Zircon U–Pb geochronology of lower crust and quartzo-feldspathic clastic sediments from the Balagne ophiolite (Corsica)

The Balagne ophiolite from central-northern Corsica represents a continent-near paleogeographic domain of the Jurassic Liguria-Piedmont ophiolitic basin. Pillow and massive basalt lavas are primarily associated with Middle–Upper Jurassic pelagic sediments (mostly radiolarites at their base), continental-derived quartzo-feldspathic clastic sediments and ophiolitic breccias containing clasts of gabbros and basalts. The basalt-sedimentary succession is tectonically associated with a slice composed of an intrusive sequence overlain by basalt lavas. A “plagiogranite” from the intrusive sequence was dated by U–Pb zircon geochronology. Although affected by some uncertainty, mainly reflecting common Pb contamination, the U–Pb zircon data suggest a crystallization age of 159 ± 3 Ma (MSWD = 6.3), which is coeval with the formation of oceanic lower crust in the Schistes Lustrés units from Alpine Corsica. The predominance of quartz grains preserving typical volcanic shape, the prevalence of prismatic zircons and the arkose whole-rock composition indicate that the continental-derived quartzo-feldspathic clastic sediments have a low degree of textural maturity. U–Pb zircon geochronology carried out on two distinct levels of quartzo-feldspathic clastic sediments identified the predominance of zircons with within error U–Pb dates at ~280 Ma; minor components at ~457, ~309 and ~262 Ma were also obtained. The U–Pb date distribution is consistent with a source magmatic material mostly developed during the Variscan orogenic collapse.     

Seismicity assessment using earthquake catalogues with uncertain and incomplete data: probabilistic formulation

A novel generalized probabilistic formulation is proposed to assess seismicity using earthquake catalogues with uncertain and incomplete data. The seismicity, described by the complete exceedance rate of magnitudes, is estimated starting from a consistent incomplete exceedance rate which is rationally linked to the catalogue data. Complete and incomplete exceedance rates are represented by similar functional forms and they are related by a completeness function, which expresses the probability that an event is included in a data set. Completeness is considered uncertain and it is defined by a suitable, continuous, analytical, magnitude dependent function. The importance of this work lies on its applicability because it can be useful in seismic zones where information about seismic activity is scarce or simply when the catalogue is incomplete in a range of magnitudes that can have a significant influence on the seismic hazard analysis and on the resulting seismic risk assessment. Moreover, it can also be applied in the common case when the catalogue is considered complete above a given magnitude threshold. Numerical examples are presented to illustrate the influence of catalogue incompleteness on the complete exceedance rate estimations. In companion papers, attention is focused on the estimation of completeness probabilities of available catalogues and on parameter estimation of the exceedance rate functions.     

Diatoms from gut contents of museum specimens of an endangered minnow suggest long-term ecological changes in the Rio Grande (USA)

Diatoms consumed by Rio Grande silvery minnows (Hybognathus amarus) collected 104 years apart were used to deduce ecological requirements of this endangered species and to infer a possible cause of its decline based on environmental conditions in the Rio Grande. In 1874, foraged diatoms were largely motile, silt tolerant generalist and epipelic species (e.g. Navicula capitatoradiata, Navicula cryptotenella, Nitzschia palea, Sellaphora pupula) somewhat tolerant to pollution and indicative of eutrophic conditions, low dissolved oxygen, and high biological oxygen demand (BOD). In contrast, diatoms foraged in 1978 were mainly nonmotile epipsammic species (Fragilariaceae) sensitive to pollution and characteristic of low nutrient, oligotrophic conditions with high dissolved oxygen and low BOD. The large-scale difference in composition of the foraged diatom assemblages is consistent with a decline in nutrients and a shift in trophic state commonly associated with river regulation by dams. The results suggest that facilitating allochthonous input of detritus and nutrients into the Rio Grande ecosystem to meet foraging requirements for algivorous and detritivorous fish species such as H. amarus would be a good river restoration strategy.     

Building of the deepest crust at a fossil slow-spreading centre (Pineto gabbroic sequence, Alpine Jurassic ophiolites)

This work presents new field and petrological data on a poorly known lower crustal section from the Alpine Jurassic ophiolites, the Pineto gabbroic sequence from Corsica (France). The Pineto gabbroic sequence is estimated to be ~1.5 km thick and mainly consists of clinopyroxene-rich gabbros to gabbronorites near its stratigraphic top and of troctolites and minor olivine gabbros in its deeper sector. The sequence also encloses olivine-rich troctolite and mantle peridotite bodies at different stratigraphic heights. The composition and the lithological variability of the Pineto gabbroic sequence recall those of the lower crustal sections at slow- and ultra-slow-spreading ridges. The gabbroic sequence considered in this study is distinct in the high proportion of troctolites and olivine gabbros, which approximately constitute 2/3 of the section. In particular, the lower sector of the Pineto gabbroic sequence shows the existence of large-scale fragments of the deepest oceanic crust displaying a highly primitive bulk composition. The mineral chemical variations document that the origin and the evolution of the Pineto gabbroic rocks were mostly constrained by a process of fractional crystallisation. The clinopyroxenes from the olivine gabbros and the olivine-rich troctolites also record the infiltration of olivine-dissolving, Cr₂O₃-rich melts that presumably formed within the mantle, into replacive dunite bodies. Cooling rates of the troctolites and the olivine gabbros were evaluated using the Ca in olivine geospeedometer. We obtained high and nearly constant values of ?2.2 to ?1.7 °C/year log units, which were correlated with the building of the Pineto gabbroic sequence through multiple gabbroic intrusions intruded into a cold lithospheric mantle.     

Coral- and oyster-microbialite patch reefs in the aftermath of the Triassic–Jurassic biotic crisis (Sinemurian,Southeast France)

The end of the Triassic and the Early Jurassic are intervals characterised by profound biotic and environmental changes, accompanied by dramatic decreases in marine fauna diversity. Corals were strongly affected and assemblages underwent a severe reduction; compared with those of the Upper Triassic, the Early Jurassic is traditionally defined as holding a “reef gap”. A Sinemurian coral-microbialites patch reef, located in southern France in the Hérault department (Le Perthus locality), is here described. This bioconstruction developed in a shallow mixed siliciclastic-carbonate inner ramp setting. The reef volume is composed of up to 70% of an intercoral facies mostly microbialites, with subordinated sediments (approximately 20–30% of the intercoral facies). Therefore, the patch reef can be defined as a coral-microbialite bioconstruction, in which microbialites were the main framebuilders. The coral assemblage has low diversity and is dominated by massive to branching colonies of Chondrocoenia clavellata. This highlights the reef diversity after the T/J boundary crisis. The Le Perthus patch reef could have acted as an edge for the dominant currents and probably induced reductions in hydrodynamic energy and sedimentation on one of its sides. Consequently, it could have triggered the growth of small lateral bioconstructions, composed of oysters and microbialites, uniquely on one of its sides. The evolution of the facies shows that the Le Perthus patch reef grew in a shallowing-upward setting accompanied by an increase in siliciclastic inputs. The rate of bioerosion and the faunal assemblage suggest that the bioconstructions could have been developed in a mesotrophic environment.     

Oxygen isotope fractionation between apatite-bound carbonate and water determined from controlled experiments with synthetic apatites precipitated at 10-37 °C

The oxygen isotope fractionation between the structural carbonate of inorganically precipitated hydroxyapatite (HAP) and water was determined in the range 10-37 °C. Values of 1000 ln α() are linearly correlated with inverse temperature (K) according to the following equation: 1000 ln α() = 25.19 (±0.53)·T⁻¹ − 56.47 (±1.81) (R² = 0.998). This fractionation equation has a slightly steeper slope than those already established between calcite and water ( [O’Neil et al., 1969] and [Kim and O’Neil, 1997]) even though measured fractionations are of comparable amplitude in the temperature range of these experimental studies. It is consequently observed that the oxygen isotope fractionation between apatite carbonate and phosphate increases from about 7.5‰ up to 9.1‰ with decreasing temperature from 37 °C to 10 °C. A compilation of δ¹⁸O values of both phosphate and carbonate from modern mammal teeth and bones confirms that both variables are linearly correlated, despite a significant scattering up to 3.5‰, with a slope close to 1 and an intercept corresponding to a 1000 ln α() value of 8.1‰. This apparent fractionation factor is slightly higher or close to the fractionation factor expected to be in the range 7-8‰ at the body temperature of mammals.     

The caranto paleosol and its role in the early urbanization of Venice

As rising sea level threatens Venice, there is a need to construct a historical framework for interpreting modern environmental changes. Environmental conditions that would later help support Venice's urbanization were established during the Late Glacial period when calcic soils began to develop in the Venetian alluvial paleoplain. A calcic paleosol, buried by Middle to Late Holocene marine transgressive deposits, represents a subsurface layer long known in the Venice area as “caranto.” Referenced in the ancient chronicles of architects and builders, the caranto exhibits relatively high compressive and shear strength, making it an important substrate for supporting building foundations, some dating back to the Gothic era (12th–15th centuries A.D.). Hence, the caranto paleosol documents local post‐glacial environmental changes while playing an important role in Venetian building construction and human settlement. Here we provide geochemical, sedimentological, paleoecological, and chronological analyses of the caranto paleosol and related deposits based on recent coring of the Venetian Lagoon. © 2011 Wiley Periodicals, Inc.