Can a pollution event be detected using a single biological effects monitoring method?

The trends of malformation prevalence in embryos of dab, Limanda limanda, in the southern North Sea after the year 1990 mirrored the drop in major pollutants in the rivers draining into the German Bight. Despite this general decline, we detected a pollution event in the southern North Sea in winter 1995/1996 employing the prevalence of malformations in pelagic dab embryos as an indicator. An abrupt rise in malformation prevalence in the embryos of dab, corresponded to a dramatic increase in DDT levels in parent fish from the same area, indicating a hitherto unnoticed introduction of considerable quantities of DDT into the system.     

Modelling the variability of midlatitude storm activity on decadal to century time scales

The output of several multi-century simulations with a coupled ocean–atmosphere general circulation model is examined with respect to the variability of global storm activity in winter on time scales of decades and longer. The frequency of maximum wind speed events within a grid box, using the lower limits on the Beaufort wind speed scale of 8 and 10 Bft as thresholds, is taken as the characteristic parameter. Two historical climate runs with time-dependent forcing of the last five centuries, one control simulation, and three climate change experiments are considered. The storm frequency shows no trend until recently. Global maps for the industrially influenced period hardly differ from pre-industrial maps, even though significant temperature anomalies temporarily emerge in the historical runs. Two indicators describing the frequency and the regional shift of storm activity are determined. In historical times they are decoupled from temperature. Variations in solar and volcanic forcing in the historical simulations as well as in greenhouse gas concentrations for the industrially influenced period are not related to variations in storm activity. Also, anomalous temperature regimes like the Late Maunder Minimum are not associated with systematic storm conditions. In the climate change experiments, a poleward shift of storm activity is found in all three storm track regions. Over the North Atlantic and Southern Ocean, storm activity increases, while it decreases over the Pacific Ocean. In contrast to the historical runs, and with the exception of the North Pacific storm frequency index, the storm indices parallel the development of temperature, exceeding the 2 σ-range of pre-industrial variations in the early twenty-first century.     

Improved magnetic anomalies of the Antarctic lithosphere from satellite and near-surface data

The Antarctic magnetic anomaly map compiled marine and airborne surveys collected south of 60°S through 1999 and used Magsat data to help fill in the regional gaps between the surveys. Ørsted and CHAMP satellite magnetic observations with greatly improved measurement accuracies and temporal and spatial coverage of the Antarctic, have now supplanted the Magsat data. We combined the new satellite observations with the near-surface survey data for an improved magnetic anomaly map of the Antarctic lithosphere. Specifically, we separated the crustal from the core and external field components in the satellite data using crustal thickness variations estimated from the terrain and the satellite-derived free-air gravity observations. Regional gaps in the near-surface surveys were then filled with predictions from crustal magnetization models that jointly satisfied the near-surface and satellite crustal anomalies. Comparisons in some of the regional gaps that also considered newly acquired aeromagnetic data demonstrated the enhanced anomaly estimation capabilities of the predictions over those from conventional minimum curvature and spherical harmonic geomagnetic field models. We also noted that the growing number of regional and world magnetic survey compilations involve coverage gaps where these procedures can contribute effective near-surface crustal anomaly estimates.     

Trace element zoning in pyroxenes from ODP Hole 735B gabbros: diffusive exchange or synkinematic crystal fractionation?

Major and trace element profiles of clinopyroxene grains in oceanic gabbros from ODP Hole 735B have been investigated by a combined in situ analytical study with ion probe, and electron microprobe. In contrast to the homogeneous major element compositions, trace elements (REE, Y, Cr, Sr, and Zr) show continuous core to rim zoning profiles. The observed trace element systematics in clinopyroxene cannot be explained by a simple diffusive exchange between melts and gabbros along grain boundaries. A simultaneous modification of the melt composition is required to generate the zoning, although Rayleigh fractional crystallization modelling could mimic the general shape of the profiles. Simultaneous metasomatism between the cumulate crystal and the porous melt during crystal accumulation is the most likely process to explain the zoning. Deformation during solidification of the crystal mush could have caused squeezing out of the incompatible element enriched residual melts (interstitial liquid). Migration of the melt along grain boundaries might carry these melt out of the system. This process named as synkinematic differentiation or differentiation by deformation (Natland and Dick in J Volcanol Geotherm Res 110(3–4):191–233, 2001) may act as an important magma evolution mechanism in the oceanic crust, at least at slow-spreading ridges.     

Upper-mantle structure of the Baltic Shield below the Swedish National Seismological Network (SNSN) resolved by teleseismic tomography

Upper-mantle structure under the Baltic Shield is studied using non-linear high resolution teleseismic P -phase tomography. Observed relative arrival-time residuals from 52 teleseismic earthquakes recorded by the Swedish National Seismological Network (SNSN) are inverted to delineate the structure of the upper mantle. The network consists of 47 (currently working) three-component broad-band stations located in an area about 450 km wide and 1450 km long. In order to reduce complications due to possible significant three-dimensionality of Earth structure, events chosen for this study lay close to in-line with the long-axis of the array  (±30°)  . Results indicate P -wave velocity perturbations of ±3 per cent down to at least 470 km below the network. The size of the array allows inversion for structures even at greater depths, and lateral variations of velocity at depths of up to 680 km appear to be resolved. Below the central part of the array (60°–64° N), where ray coverage is best, the data reveals a large region of relatively low velocity at depths of over about 300 km. At depths less than about 250–300 km, the models include a number of features, including an apparent slab-like structure dipping gently towards the north.     

Dual models of pore spaces

We present a model for pore spaces that consists of two parts related by duality: (1) a decomposition of an open polyhedral pore space into open contractible pore bodies separated by relatively open interfaces and (2) a pore network that is homotopy equivalent to the pore space. The dual model is unique and free of parameters, but it relies on regularity conditions for the pore space. We show how to approximate any pore space by the interior of a polyhedral complex such that the regularity conditions are fulfilled. Thus, we are able to calculate the dual model from synthetic porous media and images of real porous media. The pore bodies are unions of relatively open Delaunay cells with respect to the corners of the pore boundary, and the pore network consists of certain at most two-dimensional (2D) Voronoi cells with respect to the corners of the pore boundary. The pore network describes the neighborhood relations between the pore bodies. In particular, any relatively open 2D Delaunay face f separating two pore bodies has a unique (relatively open) dual network edge. In our model, f is a pore throat only if it is hit by its dual network edge. Thus, as opposed to widespread intuition, any pore throat is convex, and adjacent pore bodies are not necessarily separated by pore throats. Due to the duality between the pore network and the decomposition of the pore space into pore bodies it is straightforward to store the geometrical properties of the pore bodies [pore throats] as attributes of the dual network vertices [edges]. Such an attributed network is used to perform 2D drainage simulations. The results agree very well with those from a pore-morphology based modeling approach performed directly on the digital image of a porous medium. Contractibility of the pore bodies and homotopy equivalence of the pore space and the pore network is proven using discrete Morse theory and the nerve theorem from combinatorial topology.     

Unravelling the pre-Variscan evolution of the Habach terrane (Tauern Window, Austria) by U-Pb SHRIMP zircon data

The U-Pb SHRIMP age determinations of zircons from the Habach terrane (Tauern Window, Austria) reveal a complex evolution of this basement unit, which is exposed in the Penninic domain of the Alpine orogen. The oldest components are found in zircons of a metamorphosed granitoid clast, of a migmatitic leucosome, and of a meta-rhyolitic (Variscan) tuff which bear cores of Archean age. The U-Pb ages of discordant zircon cores of the same rocks range between 540 and 520 Ma. It is assumed that the latter zircons were originally also of Archean origin and suffered severe lead loss, whilst being incorporated into Early-Cambrian volcanic arc magmas. The provenance region of the Archean (2.64-2.06 Ga) zircons is assumed to be a terrane of Gondwana affinity: i.e., the West African craton (Hoggar Shield, Reguibat Shield). The Caledonian metamorphism left a pervasive structural imprint in amphibolite facies on rocks of the Habach terrane; it is postdated by discordant zircons of a migmatitic leucosome at <440 Ma (presumably ca. 420 Ma). Alpine and Variscan upper greenschist- to amphibolite-facies conditions caused partial lead loss in zircons of a muscovite gneiss ('white schist') only, where extensive fluid flow and brittle deformation due to its position near a nappe-sole thrust enhanced the grains' susceptibility to isotopic disturbance. The Habach terrane - an active continental margin with ensialic back-arc development - showed subduction-induced magmatic activity approx. between 550 and 507 Ma. Back-arc diorites and arc basalts were intruded by ultramafic sills and subsequently by small patches of mantle-dominated unaltered and (in the vicinity of a major tungsten deposit) altered granitoids. Fore-arc (shales) and back-arc (greywackes, cherts) basin sediments as well as arc and back-arc magmatites were not only nappe-stacked by the Caledonian compressional regime closing the presumably narrow oceanic back-arc basin and squeezing mafic to ultramafic cumulates out of high-level magma chambers (496-482 Ma). It also induced uplift and erosion of deeply rooted crystalline complexes and triggered the development of a successor basin filled with predominantly clastic greywacke-arkosic sediments. The study demonstrates that the basement rocks exposed in the Habach terrane might be the 'missing link' between similar units of the more westerly positioned External domain (i.e., Aar, Aiguilles Rouges, Mont Blanc) and the Austroalpine domain to the east (Oetztal, Silvretta).     

Phase relations of a serpentine composition between 5 and 14 GPa: significance of clinohumite and phase E as water carriers into the transition zone

Run products from high pressure experiments at 800-1,200 °C and 5-14 GPa (corresponding to depths of 150 to 420 km) on a serpentine bulk composition [close to Mg₃Si₂O₅(OH)₄] were analysed by optical microscopy, micro-Raman spectroscopy and electron microprobe. All charges exhibit strong chemical zoning. Fluid, melt and hydrous solids were mostly concentrated at the top, bottom and along the wall of the capsules. The central part of the charge was devoid of H₂O. Both fluid and hydrous magnesian phases exhibit a Mg/Si ratio higher than forsterite. In contrast, the centre of the capsule was enriched in SiO₂. The observed zoning can neither be explained by gravitational settling nor by a thermal gradient alone. Most likely the fluid was separated from the solids by surface forces and thereby established the chemical gradient by preferentially dissolving MgO. If strong chemical zoning is taken into account, the occurrence of more phases than allowed by the phase rule can be explained by separating the bulk into several domains of different bulk compositions. Results indicate that small amounts of F increase the stability field of clinohumite, Mg₉Si₄O₁₆(OH,F)₂, compared to OH-clinohumite in pure MSH previously reported. Clinohumite coexists with enstatite up to 975 °C at 5 GPa, and up to 1,100 °C at 12 GPa. At 14 GPa (close to the !/#-Mg₂SiO₄ transition) phase E becomes the most important water carrier. The new results indicate that clinohumite could be an important mantle mineral for transporting water into the Earth's transition zone due to its high thermal stability compared to other important water carriers such as serpentine and phase A.