Druse clinopyroxene in D'Orbigny angritic meteorite studied by single‐crystal X‐ray diffraction,electron microprobe analysis,and Mössbauer spectroscopy

Abstract— The crystal structure of druse clinopyroxene from the D'Orbigny angrite, (Ca_0.944 Fe²⁺_0.042 Mg_0.010Mn_0.004) (Mg_0.469Fe²⁺_0.317Fe³⁺_0.035Al_0.125Cr_0.010Ti_0.044) (Si_1.742Al_0.258) O₆, a = 9.7684(2), b = 8.9124(2), c = 5.2859(1) Å, β = 105.903(1)°, V = 442.58 ų, space group C2/c, Z = 2, has been refined to an R₁ index of 1.92% using single‐crystal X‐ray diffraction data. The unit formula, calculated from electron microprobe analysis, and the refined site scattering values were used to assign site populations. The distribution of Fe²⁺and Mg over the M1 and M2 sites suggests a closure temperature of 1000 °C. Mössbauer spectroscopy measurements were done at room temperature on a single crystal and a powdered sample. The spectra are adequately fit by a Voigt‐based quadrupole‐splitting distribution model having two generalized sites, one for Fe²⁺with two Gaussian components and one for Fe³⁺with one Gaussian component. The two ferrous components are assigned to Fe²⁺at the M1 site, and arise from two different next‐nearest‐neighbor configurations of Ca and Fe cations at the M2 site: (3Ca,0Fe) and (2Ca,1Fe). The Fe³⁺/Fe_tot ratio determined by Mössbauer spectroscopy is in agreement with that calculated from the electron microprobe analysis. The results are discussed in connection with the redox and thermal history of D'Orbigny.     

Rare earth elements in groundwater from different Alpine aquifers

Rare earth elements (REE) were determined in 39 groundwater samples collected at 14 sites under low- and high-flow conditions. Water samples derived from aquifers hosted in crystalline, molasse, flysch, carbonate and evaporite rocks located in Western Switzerland. The concentration of REE in groundwater circulating in different rocks showed large variations: lowest concentrations (ΣREE≤10 ng/L) occurred in groundwater from evaporite aquifers; highest concentrations (ΣREE up to 516 ng/L) were observed in carbonate aquifers, although REE in these waters do vary under different hydrological conditions; groundwater from other aquifers had ΣREE from 10 to 100 ng/L. Distinct REE signatures were observed in waters draining specific rocks. The REE patterns in groundwater from crystalline, molasse and flysch aquifers showed heavy-REE enrichment at different degrees. Groundwaters circulating in crystalline rocks were distinguished by negative anomalies in Ce and Eu, whereas those from carbonate aquifers were nearly flat with ΣREE and the magnitude of negative anomaly in Ce is likely to be controlled by iron concentrations. The REE-Post-Archean Australian Shales (PAAS) normalized patterns appear useful to recognize the aquifer type and suggest the possibility to use the REE as geochemical tracers.     

Understanding the behaviour of X-shooter via the application of a physical model

We show how traditional instrument quality control trending can be augmented by the use of a physical instrument model. The ESO VLT archive contains a detailed record of instrument diagnostics and calibration parameters while ESO quality control monitors changes in critical parameters. The physical model allows changes in positions, orientations and other physical properties of a spectrograph to be determined from standard wavelength calibration exposures via an optimisation process that seeks the physical model parameters that best reproduce the calibration features in the data. We introduce physical model parameters to the quality control monitoring. When applying this technique to archived calibration exposures, we find that the results are sensitive to the combination of parameters open to the optimisation process. Therefore we determine the most favourable set of physical parameters to optimise for each arm. We then show correlations between several physical parameters and instrument temperature sensor readings and epoch. In addition we find clear discontinuities in some physical parameter values that correspond to known maintenance events.     

A methodological approach for estimating turbidity in a river

During the operations of purging and disposal of sediments of a reservoir it is necessary to know the values of turbidity in the river downstream in natural condition,in the absence of dams or river training works.The paper shows that under these conditions the ratio of the average values of sediment discharge to the annual maximum value of water discharge is a function of the average annual turbidity.Turbidity can be considered as representative synthetic index of the climatic conditions,the lithological features and the land cover of the basin,and the geometric characteristics of the river network.The proposed relationship of sediment discharge as a function of water discharge were validated on the basis of data collected from different Italian regions that have very different morphological,geo-lithological and rainfall features and that are characterised by a basin area changing between a few dozen and thousands of square kilometres.The results can be considered satisfying.     

Cooperative evolutionary algorithm for space trajectory optimization

A hybrid evolutionary algorithm which synergistically exploits differential evolution, genetic algorithms and particle swarm optimization, has been developed and applied to spacecraft trajectory optimization. The cooperative procedure runs the three basic algorithms in parallel, while letting the best individuals migrate to the other populations at prescribed intervals. Rendezvous problems and round-trip Earth–Mars missions have been considered. The results show that the hybrid algorithm has better performance compared to the basic algorithms that are employed. In particular, for the rendezvous problem, a 100% efficiency can be obtained both by differential evolution and the genetic algorithm only when particular strategies and parameter settings are adopted. On the other hand, the hybrid algorithm always attains the global optimum, even though nonoptimal strategies and parameter settings are adopted. Also the number of function evaluations, which must be performed to attain the optimum, is reduced when the hybrid algorithm is used. In the case of Earth–Mars missions, the hybrid algorithm is successfully employed to determine mission opportunities in a large search space.     

Thermal isostasy and deformation of possible paleoshorelines on Mars

Variations in martian surface heat flow, similar to those observed in terrestrial continental tectonothermally stable areas, could result in elevation differences of kilometric scale through differential thermal isostasy. This effect is enhanced with the increase of heat sources located within the crust. Local differences in the thermal history of the Mars’ lithosphere could have appreciably distorted the original long-wavelength topography of putative martian paleoshorelines. So, this work shows that a paleoequipotential surface does not necessarily have to fit well a present-day equipotential surface when evaluating paleoshorelines through assessment of high-resolution topography.     

Deformation patterns in a high-viscosity lava flow inferred from the crystal preferred orientation and imbrication structures: an example from Salina (Aeolian Islands,southern Tyrrhenian Sea,Italy)

Shape-preferred orientation and imbrication structures of crystals have been measured on samples representative of the base, centre and top of a highly viscous lava flow on Salina (Aeolian Islands, southern Tyrrhenian Sea). The data allow zones with different deformation patterns to be identified. In the base and top of the flow, deformation leads to the development of discrete preferred orientation and imbrication of the elongate crystals. The sense of shear is right-lateral at the base and left-lateral at the top of the flow. Shear strain can be estimated by the analysis of crystal preferred orientation. Deformation increases from the flow centre to the outer, more viscous boundary layers. Random orientation of crystals in the inner zone supports the presence of plug flow in a pseudoplastic lava. The textural features of the studied lava may be related to different mechanisms (i.e. lateral expansion). We conclude that the observed crystal alignments and imbrication structures may be related to a plug flow moving between two non-deforming walls. The walls are represented by the solidified, broken upper and basal crust of the flow. The low shear strain values calculated in the outer margins of the flow are indicative of the last deformation event. Crystal preferred orientation and imbrication structures may be related to the occurrence of velocity gradients existing between the inner zone of the flow and its solidus or near-solidus outer margins.