Stewardship of things: The radical potential of product stewardship for re-framing responsibilities and relationships to products and materials

In the context of broad-based concerns about the need to move towards a more sustainable materials economy, particularly as they are expressed in debates around Ecological Modernisation (EM), we argue that product stewardship has radical potential as a means to promote significant change in the relationship between society and the material world. We focus on two important dimensions that have been neglected in approaches to product stewardship to date. Firstly, we argue that immanent within the basic concept of stewardship is a problematisation of dominant understandings of property ownership in neoliberal market economies. In the space opened up by notions of stewardship, different ways of enacting both rights and responsibilities to products and materials emerge which have potential to advance the sustainability of material economies. Secondly, through exploration of existing expressions of product stewardship, we uncover a neglected scale of action. Both policy and dominant articulations of EM focus primarily on the efficiency of production processes; and secondarily, the attitudes and behaviours of individual consumers. Missing from this is the ‘meso-scale’ of social collectives including households, neighbourhoods, more distributed communities and small scale social enterprises. Based on a review of existing research from Australia and the UK, including our own, we argue that understanding of embedded practices of material responsibility at the household scale can both reinvigorate the concept of product stewardship as a potentially radical intervention, and reveal the potential of the meso-scale as a challenging but worthwhile realm of policy intervention.     

Texas Coastal Hypoxia Linked to Brazos River Discharge as Revealed by Oxygen Isotopes

Hypoxic conditions in the coastal waters off Texas (USA) were observed since the late 1970s, but little is known about the causes of stratification that contribute to hypoxia formation. Typically, this hypoxia is attributed to downcoast (southwestward) advection of waters from the Mississippi–Atchafalaya River system. Here, we present evidence for a hypoxic event on the inner shelf of Texas coincident with the presence of freshwater linked to high flow of the Brazos River in Texas. These conclusions are based on hydrographic observations and isotopic measurements of waters on the inner shelf near the Brazos River mouth. These data characterize the development, breakdown, and dispersal of a hypoxic event lasting from June through September 2007 off the Texas coast. Oxygen isotope compositions of shelf water indicate that (1) discharge from the Brazos River was the principal source of freshwater and water column stratification during the 2007 event, and (2) during low Brazos River discharge in 2008, freshwater on the Texas shelf was derived mainly from the Mississippi–Atchafalaya River System. Based on these findings, we conclude that the Mississippi–Atchafalaya River System is not the sole cause of hypoxia in the northern Gulf of Mexico; however, more data are needed to determine the relative influence of the Texas versus Mississippi rivers during normal and low flow conditions of Texas rivers.     

Distribution and enrichment of trace metals and arsenic at the upper layer of sediments from Lerma River in La Piedad,Mexico: case history

Lerma River is one of the largest rivers in Mexico. Over the past 20 years, unplanned population growth occurred along its course and the river has been used as the only outlet for industrial and domestic wastewater disposal. The aim of the present study was to determine trace metals such as Cr, Ni, Cu, Zn, Fe, Pb, and arsenic concentrations at the upper layer of sediments of the Lerma River meander in La Piedad, Michoacan, Mexico. Sediment samples were collected from eight different sites during the rainy and dry seasons. All samples were physically characterized, and concentration values of trace metals and As were determined. On the basis of protection criteria for freshwater sediments, concentrations of Fe, Zn, Cu, Ni, and Pb were found to exceed the lowest effect level; moreover, the concentrations were found to exceed the severe effect level at some sites, particularly for Cu. Statistical analyses showed significant differences between sampling seasons for Fe and As, and among sites for Ni, Cu, Zn, and Pb. In addition, the enrichment factor indicates the following order Zn > Cr > Cu > Ni > Pb > As, and the geoaccumulation index (I _geo) indicates contamination in the following order Zn > Cr > Cu > Ni > As > Pb. The Lerma River meander in La Piedad shows a reduction in pollution by trace metals and arsenic near the drain area and downstream of the meander. However, there are significantly higher concentrations of these elements in sediments of sites located in the middle part of the city.     

Metal ion remediation by polyamidoamine dendrimers: a comparison of metal ion,oxidation state,and titania immobilization

The exceptional ability of dendrimers to coordinate metal ions yields the potential for many applications including wastewater remediation, which is the focus of this study. Here, the comparison of metal ion removal rate from simulated wastewater by generation 4 dendrimers with external hydroxyl functional groups (G4-OH) is evaluated for Ni²⁺, Fe²⁺, and Fe³⁺ ions. Ni²⁺ to amine complexation occurred more rapidly than Fe³⁺, which was more rapid than Fe²⁺ complexation. These results indicate that both charge density and d-electron configuration are important toward the chelation rate. The impact of both factors is discussed in light of existing models in which precursor aquation rates have been proposed as a key intermediate step. Additionally, the application of the dendrimers as chelation agents is further advanced by immobilizing the dendrimer to titania and re-evaluating its chelation ability for Ni²⁺ removal. The dendrimer immobilization decreased the pseudo-first-order rate coefficient for Ni²⁺—amine complexation at a pH of 7 by a factor of 7.5. This result is significant as it suggests that mass transfer becomes important following immobilization of the dendrimer to titania.     

Cosmological magnetic fields: their generation,evolution and observation

We review the possible mechanisms for the generation of cosmological magnetic fields, discuss their evolution in an expanding Universe filled with the cosmic plasma and provide a critical review of the literature on the subject. We put special emphasis on the prospects for observational tests of the proposed cosmological magnetogenesis scenarios using radio and gamma-ray astronomy and ultra-high-energy cosmic rays. We argue that primordial magnetic fields are observationally testable. They lead to magnetic fields in the intergalactic medium with magnetic field strength and correlation length in a well defined range.We also state the unsolved questions in this fascinating open problem of cosmology and propose future observations to address them.     

Validation of a field filtration technique for characterization of suspended particulate matter from freshwater. Part II. Minor, trace and ultra trace elements

A field filtration method for the concentration and separation of suspended particulate matter (SPM) from freshwater systems and the subsequent determination of minor, trace and ultra trace elements (As, Ba, Be, Cd, Co, Cr, Cs, Cu, Ga, Hf, Mo, Nb, Ni, Pb, Rb, Sb, Sc, Sn, Sr, Ta, Th, Tl, U, V, W, Zn and Zr) is validated with respect to detection limits, precision and bias. The validation comprises the whole procedure including filtration, sample digestion and instrumental analysis. The method includes two digestion procedures (microwave acid digestion and alkali fusion) in combination with inductively coupled plasma atomic emission spectrometry (ICP-AES) and inductively coupled plasma quadrupole mass spectrometry (ICP-QMS). Total concentrations of these 27 trace and minor elements have been determined in suspended particulate matter (SPM) from lake and river water with low levels of suspended solids (<2 mg L⁻¹ DW), and a wide range of element concentrations. The precision of the method including filtration, digestion and instrumental determination ranges between 8% and 18% RSD for most elements on a dry weight basis. Higher recovery after acid digestion is found for some elements, probably because of volatilization or retention losses in the fusion procedure. Other elements show higher recovery after fusion, which is explained by more efficient decomposition of refractory mineral phases relative to the non-total acid digestion. Non-detectable concentrations of some elements are reported due to small differences between blank filter levels and the amounts of elements present on the filters after sampling. The method limits of detection range between 0.7 ng and 2.65 μg, as estimated from the blank filter samples. These detection limits are 10–550 times higher compared to the corresponding instrumental limits of detection. The accuracy and bias of the overall analytical procedure was assessed from replicate analysis of certified reference materials. A critical evaluation of the instrumental capabilities of the ICP-QMS instrumentation in comparison with a double focusing sector field plasma mass spectrometry technique (ICP-SFMS) is also included. It was found that a modified microwave acid digestion procedure in combination with ICP-SFMS could replace ICP-AES determinations and fusion digestions for most of the investigated elements. Guidelines and limitations for this time- and labour- efficient procedure, offering accurate results for the majority of elements studied are discussed.     

He, Sr, Nd, and Pb isotopic constraints on the origin of the Marquesas and other linear volcanic chains

The classic hotspot hypothesis [Morgan, W. J., 1971. Convection plumes in the lower mantle. Nature 230, 42–43], which posits that linear volcanic chains are traces of fixed plumes in the mantle on moving lithospheric plates, was instrumental in elevating the plate tectonics paradigm in the 1960s into a modern Earth Science theory. The hypothesis itself, however, remains conjectural because many of its predictions, particularly the simple age-progressive type of volcanism, are not observed in many linear volcanic chains. As an alternative explanation, it is proposed that linear volcanic chains are formed through magmatism along pre-existing lines of weakness such as transform zones and old sutures, or along cracks created by stresses on lithospheric plates. The Marquesas linear volcanic chain in south-central Pacific has geologic features that are consistent with some of the predictions of both hypotheses. To better constrain the origin of this volcanic chain, we collected major and trace element and Sr, Nd, Pb, and He isotopic data from several Marquesan lavas. Our new analyses combined with literature data classify the samples into the well established tholeiitic to mildly alkalic, low ⁸⁷Sr/⁸⁶Sr, high ¹⁴³Nd/¹⁴⁴Nd, shield-building volcanic phase lava group and highly alkalic, high ⁸⁷Sr/⁸⁶Sr, low ¹⁴³Nd/¹⁴⁴Nd, post-shield phase group. Lead isotopes show generally higher ²⁰⁶Pb/²⁰⁴Pb ratios and suggest evidence of crustal assimilation for the shield-building phase lavas, consistent with the argument that the shield-building phase volcanism has a lithospheric source component. On the other hand, post-shield phase lavas that are predicted to represent the true composition of the mantle source by the hotspot hypothesis have higher ³He/⁴He ratios and these are coupled to other geochemical tracers. Thus our results show that the Marquesas volcanic chain, similar to many other linear volcanic chains, has a high ³He/⁴He component in its mantle source. The presence of such a distinct source component cannot be easily explained by dispersed upper mantle heterogeneities, but provides a powerful constraint for the hotspot origin of many linear volcanic chains.     

Spektrographische Untersuchungen des magnetischen Sterns α2CVn

The main purpose of this paper was the examination of the Cassegrain-spectrograph of the 2-m-universaltelescope at Tautenburg for investigations of magnetic stars. Therefore from 26 spectrograms of the well known magnetically variable star α²CVn taken with a reciprocal linear dispersion of 10 Å/mm variations of radial velocity and magnetic field strength for some lines of Eu II, Cr II, Si II, Mg II were determined. The results agree well with those of Babcock [5] and Struve and Swings [2], derived from spectrograms of higher dispersion. The large variation in the radial velocity of Eu II and Cr II is confirmed. In the oblique rotator model this requires a very strong concentration of Eu II at the poles and of Cr II at the equator.