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51.
The world-class Idrija mercury deposit (western Slovenia) is hosted by highly deformed Permocarboniferous to Middle Triassic sedimentary rocks within a complex tectonic structure at the transition between the External Dinarides and the Southern Alps. Concordant and discordant mineralization formed concomitant with Middle Triassic bimodal volcanism in an aborted rift. A multiple isotopic (C, O, S) investigation of host rocks and ore minerals was performed to put constraints on the source and composition of the fluid, and the hydrothermal alteration. The distributions of the 13C and 18O values of host and gangue carbonates are indicative of a fracture-controlled hydrothermal system, with locally high fluid-rock ratios. Quantitative modeling of the 13C and 18O covariation for host carbonates during temperature dependent fluid-rock interaction, and concomitant precipitation of void-filling dolomites points to a slightly acidic hydrothermal fluid (13C–4 and 18O+10), which most likely evolved during isotopic exchange with carbonates under low fluid/rock ratios. The 34S values of hydrothermal and sedimentary sulfur minerals were used to re-evaluate the previously proposed magmatic and evaporitic sulfur sources for the mineralization, and to assess the importance of other possible sulfur sources such as the contemporaneous seawater sulfate, sedimentary pyrite, and organic sulfur compounds. The 34S values of the sulfides show a large variation at deposit down to hand-specimen scale. They range for cinnabar and pyrite from –19.1 to +22.8, and from –22.4 to +59.6, respectively, suggesting mixing of sulfur from different sources. The peak of 34S values of cinnabar and pyrite close to 0 is compatible with ore sulfur derived dominantly from a magmatic fluid and/or from hydrothermal leaching of basement rocks. The similar stratigraphic trends of the 34S values of both cinnabar and pyrite suggest a minor contribution of sedimentary sulfur (pyrite and organic sulfur) to the ore formation. Some of the positive 34S values are probably derived from thermochemical reduction of evaporitic and contemporaneous seawater sulfates.Editorial handling: P. Lattanzi 相似文献
52.
Gerd?RantitschEmail author Thomas?Rainer 《International Journal of Earth Sciences》2003,92(2):195-209
Vitrinite reflectance was measured in Late Carboniferous to Triassic shales, siltstones and marls of the Karawanken Range. Thermal models of the central South-Karawanken Range were calibrated on the basis of these data. They suggest an eroded overburden of more than 3,200 m of Jurassic to Cretaceous sediments and a heat flow in the range of 42 to 60 mW m?2 during the time of maximum subsidence. Because the reconstructed thermal history of the South-Karawanken Range is very similar to the thermal history of the Generoso basin (western Southern Alps), these data provide strong evidence for a deep basinal position of the Southern Karawanken Range during Jurassic to Cretaceous times. A vitrinite reflectance anomaly at the northern margin of the South-Karawanken Range is explained by advective heat transport during the Oligocene. The heat source for the anomalies at the western margin of the Seeberg Rise and in the area between the Periadriatic Lineament and the Donat Fault Zone is unknown. Vitrinite reflectance in Late Triassic sediments indicates the South-Karawanken Range and the South-Zala Unit of the Pannonian basement as exotic blocks in the Sava Composite Unit. This is explained by Miocene displacement of structural units, which were derived from different paleogeographical segments of the Permo-Mesozoic western Tethyan margin. 相似文献
53.
Release of heavy metals during weathering of the Lower Cambrian Black Shales in western Hunan,China 总被引:8,自引:0,他引:8
Bo?PengEmail author Zhaoliang?Song Xiangling?Tu Meilian?Xiao Fucheng?Wu Huanzhe?Lv 《Environmental Geology》2004,45(8):1137-1147
Weathering of heavy metal enriched black shales may be one of the most important sources of environmental contamination in areas where black shales are distributed. Heavy metal release during weathering of the Lower Cambrian Black Shales (LCBS) in western Hunan, China, was investigated using traditional geochemical methods and the ICP-MS analytical technique. Concentrations of 16 heavy metals, 8 trace elements and P were measured for samples from selected weathering profiles at the Taiping vanadium ore mine (TP), the Matian phosphorous ore mine (MT), and Taojiang stone-coal mine (TJ). The results show that the bedrock at these three profiles is enriched with Sc, V, Cr, Co, Ni, Cu, Zn, Pb, Th, U, Mo, Cd, Sb, Tl, and P. Based on mass-balance calculation, the percentages of heavy metals released (in % loss) relative to immobile element Nb were estimated. The results show significant rates of release during weathering of: V, Cr, Co, Ni, Cu, Zn, U, Mo, Cd, Sn, Sb, and Tl for the TP profile; Sc, Cr, Mn, Co, Ni, Cu, Zn, Pb, Th, Cd, and Sn for the MT profile; and Sc, Mn, Co, Ni, Zn, Th, Cd, Sn, and Tl for the TJ profile. Among these heavy metals, Co, Ni, Zn, Cd, and Sn show very similar features of release from each of the three weathering profiles. The heavy metals released during weathering may affect the environment (especially topsoil and surface waters) and are possibly related to an observed high incidence of endemic diseases in the area. 相似文献
54.
Stefanie?SchwarzEmail author Andreas?Klügel Cora?Wohlgemuth-Ueberwasser 《Contributions to Mineralogy and Petrology》2004,147(2):228-240
The Madeira and Desertas Islands (eastern North Atlantic) show well-developed rift zones which intersect near the eastern tip of Madeira (São Lourenço peninsula). We applied fluid inclusion barometry and clinopyroxene-melt thermobarometry to reconstruct levels of magma stagnation beneath the two adjacent rifts and to examine a possible genetic relationship during their evolution. Densities of CO2-dominated fluid inclusions in basanitic to basaltic samples from São Lourenço yielded frequency maxima at pressures of 0.57–0.87 GPa (23–29 km depth) and 0.25–0.32 GPa (8–10 km), whereas basanites, basalts and xenoliths from the Desertas indicate 0.3–0.72 GPa (10–24 km) and 0.07–0.12 GPa (2–3 km). Clinopyroxene-melt thermobarometry applied to Ti-augite phenocryst rim and glass/groundmass compositions indicates pressures of 0.45–1.06 GPa (15–35 km; São Lourenço) and 0.53–0.89 GPa (17–28 km; Desertas Islands) which partly overlap with pressures indicated by fluid inclusions. We interpret our data to suggest a multi-stage magma ascent beneath the Madeira Archipelago: main fractionation occurs at multiple levels within the mantle (>15 km depth) and is followed by temporary stagnation within the crust prior to eruption. Depths of crustal magma stagnation beneath São Lourenço and the Desertas differ significantly, and there is no evidence for a common shallow magma reservoir feeding both rift arms. We discuss two models to explain the relations between the two adjacent rift systems: Madeira and the Desertas may represent either a two-armed rift system or two volcanic centres with separate magma supply systems. For petrological and volcanological reasons, we favour the second model and suggest that Madeira and the Desertas root in distinct regions of melt extraction. Magma focusing into the Desertas system off the hotspot axis may result from lithospheric bending caused by the load of the Madeira and Porto Santo shields, combined with regional variations in melt production due to an irregularly shaped plume.Electronic Supplementary Material Supplementary material is available for this article if you access the article at . A link in the frame on the left on that page takes you directly to the supplementary material.Editorial responsibility: J. Hoefs 相似文献
55.
Instability and geotechnical problems of the Buddha niches and surrounding cliff in Bamiyan Valley,central Afghanistan 总被引:2,自引:0,他引:2
This paper describes the slope-instability processes and geological hazards affecting the historical site of Bamiyan, central Afghanistan, a major world-cultural heritage site. Here, two standing Buddhas carved in rock during the 2nd–4th centuries A.D. were destroyed by the Taliban in March 2001. There are very evident slope instabilities resulting from both explosions and natural processes: rock slides and rock falls had already occurred in the past and most areas are prone to collapse. Under the coordination of UNESCO, field data were collected and laboratory tests were performed to determine mechanisms for potential evolution of the cliff and niches. Areas of greatest instability, based on the field survey and data interpretation for both the small and great Buddha niches and surrounding cliff, were determined. This information helps to identify the most suitable method for restoration, in accord with the high cultural value of this site. 相似文献
56.
57.
A new estimate of global methane flux from onshore and shallow submarine mud volcanoes to the atmosphere 总被引:3,自引:0,他引:3
A new estimate of global methane emission into the atmosphere from mud volcanoes (MVs) on land and shallow seafloor is presented. The estimate, considered a lower limit, is based on 1) new direct measurements of flux, including both venting of methane and diffuse microseepage around craters and vents, and 2) a classification of MV sizes in terms of area (km2) based on a compilation of data from 120 MVs. The methane flux to the atmosphere is conservatively estimated between 6 and 9 Mt y–1. This emission from MVs is 3–6% of the natural methane sources and is comparable with ocean and hydrate sources, officially considered in the atmospheric methane budget. The total geologic source, including MVs, seepage from seafloor, microseepage in hydrocarbon-prone areas and geothermal sources, would amount to 35–45 Mt y–1. The authors believe it is time to add this parameter in the Intergovernmental Panel on Climate Change official tables of atmospheric methane sources.GEM 相似文献
58.
Jianping?Zheng W.?L.?GriffinEmail author Suzanne?Y.?O’Reilly Fengxiang?Lu Chunmei?Yu Ming?Zhang Huimin?Li 《Contributions to Mineralogy and Petrology》2004,148(1):79-103
Mafic xenoliths from the Paleozoic Fuxian kimberlites in the North China craton include garnet granulite, and minor pyroxene amphibolite, metagabbro, anorthosite and pyroxenite. The formation conditions of the amphibolites are estimated at 745–820 °C and 7.6–8.8 Kb (25–30 km); the granulites probably are derived from greater depths in the lower crust. LAM-ICPMS U–Pb dating of zircons from four granulites reveals multiple age populations, recording episodes of magmatic intrusion and metamorphic recrystallisation. Concordant ages and upper intercept ages, interpreted as minimum estimates for the time of magmatic crystallisation, range from 2,620 to 2,430 Ma in three granulites, two amphibolites and two metagabbros. Lower intercept ages, represented by near-concordant zircons, are interpreted as reflecting metamorphic recrystallisation, and range from 1,927 to 1,852 Ma. One granulite contains two metamorphic zircon populations, dated at 1,927±55 Ma and 600–700 Ma. Separated minerals from one granulite and one amphibolite yield Sm–Nd isochron ages of 1,619±48 Ma (143Nd/144Nd)i=0.51078), and 1,716±120 Ma (143Nd/144Nd)i=0.51006), respectively. These ages are interpreted as recording cooling following metamorphic resetting; model ages for both samples are in the range 2.40–2.66 Ga. LAM-MC-ICPMS analyses of zircon show a range in 176Hf/177Hf from 0.28116 to 0.28214, corresponding to a range of Hf from –34 to +12. The relationships between 207Pb/206Pb age and Hf show that: (1) the granulites, amphibolites and metagabbro were derived from a depleted mantle source at 2.6–2.75 Ga; (2) zircons in most samples underwent recrystallisation and Pb loss for 100–200 Ma after magmatic crystallisation, consistent with a residence in the lower crust; (3) metamorphic zircons in several samples represent new zircon growth, incorporating Hf liberated from breakdown of silicates with high Lu/Hf; (4) in other samples metamorphic and magmatic zircons have identical 176Hf/177Hf, and the younger ages reflect complete resetting of U–Pb systems in older zircons. The Fuxian mafic xenoliths are interpreted as the products of basaltic underplating, derived from a depleted mantle source in Neoarchean time, an important period of continental growth in the North China craton. Paleoproterozoic metamorphic ages indicate an important tectonic thermal event in the lower crust at 1.8–1.9 Ga, corresponding to the timing of collision between the Eastern and Western Blocks that led to the final assembly of the North China craton. The growth of metamorphic zircon at 600–700 Ma may record an asthenospheric upwelling in Neoproterozoic time, related to uplift and a regional disconformity in the North China craton. 相似文献
59.
Land cover change over the last three centuries due to human activities: The availability of new global data sets 总被引:15,自引:0,他引:15
Land use and land cover change is an important driver of global change (Turner et al., 1993). It is recognized that land use change has important consequences for global and regional climates, the global biogeochemical cycles such as carbon, nitrogen, and water, biodiversity, etc. Nevertheless, there have been relatively few comprehensive studies of global, long-term historical changes in land cover due to land use. In this paper, we review the development of global scale data sets of land use and land cover change. Furthermore, we assess the differences between two recently developed global data sets of historical land cover change due to land use. Based on historical statistical inventories (e.g. census data, tax records, land surveys, historical geography estimates, etc) and applying different spatial analysis techniques, changes in agricultural land cover (croplands, pastures) were reconstructed for the last 300 years. The two data sets indicate that cropland areas expanded from 3–4 million km2 in 1700 to 15–18 million km2 in 1990 (mostly at the expense of forests), while grazing land area expanded from 5 million km2 in 1700 to 31 million km2 in 1990 (mostly at the expense of natural grasslands). The data sets disagree most over Latin America and Oceania, and agree best over North America. Major differences in the two data sets can be explained by the use of a fractional versus Boolean approach, different modelling assumptions, and inventory data sets. 相似文献
60.
The extent of desertification on Saudi Arabia 总被引:2,自引:0,他引:2
Desertification is the process that turns productive deserts into non-productive deserts as a result of poor land-management. Desertification reduces the ability of land to support life, affecting wild species, domestic animals, agricultural crops and humans. The reduction in plant cover that accompanies desertification leads to accelerated soil erosion by wind and water. South Africa is losing approximately 300–400 million tons of topsoil every year. As vegetation cover and soil layer are reduced, rain fall impact and run-off increases. This paper discusses the extent of desertification, its potential threat to sustained irrigated agriculture and possible measures adopted to control ongoing desertification processes to minimize the loss of agricultural productivity in an arid country such as the Kingdom of Saudi Arabia. 相似文献