Potassium loss during metasomatic alteration of mica pyroxenite from Oldoinyo Lengai,northern Tanzania: contrasts with fenitization

Mica pyroxenite xenoliths, occurring as the cores of nephelinite and ijolite bombs in the pyroclastic deposits of the active volcano Oldoinyo Lengai, have undergone metasomatism in which K was lost and Fe²⁺ and Ti gained. This is unlike the alkali and ferric iron addition that typifies most examples of metastomatism adjacent to peralkaline igneous rocks in carbonatite complexes.     

Eucolite from oldoinyo Lengai,Tanzania

Eucolite occurs in ejected blocks of agpaitic wollastonite-bearing nepheline syenite in the pyroclastics of the active carbonatite volcano Oldoinyo Lengai, northern Tanzania. An analysis of the syenite is given, and chemical, optical and X-ray data for the eucolite are presented. The agpaitic paragenesis at Oldoinyo Lengais is one of the few recorded instances of agpaitic rocks in carbonatite environment.     

PCBs in the firth of clyde

Attention to detail is essential for the reduction of pollution. By detective work, a river purification board has been able to track down an important single source of PCB contamination of its sewage sludge and institute remedial action.     

Martian craters from earth

Martian craters were evidently observed and described by E. E. Barnard in 1892–1893 and by John E. Mellish in 1915.     

The monosaccharide spectra of natural waters

Monosaccharides were determined in waters and sediment pore waters from a wide variety of environments and locations. Desalting was performed by electrodialysis and concentrated extracts were analyzed by two forms of liquid chromatography. At least 12 sugars were identified. Glucose and fructose were the dominant monosaccharides in nearly all samples examined. Analyses of over 150 seawater and sediment pore water samples showed that fructose is highly significantly correlated (>0.99) with glucose concentrations. Laboratory kinetic experiments on the epimerization reaction, glucose ? fructose, in sterilized natural seawater in the dark, yielded a forward rate constant, k₁, of 1.2 × 10^?5 h^?1 at 25°C and 1.6 × 10^?7 h^?1 at 2°C. The approximate time required to attain equilibrium at 25°C was 1.1 y and at 2°C, 15.4 y; the measured equilibrium constant was in the range 0.3–0.4. The actual ratio of fructose to glucose in natural water samples was usually in the range 1.0–1.4/l, independent of the total monosaccharide concentrations, which varied in the samples by a factor of ～100. Several possible explanations for the apparent discrepancy in the determined and found ratios are discussed: the presence of universal, as yet, undiscovered major biological sources for fructose in marine environments; preferential utilization of glucose; preferential incorporation of fructose into or onto inorganic colloids; and preferential formation of fructose-transition metal ion associations.     

Modelling phosphorus transport in a surface irrigation drain

Understanding phosphorus (P) transport from agricultural land is essential to the development of effective management strategies that reduce the impact of agriculture on inland water quality. This paper describes the development and application of a process based model describing P transfer down a farm scale irrigation drain.     

Tsunami deposits in the geological record

A review is presented here of tsunami deposits in the geological record. It begins with a discussion of the relationships between the processes of tsunami generation and propagation and the sedimentary responses. This is followed by a consideration of the sedimentary processes associated with the passage of tsunami waves across coastlines. Attention is also given to the sedimentary processes associated with tsunami-triggered gravity backwash flows and comparisons are made with turbidity current action. We observe that despite sedimentary evidence for recent tsunamiites, geological research on ancient tsunamis has not identified stratigraphic units associated with onshore tsunami sedimentation. Equally, it is noted that nearly all published studies of sedimentary processes associated with modern tsunamis have not considered patterns of sediment transport and deposition in the offshore zone.     

Employment in retailing: A case study of employment in suburban shopping centres

There have been many studies of the retail industry in recent years, and of the impact that retailing has had on the spatial arrangement of urban areas and on consumer behaviour. Little attention has been paid, however, to employment in retailing, which is disturbing in view of its growing importance and its rapidly changing nature and composition. This paper examines the nature of the broad structural changes within the industry, and investigates their spatial consequences through a case study of employment generation within a system of suburban retail centres in Canberra, Australia. It is shown that the evolution of suburban centres, particularly those of a regional variety, has had an important and enriching impact on the suburban labour market. The regional centres are also seen to be the focus of the major structural employment changes currently affecting the retail industry. This has some important implications for urban planning.     

Fertile and barren AlCr-spinel harzburgites from the upper mantle: Ion and electron probe analyses of trace elements in olivine and orthopyroxene: Relation to lherzolites

Ion and electron microprobe analyses of twenty-one CrAl-spinel harzburgite xenoliths from southern African kimberlites show two chemical groups. Orthopyroxenes from “fertile” harzburgites have higher CaO (mean of 11, 0.95 wt.%), Al₂O₃ (3.05 wt.%), Cr₂O₃ (0.85 wt.%) and Li (0.8 ppmw) than those from “barren” harzburgites (mean of 10, CaO 0.24 wt.%, Al₂O₃ 1.10 wt.%, Cr₂O₃ 0.35 wt.%, Li 0.3 ppmw). Olivines from all harzburgites have similar chemistry except that mean values of Li and Na are higher for barren than fertile harzburgites (Li 0.9 vs. 0.4 ppmw; Na₂O 16 vs. 7 ppmw). Orthopyroxenes from fertile harzburgites are chemically distinct from those in garne lherzolites from southern Africa and spinel lherzolites from southwest U.S.A., but orthopyroxenes from barren harzburgites are indistinguishable from those in many coarse garnet lherzolites.Chromium, Ca, Ni, Na and Li in coexisting olivines and orthopyroxenes from the above rock types show complex patterns, which for Ca, Cr and Ni can be related to pressure and temperature. Temperatures from an empirically calibrated thermometer based on Ni-Mg exchange between olivine and orthopyroxene, measured modes of harzburgites (fertile, mean of 10: ol 68, opx 31, spinel-silicate intergrowth <0.5; barren, mean of 8: ol 76, opx 23, spinel and spinel-silicate intergrowth 1), and high-pressure experimental studies suggest (a) that harzburgites are residues of partial melting, (b) that barren harzburgites were melted to a greater extent at a higher temperature (though probably at a similar depth) than fertile harzburgites, and (c) that incomplete reequilibration during retrograde metamorphism has led to development of complex inter- and intragranular textures, probably in the range ～700–900°C.     

Chemistry of micas from kimberlites and xenoliths—II. Primary- and secondary-textured micas from peridotite xenoliths

Micas from coarse granular Iherzolites in S. African kimberlites may be separated into two groups; those showing primary textural relationships with coexisting silicates and those with secondary, alteration relationships with other silicates. Primary-textured micas form a tight cluster with a mean composition from 10 coarse garnet lherzolites of: SiO₂ 41.0, TiO₂ 0.18, Al₂O₃ 13.5, Cr₂O₃ 0.82, total Fe as FeO 2.60, MnO 0.02, MgO 26.0, NiO 0.22, CaO 0.01, BaO 0.29, Na₂O 0.31, K₂O 10.0, Rb₂O 0.028, Cl 0.08, F 0.43 wt%. Primary-textured micas in aggregates with clinopyroxene have higher TiO₂ and four specimens which look similar to the primary group but have textural ambiguities have still higher TiO₂Micas with secondary textures have wide ranges of composition which may be correlated with details of the textural parageneses. Micas from kelyphitic rims around garnets tend to be Cr-rich while those from veinlets are Cr-poor. Both groups tend to have higher FeO and TiO₂ than the primary group. Micas produced by alteration of, or filling veinlets through, orthopyroxene have a wide compositional range which overlaps that of the primary-textured micas, especially for harzburgite specimens.The primary-textured micas show a positive correlation with coexisting pyroxenes for MgO/(MgO + FeO) and TiO₂, but not for Cr₂O₃. Secondary-textured micas do not show correlations with coexisting pyroxenes for any elements.The ‘primary-metasomatic’ micas described by Harte and Gurney (1975) and metasomatic and other micas described by Boettcher et al. (1979) and Boettcher and O'neil (1979) are richer in FeO and TiO₂ than the present primary-textured micas, and are attributed to crystallization from fractionated fluids.