Basic model of water- and gas-flow through smectite clay buffers

Canister embedment of highly compacted Na bentonite forms a low-permeable medium of significant homogeneity both macro- and microscopically. However, despite the fact that a large part of the porewater is in interlamellar positions and not mobile by ordinary hydraulic gradients, there are still a number of pore passages that let water and gas through even at very high bulk densities. A preliminary model for flow and diffusion has been outlined on the basis of generalized, quantitative microstructural data and basic physical relationships. It accounts for actually recorded hydraulic and gas conductivities as well as for commonly measured swelling pressures. Qualitatively, it is in agreement also with published ion diffusion data.     

Age and evolution of scheelite-hosting rocks in the Felbertal deposit (Eastern Alps): U-Pb geochronology of zircon and titanite

U-Pb isotope analyses of zircon and titanite extracted from different rocks of the Felbertal scheelite deposit yield the following information: (1) An age of 593±22 Ma (2) is obtained for zircon crystallization in the scheelite-bearing matrix of an eruption breccia in the western ore field. (2) Discordant zircons from an elongated, up to 8 m thick scheelite-rich quartzite body in the eastern ore field give an upper intercept age of 544±5 Ma. This quartzite contains a laminated, fine-grained scheelite mineralization. (3) Zircons from a small granitoid intrusion of the western ore field reveal an age of 336±16 Ma, and concordant titanites document an age of 282±2 Ma for Variscan amphibolite facies metamorphism. Both events, granitoid intrusion and later metamorphism caused ore re-mobilization, including the formation of yellowish fluorescent (molybdo-) scheelite porphyroblasts. (4) For a narrow lamprop-1hyric dike in the western ore field, a concordant titanite age of 283±7 Ma is obtained. This age is identical with the titanites from the amphibolite facies metamorphic intrusion. Tiny scheelite grains were tapped by the dike from pre-existing scheelite mineralizations in the truncated host rocks. (5) Alpine metamorphism at 31±4 Ma did not exceed lowermost amphibolite facies conditions, and it caused scheelite re-mobilization on a minor scale only, producing bluish fluorescent porphyroblasts in quartz veinlets and veins, as well as bluish fluorescent scheelite rims around older scheelite grains. Moreover, crosscutting Alpine fissure fillings show bluish fluorescent, inclusion-free scheelite. (6) The preservation of Variscan titanites, the absence of Alpine titanite growth, and the large degree of Variscan scheelite re-mobilization demonstrate that amphibolite facies metamorphism in the Felbertal area has a Variscan age. This result clearly documents Variscan tectono-metamorphism to be the dominant event, instead of the hitherto surmised Alpine metamorphism. This multi-stage evolution of the Felbertal ore bodies corroborates the view that tungsten deposits are conditioned by several succeeding thermal events, leading to a series of stages that ultimately produce high-grade scheelite concentrations. These high-grade ores predominately occur along shear zones of different age, accompanied by the formation of large volumes of low-grade scheelite mineralizations along host rock foliations and quartz veinlets and veins.     

Quantifying how climatic factors affect variation in plant disease severity: A general method using a new way to analyze meteorological data

A general method is presented for analyzing how climatic conditions affect plant disease severity. An example of its application is given for the analysis of stripe rust (caused by Puccinia striiformis) data on winter wheat cultivar Gaines and climatic data collected at Pullman, WA. for 1968–1986. A computer program WINDOW was written to identify the climatic factors most highly correlated with disease. This program is designed to utilize meteorological data for an entire growing season of a crop as well as to include climatic conditions preceding planting. This program uses an iterative process to examine variable-length segments of meteorological data in a more exhaustive analysis than previously possible. Climatic factors considered include: mean maximum, minimum, and average temperature; total and frequency of precipitation; consecutive days with and without precipitation; accumulation of negative and positive degree days; and number of days with extreme temperature events. Variables that were highly correlated with disease were the basis for regression models that were developed to predict disease severity index for each of the three cultivars. Two- and three-variable models explained, respectively, 75 and 76% of the variation in disease from year to year. Predictions (which could be made early enough in the growing season to allow application of chemical control) were evaluated on the basis of whether years with severe disease were accurately predicted. Models were validated using Allen's PRESS statistic and by application to new data. The method is potentially applicable to studies of how climatic conditions affect the populations or productivity of other types of organisms.This research was supported by a National Science Foundation Grant (ATM 85-03115), Climate Dynamics Program, Division of Atmospheric Sciences.     

A methodology to calibrate and to validate effective solid potentials of heterogeneous porous media from computed tomography scans and laboratory-measured nanoindentation data

Built on the framework of effective interaction potentials using lattice element method, a methodology to calibrate and to validate the elasticity of solid constituents in heterogeneous porous media from experimentally measured nanoindentation moduli and imported scans from advanced imaging techniques is presented. Applied to computed tomography (CT) scans of two organic-rich shales, spatial variations of effective interaction potentials prove instrumental in capturing the effective elastic behavior of highly heterogeneous materials via the first two cumulants of experimentally measured distributions of nanoindentation moduli. After calibration and validation steps while implicitly accounting for mesoscale texture effects via CT scans, Biot poroelastic coefficients are simulated. Analysis of stress percolation suggests contrasting pathways for load transmission, a reflection of microtextural differences in the studied cases. This methodology to calibrate elastic energy content of real materials from advanced imaging techniques and experimental measurements paves the way to study other phenomena such as wave propagation and fracture while providing a platform to fine-tune effective behavior of materials given advancements in additive manufacturing and machine learning algorithms.     

An expanded weighted-averaging model for inferring past total phosphorus concentrations from diatom assemblages in eutrophic British Columbia (Canada) lakes

Eighteen lakes were added to a published training set of 46 British Columbia (BC) lakes in order to expand the original range of total phosphorus (TP) concentrations. Canonical correspondence analysis (CCA) was used to analyze the relationship between diatom assemblages and environmental variables. Specific conductivity and [TP] each explained significant (P0.05) directions of variance in the distribution of the diatoms. The relationship between diatom assemblages and [TP] was sufficiently strong to warrant the development of a weighted-averaging (WA) regression and calibration model that can be used to infer past trophic status from fossil diatom assemblages.The relationship between observed and inferred [TP] was not improved by the addition of more eutrophic lakes, however the [TP] range and the number of taxa used in the transfer function are now superior to the original model. Diatom species assemblages changed very little in lakes with TP concentrations greater than 85 µg 1^–1, so we document the development of a model containing lakes with TP85 µg 1^–1. The updated model uses 59 training lakes and covers a range of species optima from 6 to 41.9 µg 1^–1 TP, and a total of 150 diatom taxa.The updated inference model provided a more realistic reconstruction of the anthropogenic history of a highly eutrophic BC lake. The model can now be used to infer past nutrient conditions in other BC lakes in order to assess changes in trophic status.     

Stellar kinematics and populations of early-type galaxies with the SAURON and OASIS integral-field spectrographs

We summarise the results and achievements of integral-field spectroscopy of early-type galaxies, observed as part of a survey using both the SAURON and OASIS spectrographs. From the perspective of integral-field spectroscopy, these otherwise smooth and featureless objects show a wealth of structure, both in their stellar kinematics and populations. We focus on the stellar content, and examine properties on both kiloparsec scales with SAURON, and scales of 100’s of parsecs with OASIS. These complementary studies reveal two types of kinematically distinct components (KDCs), differing primarily in their intrinsic sizes. In previous studies, KDCs and their host galaxies have generally been found to be unremarkable in other aspects. We show that large KDCs, typical of the well-studied cases, indeed show little or no age differences with their host galaxy. The KDCs detected with the higher spatial-resolution of OASIS are intrinsically smaller and include, in contrast, a significant fraction of young stars. We speculate on the relationship between KDCs and their host galaxies, and the implications for young populations in early-type galaxies.     

Historical and paleolimnological evidence for expansion of Lake Athabasca (Canada) during the Little Ice Age

A multi-proxy paleolimnological record obtained from a small, lowland closed-drainage basin located in the Peace-Athabasca Delta (Alberta, Canada), 10 km northwest of the present-day shore of Lake Athabasca, captures evidence of pronounced hydroecological changes over the past ~400 years. Consistent with historical maps produced by early European explorers of western Canada, paleolimnological data support the existence of a Lake Athabasca highstand during the Little Ice Age (LIA), c. 1600–1900 Common Era (CE). This contrasts with interpretations from previous analyses on sediment cores from an upland closed-drainage basin located centrally within the Peace sector of the delta that indicate low water levels during this interval. The different paleohydrological records at these two basins reflect the relative influence of different controls on the lake water balances. During the LIA, the lowland site was influenced by high levels in Lake Athabasca, whereas the elevated basin was outside the range of water-level rise in the lake and its distributaries, and was instead controlled by dry atmospheric conditions that led to evaporative drawdown. Integration of paleolimnological records and historical sources demonstrates that the ecosystem has undergone marked climate-driven hydroecological change over the past century, which is important information for effective management.