Increased Terrestrial to Ocean Sediment and Carbon Fluxes in the Northern Chesapeake Bay Associated With Twentieth Century Land Alteration

We calculated Chesapeake Bay (CB) sediment and carbon fluxes before and after major anthropogenic land clearance using robust monitoring, modeling and sedimentary data. Four distinct fluxes in the estuarine system were considered including (1) the flux of eroded material from the watershed to streams, (2) the flux of suspended sediment at river fall lines, (3) the burial flux in tributary sediments, and (4) the burial flux in main CB sediments. The sedimentary maximum in Ambrosia (ragweed) pollen marked peak land clearance (~1900 a.d.). Rivers feeding CB had a total organic carbon (TOC)/total suspended solids of 0.24?±?0.12, and we used this observation to calculate TOC fluxes from sediment fluxes. Sediment and carbon fluxes increased by 138–269% across all four regions after land clearance. Our results demonstrate that sediment delivery to CB is subject to significant lags and that excess post-land clearance sediment loads have not reached the ocean. Post-land clearance increases in erosional flux from watersheds, and burial in estuaries are important processes that must be considered to calculate accurate global sediment and carbon budgets.     

Energy Spectra of Cosmic-Ray Protons and Nuclei Measured in the NUCLEON Experiment Using a New Method

Astronomy Reports - Some results of studies of cosmic rays obtained during the NUCLEON space experiment in 2015–2017 are presented. This experiment was intended for direct measurements of the...     

Southern Urals and Rudny Altai: A Comparative Paleovolcanic and Metallogenic Analysis

Geology of Ore Deposits - The authors have performed a comparative paleovolcanic and metallogenic analysis of two massive sulfide-bearing regions: the Southern Urals and Rudny Altai, which are...     

Mesozoic tectonic evolution of the Southeast China Block: New insights from basin analysis

In order to better understand the Mesozoic tectonic evolution of Southeast China Block (SECB in short), this paper describes geological features of Mesozoic basins that are widely distributed in the SECB. The analyzed data are derived from a regional geological investigation on various Mesozoic basins and a recently compiled 1:1,500,000 geological map of Mesozoic–Cenozoic basins. Two types of basin are distinguished according to their tectonic settings, namely, the post-orogenic basin (Type I) and the intracontinental extensional basin (Type II); the latter includes the graben and the half-graben or faulted-depression basins. Our studies suggest that the formation of these basins connects with the evolution of geotectonics of the SECB. The post-orogenic basin (Type I) was formed in areas from the piedmont to the intraland during the interval from Late Triassic to Early Jurassic; and the formation of the intracontinental extensional basin (Type II) connects with an intracontinental crustal thinning setting in the Late Mesozoic. The graben basin was generated during the Middle Jurassic and is associated with a bimodal volcanic eruption; and the half-graben or faulted-depression basin, filled mainly by the rhyolite, tuff and sedimentary rocks during Early Cretaceous, is occupied by the Late Cretaceous–Paleogene red-colored terrestrial clastic rocks. We noticed that the modern outcrops of numerous granites and basins occur in a similar level, and the Mesozoic granitic bodies contact with the adjacent basins by large normal faults, suggesting that the modern landforms between granites and basins were yielded by the late crustal movement. The modern basin and range framework was settled down in the Cretaceous. Abundant sedimentary structures are found in the various basins, from that the deposited environments and paleo-currents are concluded; during the Late Triassic–Early Jurassic time, the source areas were situated to the north and northeast sides of the outcrop region. In this paper, we present the study results on one geological and geographical separating unit and two separating fault zones. The Wuyi orogenic belt is a Late Mesozoic paleo-geographically separating unit, the Ganjiang fault zone behaves as the western boundary of Early Cretaceous volcanic rocks, and the Zhenghe–Dapu fault zone separates the SE-China Coastal Late Mesozoic volcanic-sedimentary basins and the Wuyi orogenic belt. Finally, we discuss the geodynamic mechanisms forming various basins, proposing a three-stage model of the Mesozoic sedimentary evolution.     

Investigation of a Limestone Pillar Failure Part 2: Stress History and Application of Fracture Mechanics Approach

Summary Observed pillar failure could not be explained by comparing pillar strength with stresses on the pillar induced by mining activities. Instead, the effects of the combined stress history of strata and pillar on the deformational response of rock mass and rock were assessed. Application of the principles of fracture mechanics, i.e., extension strain and strain energy release rate criteria gave a reasonable explanation for the observed pillar behavior. The derivation of the required fracture mechanics parameters from laboratory tests is described, and the necessity of an interdisciplinary approach to rock engineering, i.e., the use of historical geology, engineering geology, mining engineering and rock mechanics, is mandated.     

Upper Cretaceous carbonate hosted zinc–lead–barite deposits in Northern Thrust Zone, northern Iraq: petrography and geochemistry

Zinc–lead–barite deposits located in Lefan and Lower Banik localities of about 25 km northeast of Zakho City, Northern Iraq consist of a group of strata-bound sulfides hosted in Upper Cretaceous (Upper Campanian–Maastrichtian) dolomitic limestone. Carbonate-hosted ores contain 3.77% Zn, 2% Pb, and 5% Fe, while in lower Banik, they contain 1.5% Zn, 0.37% Pb, and 1.4% Fe. Diagenetic processes, such as dolomitization and recrystalization in addition to the type of microfacies, provided appropriate physical and chemical conditions that permitted the passage of ore-bearing fluids and participated in precipitation and ore localization. These deposits are precipitated in a platform and developed within the Foreland Thrust Belt. Ore precipitated as infill of intergranular dolomite porosity with replaced dolomite and rudist shells forming disseminated crystals that occupy intergranular pore spaces around dolomite and calcite and as infill of dissolution spaces and fractures.     

The stiff upper LIP: investigating the High Arctic Large Igneous Province

The Canadian Arctic Islands expose a complex network of dykes and sills that belong to the High Arctic Large Igneous Province (HALIP), which intruded volatile‐rich sedimentary rocks of the Sverdrup Basin (shale, limestone, sandstone and evaporite) some 130 to 120 million years ago. There is thus great potential in studying the HALIP to learn how volatile‐rich sedimentary rocks respond to magmatic heating events during LIP emplacement. The HALIP remains, however, one of the least well known LIPs on the planet due to its remote location, short field season, and harsh climate. A Canadian–Swedish team of geologists set out in summer 2015 to further explore HALIP sills and their sedimentary host rocks, including the sampling of igneous and meta‐sedimentary rocks for subsequent geochemical analysis, and high pressure‐temperature petrological experiments to help define the actual processes and time‐scales of magma–sediment interaction. The research results will advance our understanding of how climate‐active volatiles such as CO_2, SO₂ and CH₄ are mobilised during the magma–sediment interaction related to LIP events, a process which is hypothesised to have drastically affected Earth's carbon and sulphur cycles. In addition, assimilation of sulphate evaporites, for example, is anticipated to trigger sulphide immiscibility in the magma bodies and in so doing could promote the formation of Ni‐PGE ore bodies. Here we document the joys and challenges of ‘frontier arctic fieldwork’ and discuss some of our initial observations from the High Arctic Large Igneous Province.     

Nitrogen and sulfur species in Antarctic aerosols at Mawson,Palmer Station,and Marsh (King George Island)

High volume bulk aerosol samples were collected continuously at three Antarctic sites: Mawson (67.60° S, 62.50° E) from 20 February 1987 to 6 January 1992; Palmer Station (64.77° S, 64.06° W) from 3 April 1990 to 15 June 1991; and Marsh (62.18° S, 58.30° W) from 28 March 1990, to 1 May 1991. All samples were analyzed for Na⁺, SO ₄ ^2– , NO ₃ ^– , methanesulfonate (MSA), NH ₄ ⁺ ,²¹⁰Pb, and⁷Be. At Mawson for which we have a multiple year data set, the annual mean concentration of each species sometimes vary significantly from one year to the next: Na⁺, 68–151 ng m^–3; NO ₃ ^– , 25–30 ng m^–3; nss SO ₄ ^2– , 81–97 ng m^–3; MSA, 19–28 ng m^–3; NH ₄ ⁺ , 16–21 ng m^–3;²¹⁰Pb, 0.75–0.86 fCi m^–3. Results from multiple variable regression of non-sea-salt (nss) SO ₄ ^2– with MSA and NO ₃ ^– as the independent variables indicates that, at Mawson, the nss SO ₄ ^2– /MSA ratio resulting from the oxidation of dimethylsulfide (DMS) is 2.80±0.13, about 13% lower than our earlier estimate (3.22) that was based on 2.5 years of data. A similar analysis indicates that the ratio at Palmer is about 40% lower, 1.71±0.10, and more comparable to previous results over the southern oceans. These results when combined with previously published data suggest that the differences in the ratio may reflect a more rapid loss of MSA relative to nss SO ₄ ^2– during transport over Antarctica from the oceanic source region. The mean²¹⁰Pb concentrations at Palmer and Marsh and the mean NO ₃ ^– concentration at Palmer are about a factor of two lower than those at Mawson. The²¹⁰Pb distributions are consistent with a²¹⁰Pb minimum in the marine boundary layer in the region of 40°–60° S. These features and the similar seasonalities of NO ₃ ^– and²¹⁰Pb at Mawson support the conclusion that the primary source regions for NO ₃ ^– are continental. In contrast, the mean concentrations of MSA, nss SO ₄ ^2– , and NH ₄ ⁺ at Palmer are all higher than those at Mawson: MSA by a factor of 2; nss SO ₄ ^2– by 10%; and NH ₄ ⁺ by more than 50%. However, the factor differences exhibit substantial seasonal variability; the largest differences generally occur during the austral summer when the concentrations of most of the species are highest. NH ₄ ⁺ /(nss SO ₄ ^2– +MSA) equivalent ratios indicate that NH₃ neutralizes about 60% of the sulfur acids during December at both Mawson and Palmer, but only about 30% at Mawson during February and March.     

A Note on Reviving the Goddard Satellite-Based Surface Turbulent Fluxes （GSSTF） Dataset

Accurate sea surface flux measurements are crucial for understanding the global water and energy cycles. The oceanic evaporation, which is a major component of the global oceanic fresh water flux, is useful for predicting oceanic circulation and transport. The global Goddard Satellite-based Surface Turbulent Fluxes Version-2 (GSSTF2; July 1987--December 2000) dateset that was officially released in 2001 has been widely used by scientific community for global energy and water cycle research, and regional and short period data analyses. We have recently been funded by NASA to resume processing the GSSTF dataset with an objective of continually producing a uniform dataset of sea surface turbulent fluxes, derived from remote sensing data. The dataset is to be reprocessed and brought up-to-date (GSSTF2b) using improved input datasets such as a recently upgraded NCEP/DOE sea surface temperature reanalysis, and an upgraded surface wind and microwave brightness temperature V6 dataset (Version 6) from the Special Sensor Microwave Imager (SSM/I) produced by Remote Sensing Systems (RSS). A second new product (GSSTF3) is further proposed with a finer temporal (12-h) and spatial (0.25^ox0.25^o) resolution. GSSTF2b (July 1987--December 2008) and GSSTF3 (July 1999--December 2009) will be released for the research community to use by late 2009 and early 2011, respectively.     

Chloride and Bromide Loss from Sea-Salt Particles in Southern Ocean Air

Datasets on aerosol composition in Southern Ocean air at Cape Grim and Macquarie Island, and rainwater composition at Cape Grim, have been analysed for sea-salt components in order to test the validity of the multiphase autocatalytic halogen activation process proposed initially by Sander and Crutzen (1996) and developed fully for clean marine air by Vogt et al. (1996). Four distinct datasets from the two locations were analysed. All four datasets provided consistent evidence in support of three predictions of the autocatalytic model: (1) overall Cl- deficits in sea-salt aerosol were small, difficult to quantify against analytical uncertainty and at most a few percent; (2) Br- deficits were large, averaging –30% to –50% on an annual basis, with strong seasonality ranging from about –10% in some winter samples to –80% or more in some summer samples; and (3) the Br- and Cl- deficits were clearly linked to the availability of strong, S-acidity in the aerosol, confirming the importance of acid catalysis to the dehalogenation process.