Effects of Recharge Wells and Flow Barriers on Seawater Intrusion

The installation of recharge wells and subsurface flow barriers are among several strategies proposed to control seawater intrusion on coastal groundwater systems. In this study, we performed laboratory‐scale experiments and numerical simulations to determine the effects of the location and application of recharge wells, and of the location and penetration depth of flow barriers, on controlling seawater intrusion in unconfined coastal aquifers. We also compared the experimental results with existing analytical solutions. Our results showed that more effective saltwater repulsion is achieved when the recharge water is injected at the toe of the saltwater wedge. Point injection yields about the same repulsion compared with line injection from a screened well for the same recharge rate. Results for flow barriers showed that more effective saltwater repulsion is achieved with deeper barrier penetration and with barriers located closer to the coast. When the flow barrier is installed inland from the original toe position however, saltwater intrusion increases with deeper barrier penetration. Saltwater repulsion due to flow barrier installation was found to be linearly related to horizontal barrier location and a polynomial function of the barrier penetration depth.     

Highly evolved hypabyssal kimberlite sills from Wemindji,Quebec, Canada: insights into the process of flow differentiation in kimberlite magmas

Kimberlite sills emplaced in granite located near the town of Wemindji (Quebec, Canada) range from 2 cm to 1.2 m in thickness. The sills exhibit a wide variation in macroscopic appearance from fine-grained aphanitic dolomitic hypabyssal kimberlite to ilmenite/garnet macrocrystal hypabyssal kimberlite. Diatreme or crater facies rocks are not present. Multiple intrusions are present within the sills, and graded bedding and erosional features such as cross-bedding are common. The sills exhibit a wide range in their modal mineralogy with respect to the abundances of spinel, apatite, phlogopite and dolomite. Olivine is the dominant macrocryst, with an average composition of Fo₉₀. Garnet macrocrysts are low chrome (2–3 wt. %) pyrope (G1/G9 garnet). Ilmenite occurs as rounded macrocrysts (7–13 wt. % MgO). Phlogopite microphenocrysts are Ti-poor and represent a solid solution between phlogopite and kinoshitalite end members. Spinel compositions mainly represent the Cr-poor members of the qandilite–ulvöspinel–magnetite series. The principle carbonate comprising the groundmass is dolomite, with lesser later-forming calcite. Accessory minerals include apatite, Sr-rich calcite, Nb-rich rutile, baddeleyite, monazite-(Ce) and barite. While some of these accessory minerals are atypical of kimberlites in general, it is expected that differentiation products of an evolved carbonate-rich kimberlite magma will crystallize these phases. The Wemindji kimberlites offer insight into the process of crystal fractionation and differentiation in evolved kimberlite magmas. The macroscopic textural features observed in the Wemindji sills are interpreted to represent flow differentiation of a mantle-derived, very fluid, low viscosity carbonate-rich kimberlite. The diverse modes and textural features result entirely from flow differentiation and multiple intrusions of different batches of genetically related kimberlite magma. The mineralogy of the Wemindji kimberlites has some similarities to that of the Wesselton and Benfontein calcite kimberlite sills but differs in detail with respect to dominant carbonate (i.e. dolomite versus calcite), and the character of the rare earth-bearing accessory minerals (i.e. monazite-(Ce) versus rare earth fluorocarbonates).     

In situ U–Pb,Sr and Nd isotopic analysis of loparite by LA-(MC)-ICP-MS

This work describes the in situ analysis of loparite [(Na,REE)Ti₂O₆], a perovskite group mineral with extremely low Rb/Sr ratios and high rare earth contents, by LA-(MC)-ICP-MS for the determination of U–Pb ages together with Sr and Nd isotopic composition. The reliability of these data were validated by analysis of a loparite standard by TIMS solution methods. Data are given for loparite from the Lovozero and Khibiny peralkaline complexes of the Kola Alkaline Province (Russia). For Lovozero loparite the Tera–Wasserburg intercept age for 15 loparites analysed is 373 ± 11 Ma, and the weighted ²⁰⁷Pb corrected ²⁰⁶Pb/²³⁸U age is 373 ± 2 Ma. For Khibiny loparite, the intercept age for 5 loparites analysed is 375 ± 10 Ma, and the weighted ²⁰⁷Pb corrected ²⁰⁶Pb/²³⁸U age is 374 ± 3 Ma. The common Pb compositions for Lovozero and Khibiny loparites are identical i.e. ²⁰⁷Pb/²⁰⁶Pb = 0.898 ± 0.009 and 0.898 ± 0.007, respectively. The ⁸⁷Sr/⁸⁶Sr initial ratios of Lovozero loparite range from 0.703552 to 0.703682 (av. 0.703611), and εNd (t₃₇₀) from + 3.8 to + 4.4 (av. + 4.0). The ⁸⁷Sr/⁸⁶Sr initial ratios of Khibiny loparite range from 0.703560 to 0.703871, and εNd (t₇₃₀) from + 4.0 to + 4.8. Our data indicate that in situ LA-(MC)-ICP-MS analysis of loparite provides accurate and precise estimates of the intrusion ages and isotopic composition of peralkaline rocks.     

Relation between the deposition and petrology of Shanxi coals and the composition of their extracts

The soluble organic material present in a set of 12 coal samples representing three major episodes of coal deposition in Shanxi Province, North China, has been examined. Shanxi coals, like those from Gondwanaland, contain little liptinite and accordingly the material extracted by pyridine yields only small quantities of n-hexane soluble n-alkanes, steranes and hopanes identifiable by gas-chromatography/mass spectrometry. The distribution of the n-alkanes is characteristic of the environment from which each of the Shanxi coals was formed but the distribution of the branched alkanes is generally determined by the dia- and catagenesis each coal experienced. Aromatic compounds identified in the extracts typify the small molecules present within the vitrinite lattice. Technologically significant benzene-methanol extracts deriving from vitrinite-inertinite have been characterised by proton NMR spectroscopy and partially separated by HPLC.     

Seafloor mapping for geohazard assessment: state of the art

During the last two decades, increasing use of full-coverage sonic mapping of the seafloor has made us more aware of the large and different number of seafloor processes and events bearing significant geohazard potential. This awareness combines with the increasing use of the seafloor for infrastructure and with the high density of population and settlement on the coast. Seafloor mapping is the first step in making a census of the geohazard-bearing features present in a given offshore area. It often provides the only tool for a comprehensive, although non-specific, seafloor geohazard assessment over large areas that are scarcely groundtruthed by acoustic prospection and seafloor sampling. However, the characterization of geohazard features on a morphological basis alone is limited, and more detailed investigations are needed to define the character and state of activity of potentially hazardous features. Such investigations include the use of deep-tow or autonomous platforms designed to acquire high-resolution data at depth as well as in situ measurements, both being very expensive activities not applicable over large areas. Thus seafloor mapping is often not only the first and the main but also the only tool for a comprehensive seafloor geohazard assessment. This special issue represents an example of the diversity of approaches to seafloor geohazard assessment and summarizes the present state of this discipline. Both the diverse technologies applied and the specific aims of offshore geohazard assessment brought different communities to deal with the study of seafloor processes and events from remarkably distinct viewpoints. We identified three end members in offshore geohazard assessment: (1) geohazard assessment ??sensu stricto??, (2) ??engineering?? geohazard assessment, (3) ??non-specific?? geohazard assessment. These are being conducted by industry, academia and public agencies in charge of civil protection and land-use planning and management. Understanding the needs and geohazard perception of the different groups is a necessary step for a profitable collaboration in such an interesting and rapidly developing field of marine geology.     

Dissipation of Titan's north polar cloud at northern spring equinox

Saturn's Moon Titan has a thick atmosphere with a meteorological cycle. We report on the evolution of the giant cloud system covering its north pole using observations acquired by the Visual and Infrared Mapping Spectrometer onboard the Cassini spacecraft. A radiative transfer model in spherical geometry shows that the clouds are found at an altitude between 30 and 65 km. We also show that the polar cloud system vanished progressively as Titan approached equinox in August 2009, revealing at optical wavelengths the underlying sea known as Kraken Mare. This decrease of activity suggests that the north-polar downwelling has begun to shut off. Such a scenario is compared with the Titan global circulation model of Rannou et al. (2006), which predicts a decrease of cloud coverage in northern latitudes at the same period of time.     

The zoned Bruinbun granitoid pluton and its aureole

The Bruinbun pluton is a small, massive, I‐type granitoid intruded into the meta‐sedimentary Hill End Trough, in eastern N.S.W. It is a multiple pluton representing two discrete magma pulses, the granodiorite core intruding the adamellite margin. A weak alignment of orthoclase megacrysts in the granitoids is best developed adjacent to both the internal and external intrusive contacts, and is considered by the writer to be a product of magmatic flow. Part of the northern contact and the southern and western contacts dip inward at moderate angles, whereas the eastern contact is vertical to outward‐dipping. The pluton is inferred to be mushroom‐shaped, and slightly tilted.

The intensity of aureole deformation is low. The aureole has been flexed into concordancy with the pluton roof, and a rudimentary rim fold‐zone is present around lower levels of the pluton. Intrusion of the granitoid is inferred to be primarily by uplift of its roof and depression of its floor.

The highest‐grade contact metamorphic parageneses developed are: cordierite‐K feldspar‐biotite‐quartzite ± andesine ± epidote in metapelites, and ferrohornblende‐biotite‐muscovite‐andesine‐epidote‐quartz in metavolcarenites. No intrusion‐related foliation or lineation was formed.     

Aspects of Mechanical Behavior and Modeling of a Tropical Unsaturated Soil

The research studies the applicability of two elastoplastic models for the collapse prediction of the lateritic soil profile from Southeastern Brazil. These tropical soils have peculiar geotechnical behavior, due to their mineralogical composition and porous structure coming from intense process of formation. Two elastoplastic models were analyzed: the Barcelona Basic Model (BBM) and another one based on BBM, however developed for tropical soils. Oedometric tests with suction control were performed at three distinct depths of the soil profile. The BBM was not suitable for the upper layer of the soil profile, because BBM considers the compressible behavior of the soil in function of the reduction of the elastoplastic compressibility index with the increase of the matric suction. The model developed for tropical soils showed better suited to the compressible behavior of the soil profile, resulting in good prediction of the collapse potential, mainly by accepting increasing values of the elastoplastic compressibility index of the soil profile with the matric suction rise.