Active layer hydrology in an arctic tundra ecosystem: quantifying water sources and cycling using water stable isotopes

Climate change and thawing permafrost in the Arctic will significantly alter landscape hydro‐geomorphology and the distribution of soil moisture, which will have cascading effects on climate feedbacks (CO₂ and CH₄) and plant and microbial communities. Fundamental processes critical to predicting active layer hydrology are not well understood. This study applied water stable isotope techniques (δ²H and δ¹⁸O) to infer sources and mixing of active layer waters in a polygonal tundra landscape in Barrow, Alaska (USA), in August and September of 2012. Results suggested that winter precipitation did not contribute substantially to surface waters or subsurface active layer pore waters measured in August and September. Summer rain was the main source of water to the active layer, with seasonal ice melt contributing to deeper pore waters later in the season. Surface water evaporation was evident in August from a characteristic isotopic fractionation slope (δ²H vs δ¹⁸O). Freeze‐out isotopic fractionation effects in frozen active layer samples and textural permafrost were indistinguishable from evaporation fractionation, emphasizing the importance of considering the most likely processes in water isotope studies, in systems where both evaporation and freeze‐out occur in close proximity. The fractionation observed in frozen active layer ice was not observed in liquid active layer pore waters. Such a discrepancy between frozen and liquid active layer samples suggests mixing of meltwater, likely due to slow melting of seasonal ice. This research provides insight into fundamental processes relating to sources and mixing of active layer waters, which should be considered in process‐based fine‐scale and intermediate‐scale hydrologic models. Copyright © 2016 John Wiley & Sons, Ltd.     

Orthorectification of VHR optical satellite data exploiting the geometric accuracy of TerraSAR-X data

Orthorectification of satellite data is one of the most important pre-processing steps for application oriented evaluations and for image data input into Geographic Information Systems. Although high- and very high-resolution optical data can be rectified without ground control points (GCPs) using an underlying digital elevation model (DEM) to positional root mean square errors (RMSEs) between 3 m and several hundred meters (depending on the satellite), there is still need for ground control with higher precision to reach lower RMSE values for the orthoimages. The very high geometric accuracy of geocoded data of the TerraSAR-X satellite has been shown in several investigations. This is due to the fact that the SAR antenna measures distances which are mainly dependent on the terrain height and the position of the satellite. The latter can be measured with high precision, whereas the satellite attitude need not be known exactly. If the used DEM is of high accuracy, the resulting geocoded SAR data are very precise in their geolocation. This precision can be exploited to improve the orientation knowledge and thereby the geometric accuracy of the rectified optical satellite data. The challenge is to match two kinds of image data, which exhibit very different geometric and radiometric properties. Simple correlation techniques do not work and the goal is to develop a robust method which works even for urban areas, including radar shadows, layover and foreshortening effects. First the optical data have to be rectified with the available interior and exterior orientation data or using rational polynomial coefficients (RPCs). From this approximation, the technique used is the measurement of small identical areas in the optical and radar images by automatic image matching, using a newly developed adapted mutual information procedure followed by an estimation of correction terms for the exterior orientation or the RPC coefficients. The matching areas are selected randomly from a regular grid covering the whole imagery. By adjustment calculations, parameters from falsely matched areas can be eliminated and optimal improvement parameters are found. The original optical data are orthorectified again using the delivered metadata together with these corrections and the available DEM. As proof of method the orthorectified data from IKONOS and ALOS-PRISM sensors are compared with conventional ground control information from high-precision orthoimage maps of the German Cartographic Survey. The results show that this method is robust, even for urban areas. Although the resulting RMSE values are in the order of 2-6 m, the advantage is that this result can be reached even for optical sensors which do not exhibit low RMSE values without using manual GCP measurements.     

The evolution of spinel lherzolite xenoliths and the nature of the mantle at Kilbourne Hole,New Mexico

In peridotites, olivine, clinopyroxene, and orthopyroxene are complex solid solutions with wide stability fields. Depending mostly on bulk composition and pressure, these minerals may be accompanied by plagioclase (low pressure), spinel (moderate pressure), or garnet (high pressure), resulting in 4-phase and rarer 5-phase assemblages. Although a particular mineral assemblage is stable over a range of P–T, the compositions of the individual minerals vary with changing P–T conditions. Application of standard geothermobarometers to olivine–clinopyroxene–orthopyroxene–spinel peridotites is problematic. An alternative approach is to use a bulk rock composition to calculate equilibrium phase diagrams to determine the conditions under which a particular assemblage is stable. This requires consideration of the 7-component system SiO₂–Al₂O₃–Cr₂O₃–FeO–MgO–CaO–Na₂O, internally consistent thermodynamic data for end members, and reliable mixing models for all mineral solutions. Experimental studies in simpler systems, and solution models from the literature, permit derivation of multicomponent thermodynamic mixing models for the key minerals. The models, when applied to xenoliths from Kilbourne Hole, constrain P and T of equilibration and are less sensitive to mineral compositional variations, or uncertainty in activity models, than standard thermobarometry. Our modeling provides the first tightly constrained pressure estimates for Kilbourne Hole, placing the xenoliths in the spinel stability field at depths (30–45 km) that correspond to the uppermost mantle beneath the Rio Grande Rift. The fine-grained equigranular lherzolite, porphyroclastic lherzolite, and some harzburgite-dunite specimens equilibrated at average conditions of 11.5 Kbar-930°C, 12 Kbar-990°C, and 13 Kbar-1,080°C, respectively. The mantle beneath the Rio Grande Rift is layered; the fine-grained equigranular lherzolite derives from relatively shallow depth (35 km average), and the porphyroclastic lherzolite from slightly deeper levels. Lying 5–10 km beneath both lherzolites, the harzburgite-dunite represents a depth where melt extraction has significantly altered mantle chemistry and where local thermodynamic equilibrium has not been maintained.     

Old Crow tephra across eastern Beringia: a single cataclysmic eruption at the close of Marine Isotope Stage 6

Old Crow tephra is the largest and most widespread Quaternary eruption presently known in eastern Beringia. Its major- and trace-element geochemistry, Fe-Ti oxides, and stratigraphic and paleoecological context indicate that it is the result of a single cataclysmic eruption. The proximal region may well have experienced tephra fallout from small eruptions just prior to or after the Old Crow event, but there is no evidence to indicate that the distal area was affected. We recalculate the glass fission-track age at 124 ± 10 ka, which, coupled with stratigraphic and paleoenvironmental reconstructions, indicates that deposition occurred prior to development of the last interglacial boreal forest, which suggests a latest Marine Isotope Stage (MIS) 6 age. The bulk tephra volume erupted is estimated by three different approaches, that are in broad agreement at ～200 km³, but this result must be considered as tentative given the poor controls on definition of isopachs over such a large area. The source caldera, although presently unrecognized, is located in the eastern Aleutian arc, possibly at or near the Emmons Lake volcanic center.     

A 15 000‐year record of climate change in northern New Mexico,USA, inferred from isotopic and elemental contents of bog sediments

Elemental (C, N, Pb) and isotopic (δ¹³C, δ¹⁵N) measurements of cored sediment from a small bog in northern New Mexico reveal changes in climate during the Late Pleistocene and Holocene. Abrupt increases in Pb concentration and δ¹³C values ca. 14 420 cal. YBP indicate significant runoff to the shallow lake that existed at that time. Weathering and transport of local volcanic rocks resulted in the delivery of Pb‐bearing minerals to the basin, while a ¹³C‐enriched terrestrial vegetation source increased the δ¹³C values of the sedimentary material. Wet conditions developed over a 300 a period and lasted for a few hundred years. The Younger Dryas period (ca. 12 700–11 500 cal. YBP) caused a reduction in terrestrial productivity reflected in decreasing C/N values, δ¹⁵N values consistently greater than 0‰ and low organic content. By contrast, aquatic productivity increased during the second half of this period, evidenced by increasing δ¹³C values at the time of highest abundance of algae. Dry conditions ca. 8 000–6 000 cal. YBP were characterised by low organic carbon content and high Pb concentrations, the latter suggesting enhanced erosion and aeolian transport of volcanic rock. The range in δ¹³C, δ¹⁵N and C/N values in the sedimentary record fall within the range of modern plants, except during the periods of runoff and drought. The sedimentary record provides evidence of natural climate variability in northern New Mexico, including short‐ (multi‐centennial) and long‐(millennial) term episodes during the Late Pleistocene and Holocene. Copyright © 2010 John Wiley & Sons, Ltd.     

Stress and energy reflection from impact on rocks using different indentors

Experiments have been conducted using an impact method with drop-hammers to obtain the required signals so that a detailed analysis of these data could be undertaken to quantify the drillability index of rocks. The dynamic stress waveform or reflected energy from the rock-drill bit interface is represented as a drillability index. This information enables the assessment of the characteristics of the rock under the bit. The results show that neither the amplitude nor the frequency spectra of the reflected stress wave significantly changes with the type of rock tested. However, the energy reflection coefficient varies with rock hardness. In the process of drilling the rocks, the energy reflection coefficient can increase by approximately 20% when the hardness or penetration resistance index of rock is doubled. This investigation confirmed the variation of reflected energy of rocks. For a single sharp or domed indentor, energy reflection decreases with penetration resistance index of the rock while it increases with this index in actual drilling or testing of percussive bits. In drill bit design and in tests for using a single indentor, a reasonable indentor shape should be adopted to correspond to a high energy reflection coefficient. By contrast, the energy reflection from a drill system or percussive bit should be minimised in practice.     

The impact of discharges from seafood processing on southeastern estuaries

A study to determine the impact of seafood packing and processing effluents discharged to southeastern estuarine waters was conducted in July and August of 1979. The environmental impact of current seafood processing wastes on Georgia’s estuaries appears to be minimal when compared with the natural organic load. One large estuary demonstrated a high residual capacity to receive processing effluents without significant change. The BOD load from shrimp thawing, peeling, sorting, and cleaning operations at a large seafood processing plant was shown to be equivalent to the organic material generated by a 302 m² plot (57 ft×57 ft) of salt marsh. NH₄?N levels were greater than, but the same order of magnitude as, natural runoff from marsh land.     

Reinvestigation of fayalite+anorthite=garnet

The reaction fayalite+anorthite=garnet (GAF) has been investigated in a piston-cylinder apparatus and in an internally heated gas apparatus. Piston-cylinder reversals were obtained at 900 °C (6.0–6.4 kbar), 950 °C (6.3–6.8 kbar), 1000 °C (6.6–7.1 kbar), and 1050 °C (7.0–7.3 kbar). Gas-apparatus experiments yielded a reversal at 7 kbar (993–1049 °C). Results are consistent with earlier experimental studies. Unless garnet Ca–Fe mixing is attended by an excess entropy of at least 2–3 J/K-atom, discrepancies remain between calculated and experimentally determined slopes for GAF. The discrepancy is greater if there is no Al–Si disorder in anorthite. High temperature thermodynamic data for almandine and grossular are needed to help resolve this problem.