Trace metals in sediment cores from Deception and Penguin Islands (South Shetland Islands, Antarctica)

This paper presents information on the levels of trace elements in sediments collected at Deception and Penguin Islands and tracks the sources of natural and anthropogenic inputs of metals into this sub-Antarctic region. The results suggest that natural processes, such as volcanic activity, hydrothermal processes and sediment transport, are more important than anthropogenic inputs in accounting for the metal concentrations measured in sediments at Deception Island. The higher levels of trace metals recorded in sediments at Penguin Island seem to reflect the composition of the source rocks of the island, which are dominated by the olivine-basalt group. Our findings show that human activities in the study areas may contribute to negligible levels of trace metals associated with anthropogenic inputs (e.g., Cr and Zn) in sediments, and these results can be used in the future as background levels related to low anthropogenic impacts.     

Thermoelasticity and high-<Emphasis Type="Italic">T</Emphasis> behaviour of anthophyllite

The thermoelastic behaviour of anthophyllite has been determined for a natural crystal with crystal-chemical formula ^ANa_0.01 ^B(Mg_1.30Mn_0.57Ca_0.09Na_0.04) ^C(Mg_4.95Fe_0.02Al_0.03) ^T(Si_8.00)O₂₂ ^W(OH)₂ using single-crystal X-ray diffraction to 973 K. The best model for fitting the thermal expansion data is that of Berman (J Petrol 29:445–522, 1988) in which the coefficient of volume thermal expansion varies linearly with T as α _V,T  = a ₁ + 2a ₂ (T − T ₀): α₂₉₈ = a ₁ = 3.40(6) × 10⁻⁵ K⁻¹, a ₂ = 5.1(1.0) × 10⁻⁹ K⁻². The corresponding axial thermal expansion coefficients for this linear model are: α _a ,₂₉₈ = 1.21(2) × 10⁻⁵ K⁻¹, a _2,a  = 5.2(4) × 10⁻⁹ K⁻²; α _b ,₂₉₈ = 9.2(1) × 10⁻⁶ K⁻¹, a _2,b  = 7(2) × 10⁻¹⁰ K⁻². α _c ,₂₉₈ = 1.26(3) × 10⁻⁵ K⁻¹, a _2,c  = 1.3(6) × 10⁻⁹ K⁻². The thermoelastic behaviour of anthophyllite differs from that of most monoclinic (C2/m) amphiboles: (a) the ε ₁ − ε ₂ plane of the unit-strain ellipsoid, which is normal to b in anthophyllite but usually at a high angle to c in monoclinic amphiboles; (b) the strain components are ε ₁ ≫ ε ₂ > ε ₃ in anthophyllite, but ε ₁ ~ ε ₂ ≫ ε ₃ in monoclinic amphiboles. The strain behaviour of anthophyllite is similar to that of synthetic C2/m ^ANa ^B(LiMg) ^CMg₅ ^TSi₈ O₂₂ ^W(OH)₂, suggesting that high contents of small cations at the B-site may be primarily responsible for the much higher thermal expansion ⊥(100). Refined values for site-scattering at M4 decrease from 31.64 epfu at 298 K to 30.81 epfu at 973 K, which couples with similar increases of those of M1 and M2 sites. These changes in site scattering are interpreted in terms of Mn ↔ Mg exchange involving M1,2 ↔ M4, which was first detected at 673 K.     

Towards hydrological triggering mechanisms of large deep-seated landslides

It is a widely accepted idea that hydrologically triggered deep-seated landslides are initiated by an increase in pore-water pressure on potential slip surface induced by rising groundwater level after prolonged period of intense rainfall although the process is not fully understood. In order to contribute to better understanding, the rainfall–groundwater relationships, hydrogeological monitoring and repeated geoelectrical imaging were carried out from March 2007 to April 2011 in large deep-seated landslide near ?ubietová (Western Carpathians) catastrophically reactivated at the end of February 1977. Based on our observations, groundwater level (GWL) response to precipitation differs considerably with respect to both overall hydrological conditions and GWL mean depth. While the rate of GWL increase up to 25 cm/day were measured after some rainfall events during wet periods, noticeably lower recharge rate (up to 1–2 cm/day) and delayed GWL response to rainfall (usually from 2 weeks to 2–4 months) were observed at the beginning of the wet season after considerable depression of GWLs due to previous effective rainfall deficit. Likewise, slow GWL fluctuations without short-term oscillations are typical for deeper GWLs. Thus, long-term (several seasons to several years) hydrological conditions affect markedly groundwater response to rainfall events in the studied landslide and can be crucial for its behaviour. Comparison of hydrological conditions characterising the analysed period with those that accompanied the landslide reactivation in 1977 allow us to assume that slightly above-average rainy season following the prolonged wet period can be far more responsible for movement acceleration (and possibly failure initiation) in deep landslides than the isolated season of extreme precipitation following a longer dry period. This is true especially for landslides in regions with significant seasonal temperature changes where potential effective precipitation (PEP), calculated as excess of precipitation (P) over potential evapotranspiration (PET), may be efficiently used for estimation of slope saturation condition.     

The Acre Basin basement (NW Brazil) and the transition from the intracratonic to retroarc foreland basin system

The understanding of the crustal transition between orogenic zones and cratonic portions in distal regions of foreland basins has received increasing attention, but the analysis is often hampered by the sedimentary cover. Despite the peculiar location of the Acre Basin, specifically between the Amazonian Craton and the sub-Andean zone, local basement studies are still scarce due to lacking seismic data and exploratory wells. Therefore, this work aims to map basement depths, estimate crustal compositions and identify the main depocenters, structures and limits of Acre Basin using an integrated analysis to understand better the region lithospheric evolution, its relationship with the Amazonian Craton and its positioning within the Andean orogeny. For that, we used well, 2D seismic reflection, airborne and ground gravity and magnetic data as well as the EMG2008. Tilt Depth estimates indicate basement depths between 500 and 7800 m and larger sedimentary thicknesses in the northern portion. Additionally, we modelled groups of potential sources between 0.1 and 22 km and Moho depths between 26 and 37 km. Compositionally, the upper crust consists dominantly of meta-sedimentary and low-grade metamorphic rocks and granites, indicating that the sub-Andean and Acre Basins share a similar basement. Thus, there are indications that the basement of the Acre Basin is essentially formed by the Sunsás province in the Amazonian Craton. However, local differences in basement depth, magnetic susceptibility and exploratory potential led to the subdivision into Divisor and Xapuri sub-basins, north and south of the Fitzcarrald Arch, respectively. Finally, it was possible to establish the limits of the Andean orogeny influence in the Acre Basin and delimit the area of the Western Amazon Foredeep installed during the Neogene.     

Using the present to estimate the future: A simplified approach for the quantification of climate change effects on urban flooding by scenario analysis

Understanding and modelling pluvial flood patterns is pivotal for the estimation of flood impacts in urban areas, especially in a climate change perspective. However, urban flood modelling under climate change conditions poses several challenges. On one hand, the identification and collection of climate change data suitable for flood-related evaluations requires consistent computational and scientific effort. On the other hand, large difficulties can arise in the reproduction of the rainfall-runoff transformation process in cases when only little information about the subsurface processes is known. In this perspective, a simplified approach is proposed to address the challenges regarding the quantitative estimation of climate change effects on urban flooding for real case applications. The approach is defined as “bottom-up” because climate change information is not included in flood modelling, but it is only invoked for the interpretation of results. In other words, the challenge faced in this work is the development of a modelling strategy that is expeditious, because it does not require flood simulations for future rainfall scenarios, but only under current climate conditions, thus reducing the overall computational effort; and it is flexible, because results can be easily updated once new climate change data, scenarios or methods become available, without the need of additional flood simulations. To simulate real case applications, the approach is tested for a scenario analysis, where different return periods and hyetograph shapes are used as input for urban inundation modelling in Naples, Italy. The approach can support public and private stakeholders, such as land administrators and water systems managers; moreover, it represents a valuable and effective basis for climate change risk communication strategies.     

Changes and variations of polycyclic aromatic hydrocarbon concentrations in fish, barnacles and crabs following an oil spill in a mangrove of Guanabara Bay, Southeast Brazil

On April 26th, 2005, an accident caused a leak of 60,000 L of Diesel Oil Type “B”, freighted by train wagons upstream on a mangrove area within Guanabara Bay, Southeast Brazil. After the accident, samples from animals with different biological requirements were collected in order to monitor polycyclic aromatic hydrocarbons concentrations for the following 12 months. Sessile, mobile, carnivorous, omnivorous, organic detritus feeders, planktivorous and suspension feeders were some of the attributes compared. Concentrations of PAHs did not vary in relation to different dietary habits and the best response was from the sessile suspensivorous barnacles. A background level of <50 μg kg⁻¹ was suggested based on the reference site and on values observed in the following months after the accident. The highest values of PAH concentrations were observed in barnacles in the first month immediately after the spill, decreasing to background levels after few months. Barnacles are suggested as a sentinel species.     

Reconstructing the palaeoenvironments of the early Pleistocene mammal faunas from the pollen preserved on fossil bones

We carried out a systematic investigation on the pollen content of sediment adhering to skeletal elements of large mammals which originate from the long lacustrine record of Leffe (Early Pleistocene of the Italian Alps). Three local faunas were discovered during mining activities along the intermediate part (spanning from 1.5 to 0.95 Ma) of the basin succession. The excellent pollen preservation allowed testing the reproducibility of the pollen signal from single skeletons. A clear palaeoenvironmental patterning, consistent with the ecological preferences of the considered mammal species, emerged from the canonical correspondence analysis of pollen types diagnostic for vegetation communities. Edaphic factors related to seasonal river activity changes and to the development of swamp forests in the riverbanks are significantly associated to the occurrences of Hippopotamus cf. antiquus, whereas finds of Mammuthus meridionalis belong to fully forested landscapes dominated by conifer or mixed forests of oceanic, warm to cool-temperate climate. Rhinoceros habitats include variable forest cover under different climate states. Distinct cool-temperate, partially open vegetation could be recognized for large deer included Cervalces cf carnutorum.A palynostratigraphic correlation between individual spectra and a reference palynostratigraphic record allowed assignment of many fossil remains to a precise stratigraphic position. This procedure also shown that the Leffe local faunas include specimens accumulated under different environmental and climate states, as a consequence of high-frequency climate changes characterizing the Late Villafranchian Early Pleistocene.     

Syn-orogenic extension in the Peloritani Alpine Thrust Belt (NE Sicily,Italy): Evidence from the Alì Unit

Structural and petrological analyses on the Alì Unit, in the Peloritani Thrust Belt, document the first evidence for Alpine exhumation associated with syn-orogenic extension in this part of the Calabria-Peloritani Arc. The Alì Unit displays ductile structures occurred during three Alpine deformation phases (D_a1, D_a2, D_a3). D_a1 and D_a3 developed in a contractional context, whereas D_a2 was generated in an extensional regime. The present-day tectonic contact between the Alì Unit and the overlying Mandanici Unit is interpreted as a low-angle extensional detachment responsible for the metamorphic break between the two units. Structural overprinting relationships indicate that the development of D_a2 structures and related tectonic exhumation occurred during syn-convergence extension, and were followed by further nappe stacking in the Peloritani Belt. To cite this article: R. Somma et al., C. R. Geoscience 337 (2005).     

Correlation between the rainfall,sediment recharge,and triggering of torrential flows in the Rebaixader catchment (Pyrenees,Spain)

The debris flow (DF) and debris flood (DFD) activity in the Rebaixader catchment (Spanish Pyrenees) is analyzed in this study. The research is focused on how precipitation leads to the triggering of torrential floods and influences the sediment availability during the recharge period, in a supply-unlimited catchment. Two kinds of correlations are studied: (1) the correlation between the rainfall features (intensity and kinetic energy) and the DF/DFD triggering and (2) the correlation between the hyetograph and the DF/DFD volumes. The tested hypothesis was that a greater amount of rainfall during the recharge period would produce a greater DF/DFD volume. The period between two consecutive DF/DFD events is processed using a variable, the Erosion Index, originally developed for the Universal Soil Loss Equation. This analysis considered the rainfall time series and 22 DF/DFD events registered during the period 2009–2015. The results show that the precipitation of the recharge period does not seem to have a strong influence on the mobilized volumes. In many cases, a second DF/DFD event was triggered soon after the previous event, which highlighted the role of the first event in creating an unstable state of the catchment. Additionally, a threshold relationship between the kinetic energy of the rainfall event and the maximum rainfall intensity for a 30-min period seems to be a good criterion to discriminate between triggering and non-triggering rainfall events. The results show no clear trends with which to forecast the sediment volume from precipitation, weakening the role of rainfall characteristics in determining the return period of mobilized sediment volumes in catchments similar to the Rebaixader torrent.