hemp. Therefore, in this study, the variations in the energy-balance components and plant characteristics such as aerodynamic and surface conductance, crop coefficient, albedo, short- and long wave down- and upward radiation have been measured and estimated for the time period from August to October 2004 over an irrigated sand field at the Arid Land Research Center in Tottori, Japan. The Bowen ratio energy-balance method was used to calculate the partitioning of heat fluxes of sunn hemp. The Bowen ratio values at the first growing stages in August were found to be higher than the Bowen ratio values at the latest growing stages in September and October because of the heavy rain and high soil-water content. The daytime averaged Bowen ratio was 0.19. During the measurement period, the daytime average net radiation, and soil, latent and sensible heat fluxes were approximately 231, 28, 164, and 39 W m^–2, respectively. The net radiation and soil heat flux showed decreasing trends from the beginning to the end of the experiment period due to the atmospheric and crop growth conditions. The daytime averages of aerodynamic and surface conductance for sunn hemp were around 31 and 17 mm s^–1, respectively. Also, the daytime average albedo of sunn hemp was around 19%. Finally, the high precipitation amount due to typhoons, high soil-water content, low available energy and low vapor-pressure deficit lead to decreasing trend of the energy fluxes during the generative phase of sunn hemp.     

A Simple Single-Layer Urban Canopy Model For Atmospheric Models: Comparison With Multi-Layer And Slab Models

We developed a simple, single-layer urban canopy model, and comparedit to both multi-layer and slab models. Our single-layer model has thefollowing features: (a) It is a column model of energy and momentumexchange between an urban surface and the atmosphere, (b) it includesthe influence of street canyons, which are parameterized to representthe urban geometry, (c) it includes shadowing from buildings andreflection of radiation, and (d) it estimates both the surfacetemperatures of, and heat fluxes from, three surface types: roof, wall,and road. In the simulation of the single-layer model, the roof washottest during the daytime, but coolest from midnight to early morning.This is consistent with output from the multi-layer model and fieldobservations at a residential area on a clear, summer day. The diurnalvariation of the energy budget from the single-layer model agrees wellwith that from the multi-layer model. Our single-layer model'sperformance is nearly that of a multi-layer model for studyingmesoscale heat islands. Nevertheless, it is simply parameterized,and thus easily included in larger-scale atmospheric models. The slabmodel has the largest nighttime cooling rate of the three models. Toovercome this, it needs more adjustments than for the canopy models.     

Rapid Identification of Water-Conducting Fractures Using a Trace Methane Gas Measurement

Identification of water-conducting fractures is important for the safety assessment of underground projects in crystalline rocks at geological disposal sites. We applied a portable methane gas analyzer by wavelength-scanned cavity ring-down spectroscopy to detect the water-conducting fractures in the underground tunnel of the Mizunami Underground Research Laboratory, central Japan. The tunnel is excavated in granite with CH₄-rich groundwater. Two approaches were taken to obtain the profile of CH₄ concentration along the gallery walls: (1) “Scan by walking” at the speed of 0.5 m/s and (2) monitoring for 30 s at 0.5 or 1 m intervals. In the Scan by walking approach, the peaks of the CH₄ concentration corresponded well with the occurrence of high water flow rate fractures. Thus, this method is useful for rapid identification of major water-conducting fractures. Monitoring at constant intervals takes more time than the Scan by walking approach; however, this method can largely detect occurrences of fractures with low fluid fluxes.     

Planform evolution of deltas with graded alluvial topsets: Insights from three‐dimensional tank experiments,geometric considerations and field applications

The profile of a river that conveys sediment without net deposition and net erosion is referred to as ‘graded’ with respect to vertical aggradation of the river segment. Three experimental series, designed in terms of the autostratigraphic view of alluvial grade, were conducted to clarify the diagnostic spatial behaviour of graded alluvial–deltaic rivers: an ‘R series’, which utilized a moving boundary setting with a stationary base level; an ‘F series’ in a fixed boundary setting with a stationary base level to produce ‘forced grade’; and an ‘M series’ in a moving boundary setting with constant base‐level fall to produce ‘autogenic grade.’ The results of the three experimental series, combined with geometrical modelling of the effects of basin water depth and other experimental data, suggest the following: (i) in a graded alluvial–deltaic system, lateral shifting and avulsing of active distributary channels are suppressed regardless of whether the downstream boundary of the deltaic system is fixed; (ii) in a delta with a downstream‐fixed boundary, the graded streams are stabilized within a valley that is incised in the axial part of the delta plain, whereby the alluvial plain outside the valley is abandoned and terraced; (iii) in moving boundary settings, the graded river simply extends basinward as a linearly elongated channel and lobe system without cutting a valley; and (iv) a modern forced‐graded alluvial river is most likely to be found in a valley incised into a fan delta in front of very deep water, and the stratigraphic signal of fossil autogenic‐graded rivers will be found in deltaic successions that accumulated in the outer to marginal areas of deltaic continental shelves during sea‐level falls. This renewed autostratigraphic view of alluvial grade suggests a thorough reconsideration of the conventional understanding that an alluvial river feeding a progradational delta is graded with a stationary base level.     

Modulation of tropical cyclogenesis in the western North Pacific by the quasi-biweekly oscillation

The quasi-biweekly oscillation(QBWO) is the second most dominant intraseasonal mode over the western North Pacific(WNP) during boreal summer. In this study, the modulation of WNP tropical cyclogenesis(TCG) by the QBWO and its association with large-scale patterns are investigated. A strong modulation of WNP TCG events by the QBWO is found.More TCG events occur during the QBWO's convectively active phase. Based on the genesis potential index(GPI), we further evaluate the role of environmental factors in affecting WNP TCG. The positive GPI anomalies associated with the QBWO correspond well with TCG counts and locations. A large positive GPI anomaly is spatially correlated with WNP TCG events during a life cycle of the QBWO. The low-level relative vorticity and mid-level relative humidity appear to be two dominant contributors to the QBWO-composited GPI anomalies during the QBWO's active phase, followed by the nonlinear and potential intensity terms. These positive contributions to the GPI anomalies are partly offset by the negative contribution from the vertical wind shear. During the QBWO's inactive phase, the mid-level relative humidity appears to be the largest contributor, while weak contributions are also made by the nonlinear and low-level relative vorticity terms.Meanwhile, these positive contributions are partly cancelled out by the negative contribution from the potential intensity.The contributions of these environmental factors to the GPI anomalies associated with the QBWO are similar in all five flow patterns—the monsoon shear line, monsoon confluence region, monsoon gyre, easterly wave, and Rossby wave energy dispersion associated with a preexisting TC. Further analyses show that the QBWO strongly modulates the synoptic-scale wave trains(SSWs) over the WNP, with larger amplitude SSWs during the QBWO's active phase. This implies a possible enhanced(weakened) relationship between TCG and SSWs during the active(inactive) phase. This study improves our understanding of the modulation of WNP TCG by the QBWO and thus helps with efforts to improve the intraseasonal prediction of WNP TCG.     

Measurements of wave normal direction of whistler mode signals in the ionosphere by means of the Rocket-Doppler technique

Wave normal directions of VLF signals propagating through the ionosphere can be determined by measuring Doppler frequency shift of the signals by means of rocket borne receivers. Two rockets were launched to detect the NWC signal of 22.3 kHz which was transmitted from Australia and propagated on two completely different paths, one being propagated through the Earth-ionosphere waveguide and up to the rocket, the other propagated down to the rocket by the whistler mode directly from the source in the opposite hemisphere. The wave normal directions of the latter mode were almost vertically downward in the ionosphere in the northern hemisphere, although substantial error was involved in the determination of the wave normal direction for a part of the upgoing flight of the rockets, due to the relative geometry of the directions of the rocket flight and the geomagnetic field. The effect of the horizontal gradients of the ionosphere on the above results were found to be not significant. From the experimental results it is concluded that field aligned ducts stretching down to the rocket altitudes did not exist, at least, during the rocket flights.     

Small Scale Field Study of an Ocean CO<Subscript>2</Subscript> Plume

We have carried out a small-scale (∼20 l) CO₂ sequestration experiment off northern California (684 m depth, ∼5°C, background ocean pH ∼7.7) designed as an initial investigation of the effects of physical forcing of the fluid, and the problem of sensing the formation of a low pH plume. The buoyant CO₂ was contained in a square frame 1.2 m high, exposing 0.21 m² to ocean flow. Two pH electrodes attached to the frame recorded the signal; a second frame placed 1.9 m south of the CO₂ pool was also equipped with two recording pH electrodes. An additional pH electrode was held in the ROV robotic arm to probe the fluid interface. Local water velocities of up to 40 cm sec⁻¹ were encountered, creating significant eddies within the CO₂ box, and forcing wavelets at the fluid interface. This resulted in rapid CO₂ dissolution, with all CO₂ being depleted in a little more than 2 days. The pH record from the sensor closest (∼10 cm) to the CO₂ showed many spikes of low pH water, the extreme value being ∼5.9. The sensor 1 m immediately below this showed no detectable response. The electrodes placed 1.9 m distant from the source also recorded very small perturbations. The results provide important clues for the design of future experiments for CO₂ disposal and biogeochemical impact studies. These include the need for dealing with the slow CO₂ hydration kinetics, better understanding of the fluid dynamics of the CO₂-water interface, and non-point source release designs to provide more constant, controlled local CO₂ enrichments within the experimental area. This revised version was published online in July 2006 with corrections to the Cover Date.     

Okinawa Trough genesis: structure and evolution of a backarc basin developed in a continent

The Okinawa marginal basin was opened by crustal extension into the Asian continent, north of the Taiwan collision zone. It is located behind the Ryukyu Trench subduction zone and the Ryukyu active volcanic arc. If we except the Andaman Sea, the Okinawa Trough is the only example of marginal backarc basin type, opened into a continent at an early stage of evolution. Active rifting and spreading can be observed. Synthesis of siesmic reflection, seismic refraction, drilling, dredging and geological field data has resulted in interpretative geological cross sections and a structural map of the Ryukyu-Okinawa area. The main conclusions of the reconstruction of this backarc basin/volcanic arc evolution are. (1) Backarc rifting was initiated in the volcanic arc and propagated along it during the Neogene. It is still active at both ends of the basin. Remnants of volcanic arc are found on the continental side of the basin. (2) There was synchronism between opening and subsidence of the Okinawa Trough and tilting and subsidence of the forearc terrace. The late Miocene erosional surface is now 4000 m below sea-level in the forearc terrace, above the trench slope. Retreat and subsidence of the Ryukyu trench line relative to the Asian continental plate, could be one of the causes of tilting of the forearc and extension in the backarc area. (3) A major phase of crustal spreading occurred in Pliocene times 1.9 My ago in the south and central Okinawa Trough. (4) En échelon rifting and spreading structures of the central axes of the Okinawa Trough are oblique to the general trend of the arc and trench. The Ryukyu arc sub-plate cannot be considered as a rigid plate. Rotation of 45° to 50° of the southern Ryukyu arc, since the late Miocene, is inferred. The timing and kinematic evolution of the Taiwan collision and the south Okinawa Trough opening suggest a connection between these two events. The indentation process due to the collision of the north Luzon Arc with the China margin could have provoked: lateral extrusion; clockwise rotation (45° to 50° according to palaeomagnetic data) and buckling of the south Ryukyu non-volcanic arc; tension in the weak crustal zone constituted by the south Ryukyu volcanic arc and opening of the south Okinawa Trough. Similar lateral extrusions, rotations, buckling and tensional gaps have been observed in indentation experiments. Additional phenomena such as: thermal convection, retreating trench model or anchored slab model could maintain extension in the backarc basin. Such a hypothetical collision-lateral backarc opening model could explain the initiation of opening of backarc basins such as the Mariana Trough, Bonin Trough, Parece Vela — Shikoku Basin and Sea of Japan. A new late Cenozoic palaeogeographic evolution model of the Philippine Sea plate and surrounding areas is proposed.