Upper Palaeozoic subduction/accretion processes in the closure of Palaeotethys: Evidence from the Chios Melange (E Greece), the Karaburun Melange (W Turkey) and the Teke Dere Unit (SW Turkey)

During Late Palaeozoic time a wide ocean, known as Palaeotethys, separated the future Eurasian and African continents. This ocean closed in Europe in the west during the Variscan orogeny, whereas in Asia further east it remained open and evolved into the Mesozoic Tethys, only finally closing during Late Cretaceous–Early Cenozoic.Three Upper Palaeozoic lithological assemblages, the Chios Melange (on the Aegean Greek island), the Karaburun Melange (westernmost Aegean Turkey) and the Teke Dere Unit (Lycian Nappes, SW Turkey) provide critical information concerning sedimentary and tectonic processes during closure of Palaeotethys. The Chios and Karaburun melanges in the west are mainly terrigenous turbidites with blocks and dismembered sheets of Silurian–Upper Carboniferous platform carbonate rocks (shallow-water and slope facies) and poorly dated volcanic rocks. The Teke Dere Unit to the southeast begins with alkaline, within-plate-type volcanics, depositionally overlain by Upper Carboniferous shallow-water carbonates. This intact succession is overlain by a tectonic slice complex comprising sandstone turbidites that are intersliced with shallow-water, slope and deep-sea sediments (locally dated as Early Carboniferous). Sandstone petrography and published detrital mineral dating imply derivation from units affected by the Panafrican (Cadomian) and Variscan orogenies.All three units are interpreted as parts of subduction complexes in which pervasive shear zones separate component parts. Silurian–Lower Carboniferous black cherts (lydites) and slope carbonates accreted in a subduction trench where sandstone turbidites accumulated. Some blocks retain primary depositional contacts, showing that gravitational processes contributed to formation of the melange. Detached blocks of Upper Palaeozoic shallow-water carbonates (e.g. Chios) are commonly mantled by conglomerates, which include water-worn clasts of black chert. The carbonate blocks are restored as one, or several, carbonate platforms that collided with an active margin, fragmenting into elongate blocks that slid into a subduction trench. This material was tectonically accreted at shallow levels within a subduction complex, resulting in layer-parallel extension, shearing and slicing. The accretion mainly took place during Late Carboniferous time.Alternative sedimentary-tectonic models are considered in which the timing and extent of closure of Palaeotethys differ, and in which subduction was either northwards towards Eurasia, or southwards towards Gondwana (or both). Terrane displacement is also an option. A similar (but metamorphosed) accretionary unit, the Konya Complex, occurs hundreds of kilometres further east. All of these units appear to have been assembled along the northern margin of Gondwana by Permian time, followed by deposition of overlying Tauride-type carbonate platforms. Northward subduction of Palaeotethys beneath Eurasia is commonly proposed. However, the accretionary units studied here are more easily explained by southward subduction towards Gondwana. Palaeotethys was possibly consumed by long-lived (Late Palaeozoic) northward subduction beneath Eurasia, coupled with more short-lived (Late Carboniferous) southward subduction near Gondwana, during or soon after closure of Palaeotethys in the Balkan region to the west.     

Towards a geocomputational landscape epidemiology: surveillance,modelling, and interventions

The ability to explicitly represent infectious disease distributions and their risk factors over massive geographical and temporal scales has transformed how we investigate how environment impacts health. While landscape epidemiology studies have shed light on many aspects of disease distribution and risk differentials across geographies, new computational methods combined with new data sources such as citizen sensors, global spatial datasets, sensor networks, and growing availability and variety of satellite imagery offer opportunities for a more integrated approach to understanding these relationships. Additionally, a large number of new modelling and mapping methods have been developed in recent years to support the adoption of these new tools. The complexity of this research context results in study-dependent solutions and prevents landscape approaches from deeper integration into operational models and tools. In this paper we consider three common research contexts for spatial epidemiology; surveillance, modelling to estimate a spatial risk distribution and the need for intervention, and evaluating interventions and improving healthcare. A framework is proposed and a categorization of existing methods is presented. A case study into leptospirosis in Sri Lanka provides a working example of how the different phases of the framework relate to real research problems. The new framework for geocomputational landscape epidemiology encompasses four key phases: characterizing assemblages, characterizing functions, mapping interdependencies, and examining outcomes. Results from Sri Lanka provide evidence that the framework provides a useful way to structure and interpret analyses. The framework reported here is a new way to structure existing methods and tools of geocomputation that are increasingly relevant to researchers working on spatially explicit disease-landscape studies.     

Mobilization and attenuation of heavy metals within a nickel mine tailings impoundment near Sudbury, Ontario, Canada

 The oxidation and the subsequent dissolution of sulfide minerals within the Copper Cliff tailings area have led to the release of heavy metals such as Fe, Ni, and Co to the tailings pore water. Dissolved concentrations in excess of 10 g/l Fe and 2.2 g/l Ni have been detected within the shallow pore water of the tailings, with increasing depth these concentrations decrease to or near analytical detection limits. Geochemical modelling of the pore-water chemistry suggests that pH-buffering reactions are occurring within the shallow oxidized zones, and that secondary phases are precipitating at or near the underlying hardpan and transition zones. Mineralogical study of the tailings confirmed the presence of goethite, jarosite, gypsum, native sulfur, and a vermiculite-type clay mineral. Goethite, jarosite, and native sulfur form alteration rims and pseudo-morphs of the sulfide minerals. Interstitial cements, composed of goethite, jarosite, and gypsum, locally bind the tailings particles, forming hardpan layers. Microprobe analyses of the goethite indicate that it contains up to 0.6 weight % Ni, suggesting that the goethite is a repository for Ni. Other sinks detected for heavy metals include jarosite and a vemiculite-type clay mineral which locally contains up to 1.6 weight % Ni. To estimate the mass and distribution of heavy metals associated with the secondary phases within the shallow tailings, a series of chemical extractions was completed. The experimental design permitted four fractions of the tailings to be evaluated independently. These four fractions consisted of a water-soluble, an acid-leachable, and a reducible fraction, as well as the whole-rock total. Twenty-five percent of the total mass of heavy metals was removed in the acid-leaching experiments, and 100% of the same components were removed in the reduction experiments. The data suggest that precipitation/coprecipitation reactions are providing an effective sink for most of the heavy metals released by sulfide mineral oxidation. In light of these results, potential decommissioning strategies should be evaluated with the recognition that changing the geochemical conditions may alter the stability of the secondary phases within the shallow tailings. Received: 9 April 1997 · Accepted: 21 July 1997     

Predation by estuarine zooplankton on tintinnid ciliates

Laboratory experiments were conducted to determine the feeding performances of Uca zoeae and the estuarine copepods Acartia tonsa and Tortanus setacaudatus when these zooplankton preyed upon the co-occurring tintinnids Favella panamensis (length 265 μm) and Tintinnopsis tubulosa (length 148 μm). Predation by Favella on Tintinnopsis was also studied. Over the range of experimental prey densities used, Acartia ingested Tintinopsis at rates linearly related to prey density. Favella was ingested by Aractia at higher rates than was Tintinnopsis. Tortamus ingested Favella more readily than did Acartia, but Tortanus did not ingest Tintinnopsis. Uca ingested both Tintinnopsis and Favella while Tintinnopsis was also ingested by the larger tintinnid Favella. Comparisons of Acartia predation on tintinnids with published data on ingestion of nauplii and phytoplankton showed that when the phytoplankton are dominated by small (diameters < 10 μm) species, tintinnids in concentrations exceeding 10³ organisms 1^?1 can be important items in the diets of Acartia. At lower tintinnid concentrations or when algal species with diameters > 10 μm are present in significant concentrations, tintinnids merely supplement algae in the diet of Acartia. Generally, tintinnids are more important food items for Acartia than are comparably sized nauplii. Only at concentrations exceeding 10⁴ cop. m^?3 can Acartia depress tintinid population growth.     

Lake ice records used to detect historical and future climatic changes

Historical ice records, such as freeze and breakup dates and the total duration of ice cover, can be used as a quantitative indicator of climatic change if long homogeneous records exist and if the records can be calibrated in terms of climatic changes. Lake Mendota, Wisconsin, has the longest uninterrupted ice records available for any lake in North America dating back to 1855. These records extend back prior to any reliable air temperature data in the midwestern region of the U.S. and demonstrate significant warming of approximately 1.5 °C in fall and early winter temperatures and 2.5 °C in winter and spring temperatures during the past 135 years. These changes are not completely monotonie, but rather appear as two shorter periods of climatic change in the longer record. The first change was between 1875 and 1890, when fall, winter, and spring air temperatures increased by approximately 1.5 °C. The second change, earlier ice breakup dates since 1979, was caused by a significant increase in winter and early spring air temperatures of approximately 1.3 °C. This change may be indicative of shifts in regional climatic patterns associated with global warming, possibly associated with the Greenhouse Effect.With the relationships between air temperature and freeze and break up dates, we can project how the ice cover of Lake Mendota should respond to future climatic changes. If warming occurs, the ice cover for Lake Mendota should decrease approximately 11 days per 1 °C increase. With a warming of 4 to 5 °C, years with no ice cover should occur in approximately 1 out of 15 to 30 years.     

Hα profiles from electron-heated solar flares

We briefly review the status of models of optical flare heating by electron bombardment. We recompute Brown's (1973a) flare model atmospheres using considerably revised radiative loss rates, based on Canfield's (1974b) method applied to , L, and H^–. Profiles of are computed and compared with observation. The computed profiles agree satisfactorily with those observed during the large 1972 August 7 flare, if spatial and velocity inhomogeneities are assumed. The electron injection rate inferred from is one order of magnitude less than that inferred from hard X-rays, for this event. This may be due to either (1) the neglect of a mechanism that reduces the thick-target electron injection rate or (2) failure to incorporate important radiative loss terms.     

High-permeability layers for remediation of ground water; go wide, not deep

A nitrate-reactive porous media layer comprising wood particles with very high hydraulic conductivity (K approximately 1 cm/s) was used to successfully treat nitrate in a shallow sand-and-gravel aquifer in southern Ontario. Nitrate concentrations of 1.3 to 14 mg/L as N in the aquifer were attenuated to <0.5 mg/L as N in the reactive layer. Borehole dilution testing indicated that ground water velocities in the reactive layer, although variable, averaged five times higher than in the surrounding aquifer, suggesting that the layer was capturing ground water flow from deeper in the aquifer. The use of high-K reactive media opens up the possibility of installing permeable reactive barriers as horizontal layers in the shallow water table zone that do not necessarily have to penetrate the full depth of a contaminant plume to be effective. Model simulations show that the depth of capture of a high-K layer increases as the layer width in the direction of flow increases. Shallower emplacement could decrease barrier costs at some sites.