HCN fluorescence on Titan

The HCN emission features near 3 μm recently detected by Geballe et al. (2003, Astrophys. J. 583, L39) are analyzed with a model for fluorescence of sunlight in the ν₃ band of HCN. The emission spectrum is consistent with current knowledge of the atmospheric temperature profile and the HCN distribution inferred from millimeter-wave observations. The spectrum is insensitive to the abundance of HCN in the thermosphere and the thousand-fold enhancement relative to photochemical models suggested by Geballe et al. (2003, Astrophys. J. 583, L39) is not required to explain the observations. We find that the spectrum can be matched with temperatures from 130 to 200 K, with slightly better fits at high temperature, contrary to the temperature determination of 130±10 K of Geballe et al. (2003, Astrophys. J. 583, L39). The HCN emission spectrum is sensitive to the collisional de-excitation probability, P₁₀, for the ν₃ state and we determine a value of 10⁻⁵ with an accuracy of about a factor of two. Analysis of absorption lines in the C₂H₂ν₃ band near 3 μm, detected in the same spectrum, indicate a C₂H₂ mole fraction near 0.01 μbar of 10⁻⁵ for P₁₀=10⁻⁴. The derived mole fraction, however, is dependent upon the value adopted for P₁₀ and lower values are required if P₁₀ at Titan temperatures is less than its room temperature value.     

Instrumental temperature records at two sites in Central Canada: 1768 to 1910

As a result of affiliation between the Hudson's Bay Company and the Royal Society a relatively large number of instrumental temperature records are available from York Factory and Churchill Factory on the southwest of Hudson Bay beginning in 1768. The nature of these records, details of the instruments and information about the observers are presented. The major difficulty with the records is that the number of observations and the time of observation varied considerably. Adjustment factors were calculated for all of the combinations using a modern record maintained at the Churchill airport. By combining the Hudson's Bay Company record with data recorded by members of the Royal Canadian Mounted Police after 1852, and up to 1910, a long and relatively continuous record of daily and monthly average temperatures has been created for Central Canada.     

The Upper Oligocene of Antigua: the volcanic to limestone transition in a limestone Caribbee

Antigua is a small island at the northern end of the Lesser Antilles chain. Its geology is largely limited to the Upper Oligocene and it records with unusual fidelity the transition from island arc volcanism to quiescence and limestone deposition. Despite the apparent limitation of a rock record confined to a short stratigraphical interval, Antigua has a geodiversity that ranges from thick andesites through silicified logs and freshwater snails in cherts to limestones that include both shallow and deeper water facies, and fine karstic features.     

Preparing a seismic hazard model for Switzerland: the view from PEGASOS Expert Group 3 (EG1c)

The seismic hazard model used in the PEGASOS project for assessing earth-quake hazard at four NPP sites was a composite of four sub-models, each produced by a team of three experts. In this paper, one of these models is described in detail by the authors. A criticism sometimes levelled at probabilistic seismic hazard studies is that the process by which seismic source zones are arrived at is obscure, subjective and inconsistent. Here, we attempt to recount the stages by which the model evolved, and the decisions made along the way. In particular, a macro-to-micro approach was used, in which three main stages can be described. The first was the characterisation of the overall kinematic model, the “big picture” of regional seismogenesis. Secondly, this was refined to a more detailed seismotectonic model. Lastly, this was used as the basis of individual sources, for which parameters can be assessed. Some basic questions had also to be answered about aspects of the approach to modelling to be used: for instance, is spatial smoothing an appropriate tool to apply? Should individual fault sources be modelled in an intraplate environment? Also, the extent to which alternative modelling decisions should be expressed in a logic tree structure has to be considered.     

A paleolimnological constraint to the extent of the Last Glaciation on northern Devon Island, Canadian High Arctic

Pre-Holocenelacustrine sediments from a small coastal lake on the TrueloveLowland, northeastern Devon Island,Nunavut Territory, Canada, indicatethat a viable terrestrial ecosystem existed prior to postglacialmarine inundation and subsequent isostatic emergence of thebasin. An AMS ¹⁴C age of 38 kaBP on the basal lacustrine unit provides a preliminarygeochronological framework. This find has directimplications for regional glacial history, becauseit argues against both the Late Wisconsinan glaciation ofcertain coastal lowlands on northern Devon Island,as well as the occupation of Jones Sound by an outlet of theInnuitian Ice Sheet between Devon and Ellesmere islands.     

Modeling the Effects of Oyster Reefs and Breakwaters on Seagrass Growth

Seagrass beds have declined in Chesapeake Bay, USA as well as worldwide over the past century. Increased seston concentrations, which decrease light penetration, are likely one of the main causes of the decline in Chesapeake Bay. It has been hypothesized that dense populations of suspension-feeding bivalves, such as eastern oysters (Crassostrea virginica), may filter sufficient seston from the water to reduce light attenuation and enhance seagrass growth. Furthermore, eastern oyster populations can form large three-dimensional reef-like structures that may act like breakwaters by attenuating waves, thus decreasing sediment resuspension. We developed a quasi-three-dimensional Seagrass-Waves-Oysters-Light-Seston (SWOLS) model to investigate whether oyster reefs and breakwaters could improve seagrass growth by reducing seston concentrations. Seagrass growth potential (SGP), a parameter controlled by resuspension-induced turbidity, was calculated in simulations in which wave height, oyster abundance, and reef/breakwater configuration were varied. Wave height was the dominant factor influencing SGP, with higher waves increasing sediment resuspension and decreasing SGP. Submerged breakwaters parallel with the shoreline improved SGP in the presence of 0.2 and 0.4 m waves when sediment resuspension was dominated by wave action, while submerged groins perpendicular to the shoreline improved SGP under lower wave heights (0.05 and 0.1 m) when resuspension was dominated by along-shore tidal currents. Oyster-feeding activity did not affect SGP, due to the oysters’ distance from the seagrass bed and reduced oyster filtration rates under either low or high sediment concentrations. Although the current implementation of the SWOLS model has simplified geometry, the model does demonstrate that the interaction between oyster filtration and along-shore circulation, and between man-made structures and wave heights, should be considered when managing seagrass habitats, planning seagrass restoration projects, and choosing the most suitable methods to protect shorelines from erosion.     

Submicron-sized fluid inclusions and distribution of hydrous components in jadeite,quartz and symplectite-forming minerals from UHP jadeite–quartzite in the Dabie Mountains,China: TEM and FTIR investigation

Fluid inclusions and clusters of water molecules at nanometer-to submicron-scale in size have been investigated using transmission electron microscopy (TEM) and Fourier transform infrared spectroscopy (FTIR) in jadeite, quartz and symplectite aegirine–augite, albite, taramite and magnetite corona minerals from ultrahigh-pressure (UHP) jadeite–quartzite at Shuanghe, the Dabie Mountains, China. Fluid inclusions from 0.003 μm to 0.78 μm in size occur in jadeite and quartz crystals, and a small number of fluid inclusions from 0.001 μm to 0.25 μm have also been detected in symplectite-forming minerals. Most of the fluid inclusions have round or negative crystal morphology and contain aqueous fluids, but some contain CO₂-rich fluids. They are usually connected to dislocations undetectable at an optical scale. The dislocations represent favorable paths for fluid leakage, accounting for non-decrepitation of most fluid inclusions when external pressure decreased at later stages, although there was partial decrepitation of some fluid inclusions unconnected to defect microstructures resulting from internal overpressure. Non-decrepitation and partial decrepitation of fluid inclusions resulted in changes of original composition and/or density. It is clear that identification of hidden re-equilibration features has significant implications for the petrological interpretation of post-peak metamorphic processes. Micro-FTIR results show that all jadeite and quartz samples contain structural water occurring as hydroxyl ions (OH⁻) and free water (H₂O) in the form of clusters of water molecules. The H₂O transformed from OH⁻ during exhumation and could have triggered and enhanced early retrograde metamorphism of the host rocks and facilitated plastic deformation of jadeite and quartz grains by dislocation movement, and thus the H₂O released during decompression might represent early-stage retrograde metamorphic fluid. The nominally anhydrous mineral (NAM) jadeite is able to transport aqueous fluids in concentrations of at least several hundred ppm water along a subduction zone to mantle depths in the form of clusters of water molecules and hydroxyl ions within crystals.     

The use of infauna by juvenile Penaeus aztecus Ives and Penaeus setiferus (Linnaeus)

Penaeus aztecus Ives, the brown shrimp, and Penaeus setiferus (Linnaeus), the white shrimp, co-occur in Texas salt marshes as juveniles. Although their life cycles are similar, evidence indicates that the species utilize different resources for the primary faunal element of their diets. Prey selection and growth studies have shown that brown shrimp successfully remove infauna from natural sediment. Further, a diet of polychaetes, whether alone or in combination with algae, produced growth in the species. Brown shrimp appear to be trophically linked to infaunal populations, thus the structure and dynamics of the benthic community may directly affect local brown shrimp productivity. Areas dominated by surface-dwelling polychaetes as opposed to deep burrowers may provide more accessible foraging opportunities for juvenile brown shrimp. By contrast, white shrimp neither removed infauna nor grew to a significant degree when provided polychaetes or amphipods as food. White shrimp are omnivorous but do not rely on infaunal material to the same extent as brown shrimp. The primary faunal element in the diet of white shrimp has not yet been identified. The dietary differences between the two species may play a role in determining which species dominates in regions with varying marsh accessibility. Although not the only factors influencing penaeid survival and growth, prey choice and availability may greatly affect production and local success of penaeid populations. *** DIRECT SUPPORT *** A01BY081 00013     

Activity–composition relations for phases in petrological calculations: an asymmetric multicomponent formulation

For petrological calculations, including geothermobarometry and the calculation of phase diagrams (for example, P–T petrogenetic grids and pseudosections), it is necessary to be able to express the activity–composition (a–x) relations of minerals, melt and fluid in multicomponent systems. Although the symmetric formalism—a macroscopic regular model approach to a–x relations—is an easy-to-formulate, general way of doing this, the energetic relationships are a symmetric function of composition. We allow asymmetric energetics to be accommodated via a simple extension to the symmetric formalism which turns it into a macroscopic van Laar formulation. We term this the asymmetric formalism (ASF). In the symmetric formalism, the a–x relations are specified by an interaction energy for each of the constituent binaries amongst the independent set of end members used to represent the phase. In the asymmetric formalism, there is additionally a "size parameter" for each of the end members in the independent set, with size parameter differences between end members accounting for asymmetry. In the case of fluid mixtures, for example, H₂O–CO₂, the volumes of the end members as a function of pressure and temperature serve as the size parameters, providing an excellent fit to the a–x relations. In the case of minerals and silicate liquid, the size parameters are empirical parameters to be determined along with the interaction energies as part of the calibration of the a–x relations. In this way, we determine the a–x relations for feldspars in the systems KAlSi₃O₈–NaAlSi₃O₈ and KAlSi₃O₈–NaAlSi₃O₈–CaAl₂Si₂O₈, for carbonates in the system CaCO₃–MgCO₃, for melt in the melting relationships involving forsterite, protoenstatite and cristobalite in the system Mg₂SiO₄–SiO₂, as well as for fluids in the system H₂O–CO₂. In each case the a–x relations allow the corresponding, experimentally determined phase diagrams to be reproduced faithfully. The asymmetric formalism provides a powerful and flexible way of handling a–x relations of complex phases in multicomponent systems for petrological calculations.