Earth''s earliest continental lithosphere, hydrothermal flux and crustal recycling

The Kaapvaal craton in southern Africa and the Pilbara craton of northwestern Australia are the largest regions on Earth to have retained relatively pristine mid-Archaean rocks (3.0–4.0 Ga).The Kaapvaal craton covers about 1.2×10⁶ km², and varies in lithospheric thickness between 170 and 350 km. At surface, the craton can be subdivided into a number of Archaean sub-domains; some of the subdomains are also well defined at depth, and local variations in tomography of the lithosphere correspond closely with subdomain boundaries at surface.The Archaean history of the Kaapvaal craton spans about 1 Gyr and can be conveniently subdivided into two periods, each of about the same length as the Phanerozoic. The first period, from circa 3.7-3.1 Ga, records the initial separation of the cratonic lithosphere from the asthenosphere, terminating with a major pulse of accretion tectonics between 3.2 and 3.1 Ga, which includes the formation of “paired metamorphic belts”. This period of continental growth can be compared to plate tectonic processes occurring in modern-day oceanic basins. However, the difference is that in the mid-Archaean, these oceanic processes appear to have occurred in shallower water depths than the modern ocean basins. The second period, from circa 3.1-2.6 Ga, records intra-continental and continental-edge processes: continental growth during this period occurred predominantly through a combination of tectonic accretion of crustal fragments and subduction-related igneous processes, in much the same way as has been documented along the margins of the Pacific and Tethys oceans since the Mesozoic.The intra-oceanic processes resulted in small, but deep-rooted continental nucleii; the first separation of this early continental lithosphere could only have occurred when the mean elevation of mid-oceanicridges sank below sea-level. Substantial recycling of continental lithosphere into the mantle must have occurred during this period of Earth history. During the second period, at least two large continental nucleii amalgamated during collisional processes which, together with internal chemical differentiation processes, created the first stable continental landmass. This landmass, which is known to have been substantially bigger than its present outline, may have been part of the Earth's first supercontinent.The oldest known subdomains of the craton include the oceanic-like rocks of the Barberton greenstone belt. The comagmatic mafic-ultramafic rocks (3.48–3.49 Ga) of this belt represent a remnant of very early oceanic-like lithosphere (known as the Jamestown Ophiolite Complex), which was obducted, approximately 45 Ma after its formation, onto a volcanic arc-like terrain by processes similar to those which have emplaced modern ophiolites at convergent margins of Phanerozoic continents. The early metamorphic history, metamorphic mineralogy, oxygen isotope profiles and degree of hydration of the 3.49 Ga Jamestown Ophiolite Complex are similar to present day subseafloor hydrothermal systems. The ratio of ΔMg to ΔSi for hydrothermally altered igneous rocks, both present day and Archaean, are remarkably uniform at −5(±0.9) and the same as that of hydrothermal fluids venting on the present-day East Pacific Rise. This observation suggests that the process of Mg exchange for Si in hydrothermal systems was commonplace throughout Earth's history.The chemistry of vent fluids and hydrothermally altered igneous rocks was combined with an inventory of ³He in the mantle to model Earth's total hydrothermal flux. An Archaean flux (at 3.5 Ga) of about 10 times present day was accompanied by a correspondingly greater abundance of Mg(OH), SiO₂, carbonate and Fe---Mn metasomatic rock types as well as massive sulphides. Assuming a constant column of seawater since the Archaean, the average residence time of seawater in the oceanic crust was 1.65−8.90×10⁵ years in the Archaean. Assuming that ³He and heat are transported from the mantle in silicate melts in uniform proportions, the model stipulates that accretion of oceanic crust decreased from about 3.43−6.5×10¹⁷ g/yr to a present-day rate of 0.52−0.8×10¹⁷ g/yr, with a drop in heat flow from 1.4−2.6×10²⁰ cal/yr to 2.1−3.2×10¹⁹ cal/year.The total amounts of SiO₂ and Fe mobilised in marine hydrothermal systems since 3.5 Ga is less than their masses in the present exosphere reservoirs (crust, hydrosphere, atmosphere). The total amounts of Mg, K, CO₂, Ca and Mn are greater than their respective masses in exosphere reservoirs; therefore, they must have been recycled into mantle. The total mass of recycled hydrothermal components is small compared to the mass of the mantle. The flux of volatiles in hydrothermal systems is large compared to their volume in the atmosphere suggesting that the CO₂ and O₂ budgets of the atmosphere have been influenced by hydrothermal processes, especially in the Archaean.     

Diagenetic evolution of Aptian evaporites in the Namibe Basin (south‐west Angola)

The widespread and dissected nature of the Angolan gypsiferous salt residuals offers a uniquely detailed view of the lateral and vertical relations inherent to secondary evaporite textures, which typify exhumed salt masses worldwide. Such secondary textures are sometimes misinterpreted as primary evaporite textures. Thin, metre‐scale and patchy, dome‐like gypsum accumulations are well‐exposed within strongly incised present‐day river valleys along the eastern margin of the Namibe and Benguela basins (south‐west Angola). These sections are time equivalent to the main basinward subsurface evaporites (Aptian Loeme Formation) which mostly consist of halite. The gypsum (here called the Bambata Formation) is interpreted to represent the final residual product of fractional dissolution and recrystallization of the halite mass that occurred during Late Cretaceous margin uplift and continues today. This halite underwent multiple episodes of diagenetic alteration between its deposition and its final exhumation, leading to the formation of various secondary gypsum fabrics and solution‐related karst and breccia textures that typify the current evaporite outcrop. Four different diagenetic gypsum fabrics are defined: thinly bedded alabastrine, nodular alabastrine, displacive selenite rosettes and fibrous satin‐spar gypsum. Current arid conditions are responsible for a thin weathered crust developed at the top of the outcropping gypsum, but the fabrics in the main core of the current at‐surface evaporite unit mostly formed during the telogenetic stage of uplift prior to complete subaerial exposure. Alteration occurred as various dissolving and rehydrating saline minerals encountered shallow aquifers in the active phreatic and vadose zones. Geomorphological and petrographic analyses, mostly based on the cross‐cutting relations and crystallographic patterns in the outcrop, are used to propose a sequence of formation of these different fabrics.     

Predisposition and cause of the catastrophic landslides of August 2005 in Brienz (Switzerland)

Very intensive rainfall in August 2005 (>300 mm/3 days) triggered moderately deep (2–10 m) landslides of about 50'000 m³ volume each in two mountain torrent catchments above the village of Brienz (Berner Oberland, Switzerland). These landslides – originating in Trachtbach and Glyssibach catchments – transformed into extremely rapid (>5 m/s) debris flows, which caused significant damage in inhabited areas; two persons lost their lives and about twenty-five families became homeless. The Brienz case was the most damaging one among many landslide disasters occurring during those rainy days in the Swiss Alps. In this paper we study in detail the predisposition and causes of the 2005 landslides in the Brienz area, based on field mapping, analysis of high resolution images and digital terrain models, derived from LIDAR and infrared measurements taken before and after the event. The features of these landslides are compared with past and dormant landslides in the mid-slope portion of the mountain chain north of Brienz, which has been the source of many catastrophic mass wasting events during the last centuries. Detailed field mapping shows that highly weathered series of strongly overconsolidated Mesozoic marls (Diphyoides Limestone & Vitznau Marls of Valanginian age) and their residual soils form the primary source for the sliding materials. The rupture surfaces of the moderately deep landslides often run at the transition from saprolite to weathered bedrock, with a dip angle of about 40o in the landslide depletion area. These landslides transform into debris flows, where debris slides into strongly convergent hillslopes or directly into headwater channels.     

Identification of Uranyl Minerals Using Oxygen K‐Edge X‐Ray Absorption Spectroscopy

Although most of the world's uranium exists as pitchblende or uraninite, this mineral can be weathered to a great variety of secondary uranium minerals, most containing the uranyl cation. Anthropogenic uranium compounds can also react in the environment, leading to spatial–chemical alterations that could be useful for nuclear forensics analyses. Soft X‐ray absorption spectroscopy (XAS) has the advantages of being non‐destructive, element‐specific and sensitive to electronic and physical structure. The soft X‐ray probe can also be focused to a spot size on the order of tens of nanometres, providing chemical information with high spatial resolution. However, before XAS can be applied at high spatial resolution, it is necessary to find spectroscopic signatures for a variety of uranium compounds in the soft X‐ray spectral region. To that end, we collected the near edge X‐ray absorption fine structure (NEXAFS) spectra of a variety of common uranyl‐bearing minerals, including uranyl carbonates, oxyhydroxides, phosphates and silicates. We find that uranyl compounds can be distinguished by class (carbonate, oxyhydroxide, phosphate or silicate) based on their oxygen K‐edge absorption spectra. This work establishes a database of reference spectra for future spatially resolved analyses. We proceed to show scanning X‐ray transmission microscopy (STXM) data from a schoepite particle in the presence of an unknown contaminant.     

Gold in Madagascar

Gold is commonly found throughout the Precambrian basement exposed in the eastern two-thirds of Madagascar, composed of Archean and Proterozoic greenstone belts and metasediment belts. Gold occurs in four main kinds of deposits:- as a diffuse component of the crystalline basement rocks, - in concordant quartz veins within the metamorphic rocks of the Precambrian basement, - in recent discordant veins, - and in recent and ancient alluvial deposits.The initial gold mineralisation is probably in relation with the greenstone belt formation, and many have been formed and/or reworked during different metamorphic and magmatic events. It is therefore difficult to obtain an accurate age of the different kinds of deposits.     

The geoarchaeology of Iron Age “moated” sites of the Upper Mae Nam Mun Valley,N.E. Thailand. I: Palaeodrainage,site–landscape relationships and the origins of the “moats”

The study focuses on the “moated” Iron Age sites of N.E. Thailand, first identified as significant prehistoric settlement sites in the 1940s from aerial photography. Two more recent photograph sets are used to map the surficial geology and prehistoric site distribution for a study area west of Phimai, N.E. Thailand, with a focus on site–landscape relationships and, in particular, relationships between site location and form and patterns of palaeodrainage. The derived record of the surficial geology reflects several phases of palaeodrainage, characterized by differing locations and types of former river channels. Of note is the differentiation between a recent period in which river channels, including those presently active, are single-string meandering channels, and an older period of broad belts of meandering multistring channels. The prehistoric site distribution correlates closely with the older drainage, and for many, the encircling channels (the “moats”) are closely associated with former river channels. These relationships provide a critical and novel model for site distribution; several implications arise, supported by emerging field evidence, and introducing issues for archaeological debate: (i) there is no need, as has been done in the past, to invoke prehistoric artificial forms of drainage associated with the sites; (ii) the definition of the encircling channels as “moats” is seriously called into question; and (iii) the inferred geomorphological evolution of the floodplain implies past changes in environmental parameters such as run-off, climate or biophysical environments. Since the sites are all located in or beside ancient meander belts, these parameters should now be introduced into archaeological discussions regarding the establishment, history, evolution, and abandonment of the Iron Age sites. Methodologically, this article illustrates the need to be aware of the complexity of aerial photograph interpretation in archaeological survey, showing that careful analysis of aerial photograph information may have a significant impact upon the modeling of prehistoric interpretations. Further stratigraphical studies will be reported subsequently, and will refine the models presented here. © 1999 John Wiley & Sons, Inc.     

Gas hydrate systems at Hydrate Ridge offshore Oregon inferred from molecular and isotopic properties of hydrate-bound and void gases

We report and discuss molecular and isotopic properties of hydrate-bound gases from 55 samples and void gases from 494 samples collected during Ocean Drilling Program (ODP) Leg 204 at Hydrate Ridge offshore Oregon. Gas hydrates appear to crystallize in sediments from two end-member gas sources (deep allochthonous and in situ) as mixtures of different proportions. In an area of high gas flux at the Southern Summit of the ridge (Sites 1248-1250), shallow (0-40 m below the seafloor [mbsf]) gas hydrates are composed of mainly allochthonous mixed microbial and thermogenic methane and a small portion of thermogenic C₂₊ gases, which migrated vertically and laterally from as deep as 2- to 2.5-km depths. In contrast, deep (50-105 mbsf) gas hydrates at the Southern Summit (Sites 1248 and 1250) and on the flanks of the ridge (Sites 1244-1247) crystallize mainly from microbial methane and ethane generated dominantly in situ. A small contribution of allochthonous gas may also be present at sites where geologic and tectonic settings favor focused vertical gas migration from greater depth (e.g., Sites 1244 and 1245). Non-hydrocarbon gases such as CO₂ and H₂S are not abundant in sampled hydrates. The new gas geochemical data are inconsistent with earlier models suggesting that seafloor gas hydrates at Hydrate Ridge formed from gas derived from decomposition of deeper and older gas hydrates. Gas hydrate formation at the Southern Summit is explained by a model in which gas migrated from deep sediments, and perhaps was trapped by a gas hydrate seal at the base of the gas hydrate stability zone (GHSZ). Free gas migrated into the GHSZ when the overpressure in gas column exceeded sealing capacity of overlaying sediments, and precipitated as gas hydrate mainly within shallow sediments. The mushroom-like 3D shape of gas hydrate accumulation at the summit is possibly defined by the gas diffusion aureole surrounding the main migration conduit, the decrease of gas solubility in shallow sediment, and refocusing of gas by carbonate and gas hydrate seals near the seafloor to the crest of the local anticline structure.     

The climatic impacts of land surface change and carbon management, and the implications for climate-change mitigation policy

Strategies to mitigate anthropogenic climate change recognize that carbon sequestration in the terrestrial biosphere can reduce the build-up of carbon dioxide in the Earth’s atmosphere. However, climate mitigation policies do not generally incorporate the effects of these changes in the land surface on the surface albedo, the fluxes of sensible and latent heat to the atmosphere, and the distribution of energy within the climate system. Changes in these components of the surface energy budget can affect the local, regional, and global climate. Given the goal of mitigating climate change, it is important to consider all of the effects of changes in terrestrial vegetation and to work toward a better understanding of the full climate system. Acknowledging the importance of land surface change as a component of climate change makes it more challenging to create a system of credits and debits wherein emission or sequestration of carbon in the biosphere is equated with emission of carbon from fossil fuels. Recognition of the complexity of human-caused changes in climate does not, however, weaken the importance of actions that would seek to minimize our disturbance of the Earth’s environmental system and that would reduce societal and ecological vulnerability to environmental change and variability.     

Probabilistic reasoning about measurements of equilibrium climate sensitivity: combining disparate lines of evidence

Where policy and science intersect, there are always issues of ambiguous and conflicting lines of evidence. Combining disparate information sources is mathematically complex; common heuristics based on simple statistical models easily lead us astray. Here, we use Bayesian Nets (BNs) to illustrate the complexity in reasoning under uncertainty. Data from joint research at Resources for the Future and NASA Langley are used to populate a BN for predicting equilibrium climate sensitivity (ECS). The information sources consist of measuring the rate of decadal temperature rise (DTR) and measuring the rate of percentage change in cloud radiative forcing (CRF), with both the existing configuration of satellites and with a proposed enhanced measuring system. The goal of all measurements is to reduce uncertainty in equilibrium climate sensitivity. Subtle aspects of probabilistic reasoning with concordant and discordant measurements are illustrated. Relative to the current prior distribution on ECS, we show that after 30 years of observing with the current systems, the 2σ uncertainty band for ECS would be shrunk on average to 73% of its current value. With the enhanced systems over the same time, it would be shrunk to 32% of its current value. The actual shrinkage depends on the values actually observed. These results are based on models recommended by the Social Cost of Carbon methodology and assume a Business as Usual emissions path.