Comparison of Two Sample Preparation Methods for X‐Ray Fluorescence Spectrometry in the Determination of Ni and Cr

Pressed powder pellets and fused beads or glass disks are routinely used in X‐ray fluorescence spectrometry for the determination of major and trace elements, respectively, in geological materials. In order to evaluate the performance of these two sample preparation methods, we determined Ni and Cr concentrations of fourteen RMs from Japan, France and South Africa, and eighty‐five igneous and three sedimentary rock samples from Mexico in both powder pellets and glass beads. We also computed new values of statistical parameters for RMs from an outlier‐based multiple‐test method and compared them with the literature mean and confidence limit values. The results showed that the multiple‐test method provided more reliable central tendency and dispersion parameters for RMs than those obtained previously from the two or three standard deviation method, or from robust methods. The powder pellet and fused bead sample preparation methods provided consistent results for Ni and Cr at concentration levels > 50 μg g^?1 in this application; for lower concentration levels, however, these methods showed somewhat greater differences. For quantitative comparisons, both ordinary and weighted least‐squares linear regression models were used to show that the two sample preparation methods provided generally unbiased results.     

Late Pleistocene flank collapse of Zempoala volcano (Central Mexico) and the role of fault reactivation

Zempoala is an extinct Pleistocene (∼ 0.7–0.8 Ma) stratovolcano that together with La Corona volcano (∼ 0.9 Ma) forms the southern end of the Sierra de las Cruces volcanic range, Central Mexico. The volcano consists of andesitic and dacitic lava flows and domes, as well as pyroclastic and epiclastic sequences, and has had a complex history with several flank collapses. One of these collapses occurred during the late Pleistocene on the S–SE flank of the volcano and produced the Zempoala debris avalanche deposit. This collapse could have been triggered by the reactivation of two normal fault systems (E–W and NE–SW), although magmatic activity cannot be absolutely excluded. The debris avalanche traveled 60 km to the south, covers an area of 600 km² and has a total volume of 6 km³, with a calculated Heim coefficient (H/L) of 0.03. Based on the textural characteristics of the deposit we recognized three zones: proximal, axial, and lateral distal zone. The proximal zone consists of debris avalanche blocks that develop a hummocky topography; the axial zone corresponds with the main debris avalanche deposit made of large clasts set in a sandy matrix, which transformed to a debris flow in the lateral distal portion. The deposit is heterolithologic in composition, with dacitic and andesitic fragments from the old edifice that decrease in volume as bulking of exotic clasts from the substratum increase. Several cities (Cuernavaca, Jojutla de Juárez, Alpuyeca) with associated industrial, agricultural, and tourism activities have been built on the deposit, which pose in evidence the possible impact in case of a new event with such characteristics, since the area is still tectonically active.     

Seismotectonic Reactions to the Arc-continent Convergence in Central Philippines

Abstract. High seismic activity in the Philippines originates from tectonic convergence related to surface and subsurface seismotectonic features. Based on earthquake data, the archipelago can be divided into the seismically-active Philippine Mobile Belt and the aseismic North Palawan Block. The latter represents a rifted continental fragment of the Eurasian margin that juxtaposed with the rest of island arc units in central Philippines. Earthquake hypocenter plots on planar and in vertical profiles show that the seismic events are associated with known seismotectonic features. In addition, data suggest that the collision zone between the North Palawan Block and the Philippine Mobile Belt is characterized by a decreased amount of hypocenters at > 100 km depths. Although field evidence favors the presence of a subducted slab or slabs beneath western central Philippines, these are difficult to image using the present seismicity distribution dataset.     

Atmospheric models of He-peculiar stars: synthetic He I line profiles and absolute visual magnitudes

We analyze the influence of magnetic pressure effects on the atmospheric structure of B peculiar type stars, as well as, on the emergent He?I line profiles and absolute visual magnitudes. We consider a photosphere in local thermodynamic and hydrostatic equilibrium. The hydrostatic equilibrium equation is modified to include the Lorentz force. Atomic occupational numbers are computed in LTE considering non-ideal effects in the gas equation of state. We depict the influence of a magnetic field on local He?I line profiles and discuss the effects of the helium abundance in magnetic B-type stars. The Lorentz force might explain local variations up to 7 % in the equivalent width of helium lines, while local enhancements of He chemical abundances would produce larger changes. To analyze the line variations in real stars we computed the net contribution of a bipolar magnetic field over the stellar disk. The resulting disk-averaged magnetic field predicts variations with the rotation phase up to 2–3 % in the line EWs for a dipolar magnetic field of 1000 G.     

Automatic inspection and analysis of digital waveform images by means of convolutional neural networks

Journal of Seismology - Analyzing seismic data to get information about earthquakes has always been a major task for seismologists and, more in general, for geophysicists. Recently, thanks to the...     

The structural evolution of the southern Apuan Alps: new constraints on the tectonic evolution of the Northern Apennines (Italy)Évolution structurale des Apuanes méridionales : nouvelles contraintes sur l'évolution tectonique des Apennins septentrionaux (Italie)

Structural analysis performed in the southern sector of the Apuan Alps Metamorphic Complex (AAMC) and on the overlaying Tuscan Nappe (TN) pointed out a structural evolution much more complex than that outlined till now. The comparison between the structural evolutions of the two tectonic units could provide new important constraints on the tectonic evolution of the whole belt. The two tectonic units recorded different tectonic evolution during the first stages of compression, while they shared the same deformation history later after the Tuscan Nappe overlapped the AAMC. The coupled tectonic units have been then deformed by two systems of folds, in a compressive tectonic regime. Extensional tectonics affected the units later, at upper crustal levels. To cite this article: R. Carosi et al., C. R. Geoscience 334 (2002) 339–346.     

Modelling the influence of environmental and weather factors on the density of the invasive polychaete Boccardia proboscidea

The inter‐tidal zone around sewage discharges in a Southwest Atlantic shore (Mar del Plata, Argentina) is currently colonized by extensive inter‐tidal reefs of the invasive spionid Boccardia proboscidea. Understanding the links between both human and natural disturbances and the massive development of non‐indigenous species will help prevent marine bioinvasions, which are already favoured by global oceanic trade. We present herein predictive models for variations in the density of B. proboscidea around sewage discharges of Mar del Plata, using environmental (pH, turbidity, temperature, salinity and total organic matter content), weather (wind direction and storm records), spatial (sites) and temporal (season and year) variables. Density variations were modelled by generalized linear models, and model averaging (multimodel inference) was used to obtain predicted values. The highest predicted values of B. proboscidea density occurred at sites to the south of the sewage effluent in spring. These sites are more affected by urban effluent discharges and they showed increased B. proboscidea density when the north wind was predominant. In addition, B. proboscidea density values were higher in sites with 20–22 °C (seawater temperature), high total organic matter content in sediments and low salinity. The averaged model was only a good ‘predictive model’ for sites to the north of the outfall, but was useful as an ‘explanatory model’ in all sites. Such predictions may help to back up conservation and management policies and decisions.     

Spatial and long-term analyses of reference and sewage-impacted sites in the SW Atlantic (38°S, 57°W) for the assessment of sensitive and tolerant polychaetes

Discharges of effluent in urbanized littoral areas produce nonlinear changes in benthic organisms. Data on the composition of the benthic community are often used to obtain environmental quality classifications that serve to indicate the health of the environment. This study conducted a comparative analysis of the polychaetes associated with mussel beds and related these results to the values of environmental variables at both reference and sewage-impacted sites over a 10 year period in a rocky intertidal habitat on the coast of the SW Atlantic. The results of the study showed spatial and temporal differences in the abundance and dominance of the polychaetes. The study also furnished evidence of a decrease in the environmental quality of the area. This study allowed the classification of the polychaetes into ecological groups, facilitating the calculation of environmental quality indexes.     

Analysis of spatial variability of SPT penetration resistance in collapsible soils considering water table depth

Geostatistical kriging approach was used for mapping of water table depth and for checking its influence on penetration resistance observed in standard penetration test (SPT). Geostatistical mapping was based on a compartmentalisation of 204 SPT records in two main groups using monthly and yearly rainfall marks as a segregation criterion. Six maps produced at 1:10,000 scale were achieved as follows: water table depth variation and penetration resistance variation at the depths of 1.5, 6.0, 8.5, 11.0, 13.5 m. Greater variations of the penetration resistance, in terms of increase and reduction of resistance, were observed at the depths of 6.0 and 8.5 m.