Occurrence of noble metals in aluminum- and chromium- rich objects in ordinary chondrites and of baddeleyite (ZrO2) in a chromite inclusion

Abstract— Platinum group elements (PGE) enrichments are found in Fe-Ni blebs (<1 μm) in Al- and Cr-rich objects in the ordinary chondrites Ste. Marguerite, Forest Vale, Montferré. In Ste. Marguerite, high ZrO₂ concentrations (baddeleyite) are also present in a chromite inclusion. Iridium enrichment in this material compared to its metal content is confirmed by INAA. The widespread occurrence of PGE in Al- and Cr-rich objects, mostly present in H-group chondrites of nearly equilibrated types, must be taken into account to understand their conditions of formation.     

Production of a molybdophore during metal-targeted dissolution of silicates by soil bacteria

Although many bioessential metals are scarce in natural water and rock systems, microbial secretion of high-affinity ligands for metal extraction from solid phases has only been documented for Fe. However, we have discovered that Mo is extracted from a silicate by a high-affinity ligand (a possible “molybdophore”) secreted by an N₂-fixing soil bacterium. The putative molybdophore, aminochelin, is secreted as a siderophore under Fe-depleted conditions, but is also secreted under Fe-sufficient, Mo-depleted conditions. Presumably, molybdophore production facilitates uptake of Mo for use in Mo enzymes. In contrast, an Fe-requiring soil bacterium without a special Mo requirement only enhances the release of Fe from the silicate. Fractionation of Mo stable isotopes during uptake to cells may provide a “fingerprint” for the importance of chelating ligands in such systems. Many such metal-specific ligands secreted by prokaryotes for extraction of bioessential metals, their effects on Earth materials, and their possible utility in the recovery of economic metals remain to be discovered.     

Origin of a partially differentiated Titan

Accretional temperature profiles for Saturn’s large moon Titan are used to determine the conditions needed for accretion to avoid global melting as a function of the timing, duration, and nebular conditions of Titan’s accretion. We find that Titan can accrete undifferentiated in a “gas-starved” disk even with modest quantities of ammonia mixed in with its ices. Simulations of impact-induced core formation are used to show that Titan can remain only partially differentiated after an outer Solar System late heavy bombardment capable of melting its outer layers, permitting some of its rock to consolidate into a core.     

Institutional Adaptation of Water Resource Infrastructures to Climate Change in Eastern Ontario

Institutional barriers and bridges to local climate change impacts adaptation affecting small rural municipalities and Conservation Authorities (CAs are watershed agencies) in Eastern Ontario (Canada) are examined, and elements of a community-based adaptation strategy related to water infrastructures are proposed as a case-study in community adaptation to climate change. No general water scarcity is expected for the region even under unusually dry weather scenarios. Localized quantity and quality problems are likely to occur especially in groundwater recharge areas. Some existing institutions can be relied on by municipalities to build an effective adaptation strategy based on a watershed/region perspective, on their credibility, and on their expertise. Windows of opportunity or framing issues are offered at the provincial level, the most relevant one in a federal state, by municipal emergency plan requirements and pending watershed source water protection legislation. Voluntary and soon to be mandated climate change mitigation programs at the federal level are other ones.     

City renaming as brand promotion: exploring neoliberal projects and community resistance in New Zealand

ABSTRACT

Proposals to change the names of entire urban centres are rare. We examine the case of Blenheim, New Zealand, where in 2016, representatives of local businesses campaigned for its renaming as Marlborough City, in recognition of the region’s wine industry. Although defeated the proposal threatened to over-write established settlement history. It presumed to rename Blenheim under the aegis of New Zealand Inc., a shorthand for the pervasive yet nebulous economic nationalism that seeks to yoke all local and national identity to enhancing export growth. Drawing on media reports, we interpret this example of toponymic commodification as a neoliberalized project of place-making. Ironically, Blenheim and Marlborough are colonial names that displaced a long-established Māori name. The proposal highlights both the perversities and the deeply contested claims-making that often underlie and animate toponymic politics. Ultimately, it illustrates some of the limits of rights claimed under neoliberalism.     

Sediment transport on the Freiston Shore managed realignment site: An investigation using environmental magnetism

This paper presents the first attempt to use environmental magnetism to quantify sediment provenance on a managed realignment (MR) site. MR is one technique for creating/restoring intertidal habitats and improving the standard of coastal flood protection. Monitoring of MR sites is essential for determining how successful they are at achieving these aims, and normally includes measurement of sedimentation rates through the use of accretion plates and sediment erosion tables (SETs). One limitation of this technique is that the provenance of sediment accreting on realigned surfaces cannot readily be quantified. Our results demonstrate that magnetics-based fingerprinting can successfully apportion sediment source contributions to created/restored coastal saltmarshes with an efficiency similar to that of existing un-mixing models applied to other habitats (82.87%). Analysis of mineral magnetic properties (χ_FD, IRM_soft and SIRM) demonstrated that the majority of sediment accreting on the Freiston Shore MR Site (Lincolnshire, UK) is derived from established saltmarshes seaward of the breached embankment. This indicates that the MR site may be growing at the expense of neighbouring saltmarshes—thereby undermining the habitat-creation objectives used to justify MR. It is recommended that future MR monitoring programmes consider the provenance of post-breach deposits to help identify any adverse impacts that wetland creation/restoration may have on existing habitats. Further testing of environmental magnetism in coastal saltmarshes and MR sites is necessary to validate wider use of the technique.