Geospatial method for computing supplemental multi-decadal US coastal land use and land cover classification products,using Landsat data and C-CAP products

This paper discusses the development and implementation of a method that can be used with multi-decadal Landsat data for computing general coastal US land use and land cover (LULC) maps consisting of seven classes. With Mobile Bay, Alabama as the study region, the method that was applied to derive LULC products for nine dates across a 34-year time span. Classifications were computed and refined using decision rules in conjunction with unsupervised classification of Landsat data and Coastal Change and Analysis Program value-added products. Each classification’s overall accuracy was assessed by comparing stratified random locations to available high spatial resolution satellite and aerial imagery, field survey data and raw Landsat RGBs. Overall classification accuracies ranged from 83 to 91% with overall κ statistics ranging from 0.78 to 0.89. Accurate classifications were computed for all nine dates, yielding effective results regardless of season and Landsat sensor. This classification method provided useful map inputs for computing LULC change products.     

Insights into Li and Li isotope cycling and sub-arc metasomatism from veined mantle xenoliths,Kamchatka

Harzburgitic xenoliths cut by pyroxenite veins from Avachinsky volcano, Kamchatka, are derived from the sub-arc mantle and record element transfer from the slab to the arc. Olivine and orthopyroxene in the harzburgites have Li isotopic compositions (δ⁷Li = +2.8 to +5.6) comparable to estimates of the upper mantle (δ⁷Li ~ +4 ± 2). The pyroxenite veins, which represent modal metasomatism and may therefore provide information about the metasomatic agent, have mantle-normalized trace element characteristics that suggest overprinting of their mantle source by an aqueous, slab-derived fluid. These include relative enrichments of Pb over Ce, U over Th and Sr over Nd. Li is enriched relative to the HREE, and ortho- and clinopyroxene from the veins are in Li elemental and isotopic equilibrium with each other and the surrounding harzburgite. Vein samples (δ⁷Li = +3.0 to +5.0) do not record a significant slab-derived δ⁷Li signature. These observations can be reconciled if slab Li diffusively re-equilibrates in the mantle wedge. Modeling demonstrates that Li equilibration of small (1–2 cm width) veins or melt conduits is achieved at mantle wedge temperatures within 10¹–10⁵ years. We conclude that strongly fractionated Li isotopic signatures cannot be sustained for long periods in the sub-arc mantle, at least at shallow (<70 km) depths. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Correlating Alpine glaciation with Adriatic sea‐level changes through lake and alluvial stratigraphy

We compare lake and alluvial stratigraphy along a frame connecting the southern Alpine foothills and the Adriatic Sea, with the aim of matching the effects of Alpine glaciation and sea‐level changes on sedimentation during the last glacial cycle. The palynostratigraphy of Lake Fimon provided proxies for regional vegetation and climate change and was coupled with sediment petrography, loss on ignition and magnetic susceptibility, disentangling alluvial phases from fluvioglacial activity related to culminations of the southeastern Alpine glaciers. The Fimon area was not reached by alluvial fans during the penultimate glacial maximum, nor by the sea transgression during the last interglacial, but a closed lake soon developed at the Eemian onset due to enhanced rainfall. Sea‐level fall at glacial inception triggered the entrenchment of the drainage network in the plain reaching the outer Fimon Basin. Slow aggradation, but no sign of fluvioglacial activity, lasted to 38.2 ± 1.45 cal. ka BP, when a major forest withdrawal took place, coeval to the spread of alluvial fans. By 27.5 ± 0.5 cal. ka BP the Fimon Basin was dammed by the Brenta outwash system. The main step of of forest recovery commenced at around (15.8) cal. ka BP, when apex trenching of the outwash fans was triggered by the glacier's decay. Copyright © 2011 John Wiley & Sons, Ltd.     

Assessing landslide exposure in areas with limited landslide information

Landslide risk assessment is often a difficult task due to the lack of temporal data on landslides and triggering events (frequency), run-out distance, landslide magnitude and vulnerability. The probability of occurrence of landslides is often very difficult to predict, as well as the expected magnitude of events, due to the limited data availability on past landslide activity. In this paper, a qualitative procedure for assessing the exposure of elements at risk is presented for an area of the Apulia region (Italy) where no temporal information on landslide occurrence is available. Given these limitations in data availability, it was not possible to produce a reliable landslide hazard map and, consequently, a risk map. The qualitative analysis was carried out using the spatial multi-criteria evaluation method in a global information system. A landslide susceptibility composite index map and four asset index maps (physical, social, economic and environmental) were generated separately through a hierarchical procedure of standardising and weighting. The four asset index maps were combined in order to obtain a qualitative weighted assets map, which, combined with the landslide susceptibility composite index map, has provided the final qualitative landslide exposure map. The resulting map represents the spatial distribution of the exposure level in the study area; this information could be used in a preliminary stage of regional planning. In order to demonstrate how such an exposure map could be used in a basic risk assessment, a quantification of the economic losses at municipal level was carried out, and the temporal probability of landslides was estimated, on the basis of the expert knowledge. Although the proposed methodology for the exposure assessment did not consider the landslide run-out and vulnerability quantification, the results obtained allow to rank the municipalities in terms of increasing exposure and risk level and, consequently, to identify the priorities for designing appropriate landslide risk mitigation plans.     

Identification of Anomalous Aluminium Contents in Surface and Ground Water in the Alba Territory (NW Italy)

Aluminium was determined in surface and ground waters in the Alba region of NW Italy to provide information on natural and anthropogenic sources of contamination. Determinations were made by a spectrophotometric method based on the aluminium-pyrocatechol complex. The total aluminium content of waters was determined as well as the toxic form of monomeric aluminium, obtained from samples that had been passed through 0.20 μm cellulose filters to remove colloidal and particulate material. Results were correlated with mortality data associated with Alzheimer's disease. There appeared to be a correlation between mortality data and areas having the highest aluminium content of water.     

QUE 94204: A primitive enstatite achondrite produced by the partial melting of an E chondrite‐like protolith

Abstract– Queen Alexandra Range (QUE) 94204, an enstatite achondrite, is a coarse‐grained, highly recrystallized, chondrule‐free and unbrecciated rock dominated (about 70 vol%) by anhedral, equigranular crystals of orthoenstatite of nearly endmember composition (Fs_0.1–0.4, Wo_0.3–0.4) with interstitial plagioclase, kamacite, and troilite. Abundance of approximately 120° triple junctions and the close association of metal–sulfide and plagioclase‐rich melts indicate that QUE 94204 has undergone limited partial melting with inefficient melt extraction. Mineral chemistry indicates a high degree of thermal metamorphism. Kamacite in QUE 94204 contains between 2.09 and 2.55 wt% Si, similar to highly metamorphosed EL chondrites. Plagioclase has between 4.31 and 6.66 wt% CaO, higher than other E chondrites but closer in composition to plagioclase from metamorphosed EL chondrites. QUE 94204 troilite contains up to 2.55 wt% Ti, consistent with extensive thermal metamorphism of an E chondrite‐like precursor. Results presented in this study indicate that QUE 94204 is the result of low degree, (about 5–20 vol%, probably toward the lower end of this range) partial melting of an E chondrite protolith. Textural and chemical evidence suggests that during the metamorphism of QUE 94204, melts formed first at the Fe,Ni‐FeS cotectic near approximately 900 °C, followed by plagioclase‐pyroxene silicate partial melts near approximately 1100 °C. Neither the Fe,Ni‐FeS nor the plagioclase‐pyroxene melts were efficiently segregated or extracted. QUE 94204 belongs to a grouplet of similar “primitive enstatite achondrites” that are analogous to the acapulcoites‐lodranites, but that have resulted from the partial melting of an E chondrite‐like protolith.     

Fish bile as a biomarker for metal exposure

Fish accumulate several trace elements in muscle, gills and liver, however studies also indicate that metals can be excreted through bile. Since metal contamination leads to modifications in bile composition, biliary excretion offers an alternative way to evaluate the presence of trace-elements. Bile is easier to obtain than other organs and presents a simpler matrix, making it easier for chemical pre-treatment. To verify if bile can be useful as a biomonitoring tool for metal contamination, liver and bile trace element concentrations were determined and correlated. The Artificial Neural Networks statistical technique was used to verify if liver trace-element quantification could be substituted by bile analysis. Results show that significant correlations were obtained between trace elements in bile and liver and the ANN validated the hypothesis that certain trace-elements in bile could be utilized instead of liver trace-elements. Further studies in this field are of interest to further validate this biomarker.     

PCBs and PAHs in surficial sediments from aquatic environments of Mexico City and the coastal states of Sonora,Sinaloa, Oaxaca and Veracruz (Mexico)

Concentrations of polychlorinated biphenyls (PCBs) and polycyclic aromatic hydrocarbons (PAHs) were measured in 13 surficial sediment samples collected at three lacustrine locations in the surroundings of Mexico City and four coastal areas of the States of Sinaloa, Sonora, Oaxaca and Veracruz. Total PCB concentrations span the interval 3.18–621 ng g⁻¹. The highest values (63.7–621 ng g⁻¹) were found in Mexico City, which is a highly anthropogenically impacted area, whereas low concentrations (3.18–12.9 ng g⁻¹) were characteristic of seven places, some of them subject to intense hydrodynamics. In these latter cases, values increase by 18–73 times if normalised against the fine fraction (silt plus clay) content in sediment. Two samples from Mexico City exceed the ERM (Effect Range Median) guidelines and are likely to cause adverse effects. Samples contain only lower chlorinated PCBs (mainly 2-, 3- and 4-CB), thus suggesting that the most used PCB commercial mixture was Aroclor 1242. The homologue composition of the sample taken close to the nuclear power plant of Laguna Verde is identical to this commercial mixture. PAHs in the same samples have relatively low concentrations (14.9–287 ng g⁻¹), well below ERL (Effect Range Low) guidelines. The composition of PAH mixtures accounts for the influence of both petrogenic and pyrolitic sources, with these latter prevailing at some places in Mexico City.