Australasian microtektites from Antarctica: XAS determination of the Fe oxidation state

The Fe oxidation state and coordination number of 29 impact glass spherules recently recovered from the Transantarctic Mountains (Antarctica) have been determined by X‐ray absorption near edge structure (XANES) spectroscopy. Based on geochemical, isotopic, and fission track data, these spherules are considered as microtektites from the Australasian tektite/microtektite strewn field. Their find location is the farthest so far discovered from the possible source crater region, and their alkali content is the lowest compared with other published data on Australasian microtektite glasses. The Fe³⁺/(Fe²⁺+Fe³⁺) ratio, determined from the analysis of the pre‐edge peak energy position and integrated intensity, is below 0.1 (±0.04) for all the samples, and is comparable to that of most tektites and microtektites from the Australasian strewn field. Also, the pre‐edge peak integrated intensity, which is sensitive to the average Fe coordination geometry, is comparable to that of other Australasian microtektites reported in the literature. The agreement of the Fe oxidation state and coordination number, between the Transantarctic Mountain microtektites (TAM) and the Australasian tektites and microtektites, further confirms the impact origin of these glass spherules and provides an independent suggestion that they represent a major extension southeastward of the Australasian strewn field. The fact that similar redox conditions are observed in tektites and microtektites within the Australasian strewn field regardless of the distance from the source crater area (up to approximately 11000 km) could be an important constraint for better understanding the different processes affecting microtektite formation and transport. The fact that the Fe oxidation state of microtektites does not increase with distance, as in the case of North American microtektites, means that thermal and redox histories of Australasian and TAM microtektites could differ significantly from those of North American microtektites.     

Changing eruptive styles in basaltic explosive volcanism: Examples from Croscat complex scoria cone, Garrotxa Volcanic Field (NE Iberian Peninsula)

The Croscat pyroclastic succession has been analysed to investigate the transition between different eruptive styles in basaltic monogenetic volcanoes, with particular emphasis on the role of phreatomagmatism in triggering Violent Strombolian eruptions. Croscat volcano, an 11 ka basaltic complex scoria cone in the Quaternary Garrotxa Volcanic Field (GVF) shows pyroclastic deposits related both to magmatic and phreatomagmatic explosions.Lithofacies analysis, grain size distribution, chemical composition, glass shard morphologies, vesicularity, bubble-number density and crystallinity of the Croscat pyroclastic succession have been used to characterize the different eruptive styles. Eruptions at Croscat began with fissural Hawaiian-type fountaining that rapidly changed to eruption types transitional between Hawaiian and Strombolian from a central vent. A first phreatomagmatic phase occurred by the interaction between magma and water from a shallow aquifer system at the waning of the Hawaiian- and Strombolian-types stage. A Violent Strombolian explosion then occurred, producing a widespread (8 km²), voluminous tephra blanket. The related deposits are characterized by the presence of wood-shaped, highly vesicular scoriae. Glass-bearing xenoliths (buchites) are also present within the deposit. At the waning of the Violent Strombolian phase a second phreatomagmatic phase occurred, producing a second voluminous deposit dispersed over 8.4 km². The eruption ended with a lava flow emission and consequent breaching of the western-side of the volcano. Our data suggest that the Croscat Violent Strombolian phase was related to the ascent of deeper, crystal-poor, highly vesicular magma under fast decompression rate. Particles and vesicles elongation and brittle failure observed in the wood-shaped clasts indicate that fragmentation during Violent Strombolian phase was enhanced by high strain-rate of the magma within the conduit.     

Exploration and decision-making in geotechnical engineering – a case study

ABSTRACT

The paper presents methodologies for exploration planning under uncertain conditions based on virtual exploration and Bayesian updating. The process starts with site characterization using existing information to produce geologic profiles. Initial distributions of cost and time are obtained with a Bayesian network model that optimizes the construction strategy for particular geologic conditions. This is followed by the unique step to determine with a “virtual exploration” if additional exploration (e.g. borings) is warranted, and if so, where it should be best done. All this is then applied to the planned Abu Dhabi subway tunnels providing the transportation planners with necessary information for planning and design.     

Chemical and mineralogical evidence of the occurrence of mantle metasomatism by carbonate-rich melts in an oceanic environment (Santiago Island, Cape Verde)

Lavas from Santiago Island attest to a complex magmatic history, in which heterogeneous mantle source(s) and the interactions of advecting magmas with thick metasomatised oceanic lithosphere played an important role in the observed isotopic and trace element signatures. Young (<3.3 Ma) primitive lavas from Santiago Island are characterised by pronounced negative K anomalies and trace element systematics indicating that during partial melting D_K>D_Ce. These features suggest equilibration with an oceanic lithospheric mantle containing K-rich hydrous mineral assemblages, consistent with the occurrence of amphibole + phlogopite in associated metasomatised lherzolite xenoliths, where orthopyroxene is partially replaced by newly formed olivine + (CO₂ + spinel + carbonate inclusion-rich) clinopyroxene. Metasomatism induced a decrease in $ a ^{{{\text{melt}}}}_{{{\text{SiO}}_{{\text{2}}} }} $ and Ti/Eu ratios, as well as an increase in fO ₂ , Ca/Sc and Sr/Sm in the Santiago magmas, suggesting a carbonatitic composition for the metasomatic agent. Santiago primitive lavas are highly enriched in incompatible elements and show a moderate range in isotopic compositions (⁸⁷Sr/⁸⁶Sr?=?0.70318–0.70391, ¹⁴³Nd/¹⁴⁴Nd?=?0.51261–0.51287, ¹⁷⁶Hf/¹⁷⁷Hf?=?0.28284–0.28297). Elemental and isotopic signatures suggest the involvement of HIMU and EM1-type mantle end-members, in agreement with the overall isotopic characteristics of the southern Cape Verde Islands. The overall geochemical characteristics of lavas from Santiago Island allow us to consider the EM1-like end-member as resulting from the involvement of subcontinental lithospheric mantle in the genesis of magmas on Santiago.     

Boundary-Layer Stress Instabilities in Neutral,Rotating Turbulent Flows

Boundary-layer instabilities are studied by analyzing the results of laboratory simulations of wall turbulence in a shear-driven rotating flow. The experiments were carried out in the Turin University Laboratory rotating water tank, where a circular flow was generated by either increasing (spin-up) or decreasing (spin-down) the rotation speed of the platform. The flow was measured using a Particle Image Velocimetry technique and the developed turbulence analyzed. Two cases were accounted for, in the former the measurements were performed over a smooth surface (bottom of the tank), while in the latter a rough-to-smooth transition was considered. The turbulent boundary layer developed inside the tank is analyzed by means of vertical profiles of mean and turbulent quantities and on the basis of drag coefficients. Then turbulent structures developed in the different cases are shown and discussed in terms of the vorticity fields. Finally, an analysis based on the concept of swirling strength was carried out to select among the vortex extremes those associated with a coherent structure.     

Climatic simulations of the eastern Andes low-level jet and its dependency on convective parameterizations

The South American low level jet (SALLJ) of the Eastern Andes is investigated with Regional Climate Model version 3 (RegCM3) simulations during the 2002–2003 austral summer using two convective parameterizations (Grell and Emanuel). The simulated SALLJ is compared with the special observations of SALLJEX (SALLJ Experiment). Both the Grell and Emanuel schemes adequately simulate the low level flow over South America. However, there are some intensity differences. Due to the larger (smaller) convective activity, the Emanuel (Grell) scheme simulates more intense (weaker) low level wind than analysis in the tropics and subtropics. The objectives criteria of Sugahara (SJ) and Bonner (BJ) were used for LLJ identification. When applied to the observations, both criteria suggest a larger frequency of the SALLJ in Santa Cruz, followed by Mariscal, Trinidad and Asunción. In Mariscal and Asunción, the diurnal cycle indicates that SJ occurs mainly at 12 UTCs (morning), while the BJ criterion presents the SALLJ as more homogenously distributed. The concentration into two of the four-times-a-day observations does not allow conclusions about the diurnal cycle in Santa Cruz and Trinidad. The simulated wind profiles result in a lower than observed frequency of SALLJ using both the SJ and BJ criteria, with fewer events obtained with the BJ. Due to the stronger simulated winds, the Emanuel scheme produces an equal or greater relative frequency of SALLJ than the Grell scheme. However, the Grell scheme using the SJ criterion simulates the SALLJ diurnal cycle closer to the observed one. Although some discrepancies between observed and simulated mean vertical profiles of the horizontal wind are noted, there is large agreement between the composites of the vertical structure of the SALLJ, especially when the SJ criterion is used with the Grell scheme. On an intraseasonal scale, a larger southward displacement of SALLJ in February and December when compared with January has been noted. The Grell and Emanuel schemes simulated this observed oscillation in the low-level flow. However, the spatial pattern and intensity of rainfall and circulation anomalies simulated by the Grell scheme are closer to the analyses than those obtained with the Emanuel scheme.