Experimental biological effects assessment associated with on-shore brine discharge from the creation of gas storage caverns

Most of the studies on biological and ecological effects associated with brine discharge into the marine environment are related to the operation of desalination plants, for the production of freshwater. In this study we analysed the biological effects of a brine effluent from a completely different source, produced from the lixiviation of rock salt caves, for the creation of natural gas storage caverns. Lethal and sub-lethal endpoints following exposure to the brine were studied in a range of macrofauna species characteristic of the soft and hard bottom habitats in the vicinity of the discharge area, namely the isopod Eurydice pulchra, the annelids Sabellaria alveolata and Ophelia radiata, the sea-urchin Paracentrotus lividus and the bivalve Mytilus galloprovincialis. In a first series of experiments, brine, with salinity above 300, was diluted in distilled water to a salinity value close to that of the seawater in the discharge area (salinity 36) and, surprisingly, none of the exposed species was able to survive or develop into viable larvae. A second series of experiments exposed the species to brine diluted with seawater, simulating more realistic discharge circumstances. All the tested species at all the measured endpoints (adult survival, larval abnormal development, sperm fertilization success) showed negative biological effects in brine solutes always at a lower salinity than that of a salinity control obtained with concentrated seawater. The sub-lethal experiments with larval development of P. lividus, S. alveolata and M. galloprovincialis, and the fertilization success of P. lividus gave EC₅₀ values for the brine solute with salinity in the range of 40.9–43.5, whereas the EC₅₀ values for the concentrated seawater were in the range of salinity 44.2–49.0. It is hypothesised that differences in the ionic composition of the brine cause the inability of the species to tolerate the exposure to brine.     

Marsh benthic Foraminifera response to estuarine hydrological balance driven by climate variability over the last 2000 yr (Minho estuary,NW Portugal)

A high-resolution study of a marsh sedimentary sequence from the Minho estuary provides a new palaeoenvironmental reconstruction from NW Iberian based on geological proxies supported by historical and instrumental climatic records. A low-salinity tidal flat, dominated by Trochamminita salsa, Haplophragmoides spp. and Cribrostomoides spp., prevailed from AD 140–1360 (Roman Warm Period, Dark Ages, Medieval Climatic Anomaly). This sheltered environment was affected by high hydrodynamic episodes, marked by the increase in silt/clay ratio, decrease of organic matter, and poor and weakly preserved foraminiferal assemblages, suggesting enhanced river runoff. The establishment of low marsh began at AD 1380. This low-salinity environment, marked by colder and wet conditions, persisted from AD 1410–1770 (Little Ice Age), when foraminiferal density increased significantly. Haplophragmoides manilaensis and Trochamminita salsa mark the transition from low to high marsh at AD 1730. Since AD 1780 the abundances of salt marsh species (Jadammina macrescens, Trochammina inflata) increased, accompanied by a decrease in foraminiferal density, reflecting climate instability, when droughts alternate with severe floods. SW Europe marsh foraminifera respond to the hydrological balance, controlled by climatic variability modes (e.g., NAO) and solar activity, thus contributing to the understanding of NE Atlantic climate dynamics.     

Type of volcanoes hosting the massive sulfide deposits of the Iberian Pyrite Belt

The Volcanic Sedimentary Complex (VSC) of the Iberian Pyrite Belt (IPB) in southern Portugal and Spain, comprises an Upper Devonian to Lower Carboniferous submarine succession with a variety of felsic volcanic lithofacies. The architecture of the felsic volcanic centres includes felsic lavas/domes, pyroclastic units, intrusions and minor mafic units that define lava–cryptodome–pumice cone volcanoes. The diversity of volcanic lithofacies recognized in different areas of the IPB mainly reflects variations in proximity to source, but also differences in the eruption style. The IPB volcanoes are intrabasinal, range in length from 2 km to > 8 km and their thickest sections vary from ∼ 400 m to > 800 m. These volcanoes are dominated by felsic lavas/domes that occur at several stratigraphic positions within the volcanic centre, however the pyroclastic units are also abundant and are spatially related to the lavas/domes. The intrusions are minor, and define cryptodomes and partly-extrusive cryptodomes. The hydrothermal systems that formed the Neves Corvo and Lousal massive sulfide ore deposits are associated with effusive units of felsic volcanic centres. At Neves Corvo, the massive sulfide orebodies are associated to rhyolitic lavas that overlie relatively thick fiamme-rich pyroclastic unit. In several other locations within the belt, pyroclastic units contain sulfide clasts that may have been derived from yet to be discovered coeval massive sulfide deposits at or below the sea floor, which enhances the exploration potential of these pyroclastic units and demonstrates the need for volcanic facies analysis in exploration.     

Functional outlier detection by a local depth with application to NO<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript> levels

This paper proposes methods to detect outliers in functional data sets and the task of identifying atypical curves is carried out using the recently proposed kernelized functional spatial depth (KFSD). KFSD is a local depth that can be used to order the curves of a sample from the most to the least central, and since outliers are usually among the least central curves, we present a probabilistic result which allows to select a threshold value for KFSD such that curves with depth values lower than the threshold are detected as outliers. Based on this result, we propose three new outlier detection procedures. The results of a simulation study show that our proposals generally outperform a battery of competitors. We apply our procedures to a real data set consisting in daily curves of emission levels of nitrogen oxides (NO\(_{x}\)) since it is of interest to identify abnormal NO\(_{x}\) levels to take necessary environmental political actions.     

Microbiological composition of native and exotic clams from Tagus estuary: Effect of season and environmental parameters

The influence of seasonal and environmental parameters on the occurrence of bacteria was investigated in two clam species (Venerupis pullastra and Ruditapes philippinarum), water and sediment from the Tagus estuary. Total viable counts (TVC), Escherichia coli, Salmonella spp. and Vibrio spp. were evaluated during one-year. Overall, significant seasonal variations were found in both sampling sites, especially for E. coli and Vibrio spp. levels. In summer, significantly higher Vibrio spp. levels were found in R. philippinarum and sediment samples, but not in V. pullastra clams and water samples. In contrast, significantly higher TVC and E. coli levels were observed in winter months in water and sediment samples. Salmonella spp. was generally isolated when higher levels of E. coli were detected, particularly in R. philippinarum. This study is useful for authorities to develop monitoring strategies for coastal contamination and to estimate human health risks associated with the consumption of bivalves.     

A method for assessing kinematic bending moments at the pile head

The conventional design methods for seismically loaded piles still concentrate in providing adequate resistance from the pile to withstand only the inertial bending moments generated from the oscillation of the superstructure, thus neglecting the effect of kinematic interaction between pile and soil. By contrast there has been extensive research on kinematic effects induced by earthquakes and a number of simplified methods are available for a preliminary evaluation of kinematic bending moments at the interface between two soil layers. Less attention has been paid to the effects of kinematic interaction at the pile‐head. The paper summarizes recent research work on kinematic response analysis of fixed‐head piles aimed at the performance evaluation of a piled foundation. Results from an extensive parametric study, undertaken by means of three‐dimensional FE analyses, suggest a new criterion to predict kinematic bending effects at the pile head, where the combination of kinematic and inertial effect may be critical. Copyright © 2010 John Wiley & Sons, Ltd.     

Generalized thermostatistics and wavelet analysis of solar wind and proton density variability

In this paper, we analyze the probability density function (PDF) of solar wind velocity and proton density, based on generalized thermostatistics (GT) approach, comparing theoretical results with observational data. The time-series analyzed were obtained from the SOHO satellite mission where measurements were sampled every hour. We present in the investigations data for two years of different solar activity: (a) moderate activity (MA) period (1997) and (b) high activity (HA) period (2000). For the MA period, the results show good agreement between experimental data and GT model. For the HA period, the agreement between experimental and theoretical PDFs was fairly good, but some distortions were observed, probably due to intermittent characteristics of turbulent processes. As a complementary analysis, the global wavelet spectrum (GWS) was obtained, allowing the characterization of the predominant temporal variability scales for both periods and the stochastic aspects of the nonlinear solar wind variability are discussed.     

Geochemistry and geothermometry of volcanic rocks from Serra Branca, Iberian Pyrite Belt, Portugal

Volcanic rocks from Serra Branca, Iberian Pyrite Belt, Portugal, consist of calc-alkaline felsic and intermediate rocks. The latter are massive andesites, whereas the former include four dacitic to rhyolitic lithologies, distinguishable on spiderdiagrams and binary plots of immobile elements. Zircon thermometry indicates that two felsic suites may have formed from different magmas produced at distinct temperatures, with only limited fractionation within each suite. Alternatively, all the felsic rocks can be related through fractionation of a single magma if the lower zircon saturation temperature obtained for one suite merely results from Zr dilution, mostly reflecting silicification.

The relatively high magma temperatures at Serra Branca ease the classification of felsic rocks based on their HFSE contents and also indicate volcanogenic massive sulfide deposit favorability. This contrasts with other areas of the Belt that register lower magma temperatures and are subsequently barren. However, magma temperatures may have not been high enough to cause complete melting of refractory phases in which HFSE reside during crustal fusion of an amphibolite protolith, implying difficult discrimination of tectonic environments for the felsic rocks. The intermediate rocks were possibly formed by mixing between basaltic magmas and crustal material, compatible with volcanism in an attenuated continental lithosphere setting.