Controls on Methane Occurrences in Shallow Aquifers Overlying the Haynesville Shale Gas Field,East Texas

Understanding the source of dissolved methane in drinking‐water aquifers is critical for assessing potential contributions from hydraulic fracturing in shale plays. Shallow groundwater in the Texas portion of the Haynesville Shale area (13,000 km²) was sampled (70 samples) for methane and other dissolved light alkanes. Most samples were derived from the fresh water bearing Wilcox formations and show little methane except in a localized cluster of 12 water wells (17% of total) in a approximately 30 × 30 km² area in Southern Panola County with dissolved methane concentrations less than 10 mg/L. This zone of elevated methane is spatially associated with the termination of an active fault system affecting the entire sedimentary section, including the Haynesville Shale at a depth more than 3.5 km, and with shallow lignite seams of Lower Wilcox age at a depth of 100 to 230 m. The lignite spatial extension overlaps with the cluster. Gas wetness and methane isotope compositions suggest a mixed microbial and thermogenic origin with contribution from lignite beds and from deep thermogenic reservoirs that produce condensate in most of the cluster area. The pathway for methane from the lignite and deeper reservoirs is then provided by the fault system.     

Controls on Methane Occurrences in Aquifers Overlying the Eagle Ford Shale Play,South Texas

Assessing natural vs. anthropogenic sources of methane in drinking water aquifers is a critical issue in areas of shale oil and gas production. The objective of this study was to determine controls on methane occurrences in aquifers in the Eagle Ford Shale play footprint. A total of 110 water wells were tested for dissolved light alkanes, isotopes of methane, and major ions, mostly in the eastern section of the play. Multiple aquifers were sampled with approximately 47 samples from the Carrizo‐Wilcox Aquifer (250‐1200 m depth range) and Queen City‐Sparta Aquifer (150‐900 m depth range) and 63 samples from other shallow aquifers but mostly from the Catahoula Formation (depth <150 m). Besides three shallow wells with unambiguously microbial methane, only deeper wells show significant dissolved methane (22 samples >1 mg/L, 10 samples >10 mg/L). No dissolved methane samples exhibit thermogenic characteristics that would link them unequivocally to oil and gas sourced from the Eagle Ford Shale. In particular, the well water samples contain very little or no ethane and propane (C1/C2+C3 molar ratio >453), unlike what would be expected in an oil province, but they also display relatively heavier δ¹³C_methane (>?55‰) and δD_methane (>?180‰). Samples from the deeper Carrizo and Queen City aquifers are consistent with microbial methane sourced from syndepositional organic matter mixed with thermogenic methane input, most likely originating from deeper oil reservoirs and migrating through fault zones. Active oxidation of methane pushes δ¹³C_methane and δD_methane toward heavier values, whereas the thermogenic gas component is enriched with methane owing to a long migration path resulting in a higher C1/C2+C3 ratio than in the local reservoirs.     

Using geographically weighted regression to explore neighborhood‐level predictors of domestic abuse in the UK

Reducing domestic abuse has become a priority for both local and national governments in the UK, with its substantial human, social, and economic costs. It is an interdisciplinary issue, but to date there has been no research in the UK that has focused on neighborhood‐level predictors of domestic abuse and their variation across space. This article uses geographically weighted regression to model the predictors of police‐reported domestic abuse in Essex. Readily available structural and cultural variables were found to predict the domestic abuse rate and the repeat victimization rate at the lower super output area level and the model coefficients were all found to be non‐stationary, indicating varying relationships across space. This research not only has important implications for victims' well being, but also enables policy makers to gain a better understanding of the geography of victimization, allowing targeted policy interventions and efficiently allocated resources.     

Hekla 1947, 1845, 1510 and 1158 tephra in Finland: challenges of tracing tephra from moderate eruptions

Several cryptotephra layers that originate from Icelandic volcanic eruptions with a volcanic explosivity index (VEI) of ≤ 4 and tephra volumes of < 1 km³ have previously been identified in Northern Europe, albeit within a restricted geographical area. One of these is the Hekla 1947 tephra that formed a visible fall-out in southern Finland. We searched for the Hekla 1947 tephra from peat archives within the previously inferred fall-out zone but found no evidence of its presence. Instead, we report the first identification of Hekla 1845 and Hekla 1510 cryptotephra layers outside of Iceland, the Faroe Islands, Ireland and the UK. Additionally, Hekla 1158 tephra was found in Finland for the first time. Our results confirm that Icelandic eruptions of moderate size can form cryptotephra deposits that are extensive enough to be used in inter-regional correlations of environmental archives and carry a great potential for refining regional tephrochronological frameworks. Our results also reveal that Icelandic tephra has been dispersed into Finnish airspace at least seven times during the past millennium and in addition to a direct eastward route the ash clouds can travel either via a northerly or a southerly transport pathway.     

Factors influencing surface runoff generation in a Mediterranean semi-arid environment: Chicamo watershed,SE Spain

A deeper knowledge of the hydrological response of semi-arid Mediterranean watersheds would be useful in the prediction of runoff production for assessing flood risks and planning flood mitigation works. This study was conducted to identify the runoff generation mechanisms and their controlling factors at the hillslope scale in a Mediterranean semi-arid watershed. Four zero-order microcatchments were selected to measure rainfall and runoff for a three-year period. Two groups of soil were differentiated with respect to the hydrological response. The fine textured, poorly permeable soils of low organic carbon content had a greater runoff coefficient (9%) and lower runoff threshold (3·6 mm) than more permeable, coarser textured soils of medium organic carbon content (<3%, and 8 mm, respectively). The influence of rainfall characteristics on the hydrological response was different. Rain intensity was the major rainfall parameter controlling the runoff response in the microcatchments on fine textured, low infiltrability soils with a poor plant cover, while total rainfall was more closely correlated with runoff in coarser textured, highly permeable soils with a denser plant cover. It can be concluded that there are two runoff generation mechanisms: (i) an infiltration-excess overland flow in the more degraded areas with low organic carbon content (<0·5%) and low infiltrability (>5 mm h⁻¹); and (ii) a saturation-excess overland flow in the less degraded areas with a high organic carbon content (>2%), high infiltrability (>8 mm h⁻¹) and covered by a dense plant cover (>50%). © 1998 John Wiley & Sons, Ltd.     

Origin of high field strength element enrichment in volcanic arcs: Geochemical evidence from the Sulu Arc, southern Philippines

Lavas from the Sulu Arc, southern Philippines, exhibit an enrichment in high field strength elements (HFSE) that represents a departure from the typical volcanic arc geochemical signature. It has been postulated that this relative enrichment arises from metasomatism of mantle wedge peridotites by melts derived from the subducting oceanic lithosphere, through formation of amphibole which subsequently breaks down and enriches the mantle source of parental arc magmas in HFSE. Divergent chemical and isotopic characteristics between Sulu Arc HFSE-enriched lavas and the Sulu Sea crust being subducted—the presumed source of slab-derived melts—render it unlikely, however, that HFSE enrichment arises from the influence of such melts. New geochemical data suggest that the varying degrees of HFSE enrichment in Sulu Arc lavas are instead the result of variable amounts of mixing between enriched and depleted mantle end-components—the sources of South China Sea intraplate lavas and Sulu seafloor basalts, respectively—within a compositionally heterogeneous mantle wedge.     

Problems associated with luminescence dating of Late Quaternary glacial sediments in the NW Scottish Highlands

Linking the timing of glacial episodes and behaviour to climatic shifts that are documented in ice and marine sedimentary archives is key to understanding ocean-land interactions. In the NW Scottish Highlands a large number of closely spaced (‘hummocky’) moraines formed at retreating glacier margins. Independent age control on one palaeo-glacier limit is consistent with the timing of Younger Dryas (YD) glaciation in the area, but adjacent glacier lobes have remained undated due to the lack of sites and material for ¹⁴C dating. Direct dating of ice-marginal moraines using optically stimulated luminescence (OSL) techniques has never been attempted before in Scotland, but if successful, they may be the most appropriate methods for constraining the age of sediment deposition in the absence of organic material. Coarse-grained quartz and K-feldspar minerals from supraglacial sheet flow deposits and glacilacustrine sediments within ice-marginal moraines were analysed using the single-aliquot regenerative-dose (SAR) protocol. Independent age control and clear geomorphological relationships indicate that all samples should yield YD or post-Last Glacial Maximum (LGM) ages. Quartz OSL shine down curves showed low luminescence sensitivity, significant medium-to-slow components, a weak fast component, and scattered SAR data; Linearly Modulated-OSL (LM-OSL) measurements confirmed that the fast component was weak or absent. In contrast, feldspar infrared stimulated luminescence (IRSL) was highly sensitive with excellent SAR data. However, SAR data from 3 mm diameter aliquots of feldspar (200 grains) give higher than expected equivalent doses (D_e) by an order of magnitude. SAR measurements of small clusters of feldspar grains (ranging from 1–8) considerably broaden the apparent D_e distribution, but even the lowest value is about 2–3 times the expected D_e. Two possibilities arise to explain the quartz and feldspar data: (1) that glacial sequences in the NW Highlands re-work inherited (older) glacial deposits and that some of the pre-Devensian existing glacial landforms have only been modified during Devensian glaciation; or (2) that the sedimentary processes operating in these ice-marginal environments are not conducive to adequate bleaching of quartz and feldspar grains. Our study implies that ice-proximal supraglacial sediments from this region in NW Scotland reflect older ages of deposition, but dating YD sediments has not been possible.     

A sequential extraction to determine the distribution of apatite in granitoid soil mineral pools with application to weathering at the Hubbard Brook Experimental Forest,NH, USA

Mineral weathering in soils is an important source of many nutrients to forest ecosystems. Apatite, a Ca phosphate mineral, occurs in trace amounts in virtually all igneous and metamorphic rocks and is often found as small mineral inclusions in more weathering-resistant silicate minerals. To better understand the distribution of apatite in soils and its exposure to soil solutions, a sequential extraction method was developed to selectively dissolve minerals from soils so that the amount of apatite in contact with soil solutions versus that armored by silicate minerals could be quantified. The use of three molarities of HNO₃ (0.01, 0.1 and 1 M) at three temperatures (0, 10, or 20 °C) was explored and it was found that apatite congruently dissolved in 1 M HNO₃ at all three temperatures, but did not completely dissolve in weaker HNO₃ solutions. Soil horizons, glacial till (i.e., soil parent material), and individual minerals separated from till collected from the Hubbard Brook Experimental Forest (HBEF), NH, were subjected to a 4-step sequential extraction. Chemical analyses of the extracts indicate that 1 M NH₄Cl (pH 7; 20 °C) removes exchangeable ions, 1 M HNO₃ at 20 °C primarily dissolves apatite in contact with solutions, 1 M HNO₃ at 200 °C primarily dissolves biotite and chlorite (and apatite armored by them), and a mixture of concentrated HNO₃, HCl, and HF at 200 °C dissolves the more refractory minerals including muscovite, alkali feldspar, plagioclase feldspar and quartz (and apatite armored by these minerals). This extraction method was applied to soil profiles from HBEF to demonstrate that it could be used to interpret the abundance of apatite and other minerals as a function of depth. Approximately 70% of the apatite in the HBEF soil parent material is exposed to soil solutions; the remaining 30% is armored in more weathering-resistant micas and feldspars. In the upper soil horizons, the only apatite that has not been weathered from the soil occurs as inclusions in micas and feldspars and thus the rate of dissolution of apatite in weathered soil horizons is controlled by silicate mineral dissolution.     

Catchment contrasts: Comparing young people’s experiences and knowledge of a river environment

Early geographies focussed on children have recorded their environmental and spatial perceptions. Contemporary theoretical and methodological advances in, and beyond, children’s geographies have supported a more complex engagement with environmental topics. Complementing this work, a study of young people’s experience and knowledge of a river in southern New Zealand is presented. Data were gathered from four contrasting locations within one, 5650 sq. km, catchment, employing child-oriented, multi-method approaches. Data analysis confirms existing literature highlighting how young people are competent knowledge producers with varying experiences and understandings. Some of this variation can be appreciated by focussing on factors of age, gender and catchment location. Together these findings are relevant to both academic and planning circles and implications for young people’s participation in catchment management are noted as a key area for further development of work of this kind.