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121.
Nathan D. Sheldon Ramananda Chakrabarti Gregory J. Retallack Roger M. H. Smith 《Sedimentology》2014,61(6):1812-1829
The end of the Palaeozoic is marked by two mass‐extinction events during the Middle Permian (Capitanian) and the Late Permian (Changhsingian). Given similarities between the two events in geochemical signatures, such as large magnitude negative δ13C anomalies, sedimentological signatures such as claystone breccias, and the approximate contemporaneous emplacement of large igneous provinces, many authors have sought a common causal mechanism. Here, a new high‐resolution continental record of the Capitanian event from Portal Mountain, Antarctica, is compared with previously published Changhsingian records of geochemical signatures of weathering intensity and palaeoclimatic change. Geochemical means of discriminating sedimentary provenance (Ti/Al, U/Th and La/Ce ratios) all indicate a common provenance for the Portal Mountain sediments and associated palaeosols, so changes spanning the Capitanian extinction represent changes in weathering intensity rather than sediment source. Proxies for weathering intensity chemical index of alteration, ?W and rare earth element accumulation all decline across the Capitanian extinction event at Portal Mountain, which is in contrast to the increased weathering recorded globally at the Late Permian extinction. Furthermore, palaeoclimatic proxies are consistent with unchanging or cooler climatic conditions throughout the Capitanian event, which contrasts with Changhsingian records that all indicate a significant syn‐extinction and post‐extinction series of greenhouse warming events. Although both the Capitanian and Changhsingian event records indicate significant redox shifts, palaeosol geochemistry of the Changhsingian event indicates more reducing conditions, whereas the new Capitanian record of reduced trace metal abundances (Cr, Cu, Ni and Ce) indicates more oxidizing conditions. Taken together, the differences in weathering intensity, redox and the lack of evidence for significant climatic change in the new record suggest that the Capitanian mass extinction was not triggered by dyke injection of coal‐beds, as in the Changhsingian extinction, and may instead have been triggered directly by the Emeishan large igneous province or by the interaction of Emeishan basalts with platform carbonates. 相似文献
122.
Roger H. Mitchell Peter C. Burns Kevin S. Knight Christopher J. Howard Anton R. Chakhmouradian 《Physics and Chemistry of Minerals》2014,41(6):393-401
Laboratory powder XRD patterns of the perovskite-group mineral lueshite from the type locality (Lueshe, Kivu, DRC) and pure NaNbO3 demonstrate that lueshite does not adopt the same space group (Pbma; #57) as the synthetic compound. The crystal structures of lueshite (2 samples) from Lueshe, Mont Saint-Hilaire (Quebec, Canada) and Sallanlatvi (Kola, Russia) have been determined by single-crystal CCD X-ray diffraction. These room temperature X-ray data for all single-crystal samples can be satisfactorily refined in the orthorhombic space group Pbnm (#62). Cell dimensions, atomic coordinates of the atoms, bond lengths and octahedron tilt angles are given for four crystals. Conventional neutron diffraction patterns for Lueshe lueshite recorded over the temperature range 11–1,000 K confirm that lueshite does not adopt space group Pbma within these temperatures. Neutron diffraction indicates no phase changes on cooling from room temperature to 11 K. None of these neutron diffraction data give satisfactorily refinements but suggest that this is the space group Pbnm. Time-of-flight neutron diffraction patterns for Lueshe lueshite recorded from room temperature to 700 °C demonstrate phase transitions above 550 °C from Cmcm through P4/mbm to \(Pm\overline{3} m\) above 650 °C. Cell dimensions and atomic coordinates of the atoms are given for the three high-temperature phases. The room temperature to 400 °C structures cannot be satisfactorily resolved, and it is suggested that the lueshite at room temperature consists of domains of pinned metastable phases with orthorhombic and/or monoclinic structures. However, the sequence of high-temperature phase transitions observed is similar to those determined for synthetic NaTaO3, suggesting that the equilibrated room temperature structure of lueshite is orthorhombic Pbnm. 相似文献
123.
This paper presents the results of a case study analysis from the knowledge domains of vulnerability and resilience. We analyzed 20 scientific assessments to provide empirical evidence for successes and failures in collaborative knowledge production, i.e., the joint creation of assessments reports by researchers and decision makers in policy and practice. It became clear that the latter typically use insufficiently the research-based knowledge available and researchers typically produce insufficiently knowledge that is directly usable. We found a number of functional, structural, and social factors inhibiting a joint problem identification and framing of knowledge producers and potential users: divergent objectives, needs, scope, and priorities; different institutional settings and standards, as well as differing cultural values, understanding, and mistrust. Combining understanding from multiple sources and providing mechanisms for linking solutions proposed by research with articulated needs and problems of practitioners would reduce the discrepancies in activities of different actors and result in more timely and context-appropriate solutions. In the concluding section we argue for a more locally embedded and socially contingent production of actionable knowledge and make suggestions about ways to enhance effectiveness of research-based knowledge. 相似文献
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Abstract In the construction of global primitive equation models, based on the spherical harmonic method, two forms of truncation are in general use. Theoretical considerations suggest the triangular truncation method is superior, but the easily coded rhomboidal truncation is more commonly used. A verification experiment employing the Canadian Operational Spectral Model has been performed to determine if the theoretical superiority of the triangular truncation can be realized in practice. It was found that at least in the restricted case of extra‐tropical forecasts of less than 48 h, that the two truncation methods produced forecasts of equivalent accuracy. 相似文献
126.
Roger K. Ulrich Larry Webster John E. Boyden Nick Magnone Richard S. Bogart 《Solar physics》1991,135(2):211-241
We describe enhancements to the hardware and software for the 150-foot tower system on Mt. Wilson which make possible the acquisition of high precision line profile measurements. This system utilizes the 75-foot pit spectrograph with a photomultiplier detector system to scan line profiles repeatedly in order to study variations induced by the passage of waves vertically through the solar atmosphere. Oscillations of line profile parameters with an amplitude as low as 1.7 m s–1 have been detected with this system using integrated sunlight. Phase relations between oscillations of different parts of the line profile are appropriate to upward energy transport. Consistent with the previous conclusion by Mein and Schmieder (1981), we find that the magnitude of the energy transport is compatible with the 5-min oscillations making an important contribution to the heating of the low chromosphere.The Mount Wilson Observatory is operated by the Mount Wilson Institute under agreement with the Carnegie Institution of Washington. 相似文献
127.
Soil surface crusts are widely reported to favour Hortonian runoff, but are not explicitly represented in most rainfall‐runoff models. The aim of this paper is to assess the impact of soil surface crusts on infiltration and runoff modelling at two spatial scales, i.e. the local scale and the plot scale. At the local scale, two separate single ring infiltration experiments are undertaken. The first is performed on the undisturbed soil, whereas the second is done after removal of the soil surface crust. The HYDRUS 2D two‐dimensional vertical infiltration model is then used in an inverse modelling approach, first to estimate the soil hydraulic properties of the crust and the subsoil, and then the effective hydraulic properties of the soil represented as a single uniform layer. The results show that the crust hydraulic conductivity is 10 times lower than that of the subsoil, thus illustrating the limiting role the crust has on infiltration. Moving up to the plot scale, a rainfall‐runoff model coupling the Richards equation to a transfer function is used to simulate Hortonian overland flow hydrographs. The previously calculated hydraulic properties are used, and a comparison is undertaken between a single‐layer and a double‐layer representation of the crusted soil. The results of the rainfall‐runoff model show that the soil hydraulic properties calculated at the local scale give acceptable results when used to model runoff at the plot scale directly, without any numerical calibration. Also, at the plot scale, no clear improvement of the results can be seen when using a double‐layer representation of the soil in comparison with a single homogeneous layer. This is due to the hydrological characteristics of Hortonian runoff, which is triggered by a rainfall intensity exceeding the saturated hydraulic conductivity of the soil surface. Consequently, the rainfall‐runoff model is more sensitive to rainfall than to the subsoil's hydrodynamic properties. Therefore, the use of a double‐layer soil model to represent runoff on a crusted soil does not seem necessary, as the increase of precision in the soil discretization is not justified by a better performance of the model. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
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