Field scale heterogeneity of redox conditions in till-upscaling to a catchment nitrate model

Point scale studies in different settings of glacial geology show a large local variation of redox conditions. There is a need to develop an upscaling methodology for catchment scale models. This paper describes a study of field-scale heterogeneity of redox-interfaces in a till aquitard within an area of 600?×?600 m. The results showed significant variation of the depths to the redox-interface and thickness of the aquitard. Nitrate was present above the redox-interface but reduced to non-detectable levels a few metres below the interface. An upscaling approach for an area of 92 km² is proposed. Two models are proposed to predict the depth to the redox-interface in the aquitard and the resulting nitrate recharge concentrations to an underlying aquifer. The first model assumes that the depth to the redox-interface reflects the hydraulic head in the aquitard, and the second model assumes that the depth of the redox-interface is randomly distributed according to a log-normal probability distribution function. The upscaling approach using the random redox model estimated recharge concentrations comparable to the observed concentration in the underlying aquifer. The presented upscaling approach is applicable in distributed catchment models where sub-grid variability cannot be represented by the large grids.     

Infrared albedos and rotation curves of the Galilean satellites

Infrared (1.5–5 μm) albedos and rotation curves of the Galilean satellites have been obtained. The data suggest that the rotational variation in the infrared is less than ±10% for all four satellites. While no conclusion about rotational variation could be reached for Io, the 1.57 μm data for the outer three satellites marginally suggest phase correlation with the visual variation. The geometric albedos obtained are in general agreement with earlier results. For Io, the absorption feature near 1.5 μm found by Pilcher et al. (1972) is confirmed, thus contradicting the flat spectrum measured by Fink et al. (1973). Io and Ganymede were observed in the 1.57 μm bandpass as they reappeared from eclipse. The curve for Io shows a slight (<10%) overshoot similar to those sometimes reported for visual measurements. This result is based on a single reappearance, and is extremely tentative.     

A distinctive type of ascending prominence — ‘fountain’

Cinematographic observations of solar prominences made at Mauna Loa during the past couple of years suggest that there is a well-defined sub-class of ascending prominences characterized by closed-system transference of chromospheric material along an arch or loop (up one leg and down the other); meanwhile the entire prominence envelope steadily rises upward and expands through the corona. We denote these prominences as fountains. Several examples are described. Fountains appear to be well contained by coronal magnetic fields. Their total kinetic energy is in the order of 10³⁰ erg but dissipation is typically quite slow (over time periods like 100 min) so that the correlative disturbances (radio bursts, coronal transients, chromopsheric brightenings, etc.) are generally unspectacular or non-existent.This research was started when E. T.-H. was still on the staff of the High Altitude Observatory.The National Center for Atmospheric Research is sponsored by the National Science Foundation.     

The sources of material comprising a mass ejection coronal transient

The origin of the material which is ejected during a white light coronal transient has not been determined heretofore. Study of a disturbance on 26 and 27 August 1973, during which a slowly ascending prominence and a more rapid accompanying coronal transient were simultaneously observed, helps to resolve this question. Prominence images obtained in Hα 6563 Å and in He II 304 Å are nearly identical. The mass ejection transient observed in white light (3700–7000 Å) appeared to be a loop about 1 R_⊙ higher than the top of the ascending prominence; it accelerated away from the prominence below it. These observations imply: (1) the bulk of the ejected material did not originate in the ascending prominence; (2) therefore, most of the material must have come from the low corona above the prominence, (and was at coronal temperatures during its outward passage); and (3) the total event - ascending prominence accompanied by coronal mass ejection - was far larger, more energetic, and longer lasting than would be inferred from the prominence observations alone. The transient of 26–27 August was slow and of atypical shape compared to other mass ejection transients, but we believe that these three conclusions apply to most, if not all, of the more than 60 loop-shaped coronal transients observed by the High Altitude Observatory's coronagraph during the nine-month flight of Skylab.     

The fall and rise of metropolitan government in Copenhagen

In this paper it is argued that the re-establishment of a metropolitan government in the Greater Copenhagen Area in 2000 (Greater Copenhagen Authority) is not to be seen as a return to the kind of regional, coordinative authority (Greater Copenhagen Council) that was abolished in the Thatcherite climate of the 1980s. Throughout the 1980s and 1990s new forms of urban governance, entrepreneurialism and a higher national priority to the capital region were introduced, which changed the conditions under which the new metropolitan government is operating. This `contextualization' of the analysis of the two generations of metropolitan government points to the fact that typologies of metropolitan government, such as the one put forward by Sharpe (1995), often lacks analytical cogency. This revised version was published online in August 2006 with corrections to the Cover Date.     

Anthropogenic contributions to atmospheric Hg, Pb and As accumulation recorded by peat cores from southern Greenland and Denmark dated using the C “bomb pulse curve”

Mercury concentrations are clearly elevated in the surface and sub-surface layers of peat cores collected from a minerotrophic (“groundwater-fed”) fen in southern Greenland (GL) and an ombrotrophic (“rainwater-fed”) bog in Denmark (DK). Using ¹⁴C to precisely date samples since ca. AD 1950 using the “atmospheric bomb pulse,” the chronology of Hg accumulation in GL is remarkably similar to the bog in DK where Hg was supplied only by atmospheric deposition: this suggests not only that Hg has been supplied to the surface layers of the minerotrophic core (GL) primarily by atmospheric inputs, but also that the peat cores have preserved a consistent record of the changing rates of atmospheric Hg accumulation. The lowest Hg fluxes in the GL core (0.3 to 0.5 μg/m²/yr) were found in peats dating from AD 550 to AD 975, compared to the maximum of 164 μg/m²/yr in AD 1953. Atmospheric Hg accumulation rates have since declined, with the value for 1995 (14 μg/m²/yr) comparable to the value for 1995 obtained by published studies of atmospheric transport modelling (12 μg/m²/yr).The greatest rates of atmospheric Hg accumulation in the DK core are also found in the sample dating from AD 1953 and are comparable in magnitude (184 μg/m²/yr) to the GL core; again, the fluxes have since gone into strong decline. The accumulation rates recorded by the peat core for AD 1994 (14 μg/m²/yr) are also comparable to the value for 1995 obtained by atmospheric transport modelling (18 μg/m²/yr). Comparing the Pb/Ti and As/Ti ratios of the DK samples with the corresponding crustal ratios (or “natural background values” for preanthropogenic peat) shows that the samples dating from 1953 also contain the maximum concentration of “excess” Pb and As. The synchroneity of the enrichments of all three elements (Hg, Pb, and As) suggests a common source, with coal-burning the most likely candidate. Independent support for this interpretation was obtained from the Pb isotope data (²⁰⁶Pb/²⁰⁷Pb = 1.1481 ± 0.0002 in the leached fraction and 1.1505 ± 0.0002 in the residual fraction) which is too radiogenic to be explained in terms of gasoline lead alone, but compares well with values for U.K. coals. In contrast, the lowest values for ²⁰⁶Pb/²⁰⁷Pb in the DK profile (1.1370 ± 0.0003 in the leached fraction and 1.1408 ± 0.0003 in the residual fraction) are found in the sample dating from AD 1979: this shows that the maximum contribution of leaded gasoline occurred approximately 25 yr after the zenith in total anthropogenic Pb deposition.     

Relay ramp evolution and mass flow deposition (Upper Kimmeridgian–Lower Volgian) in the Tail End Graben, Danish North Sea

The Central Graben in the Danish North Sea sector consists of a series of N–S to NW–SE trending, eastward‐tilted half‐grabens, bound to the east by the Coffee Soil Fault zone. This fault zone has a complex Jurassic history that encompasses at least two fault populations; N–S to NNW–SSE striking faults active in the Late Aalenian–Early Oxfordian, and NNW–SSE to WNW–ESE striking faults forming in Late Kimmeridgian time (sensu gallico), following a short period of tectonic quiescence. Sediment transport across the Coffee Soil Fault zone was controlled by fault array evolution, and in particular the development of relay ramps that formed potential entry points for antecedent drainage systems from the Ringkøbing–Fyn High east of the rift. Fault and isochore trends of the Upper Kimmeridgian–Lower Volgian succession in the northeast Danish Central Graben show that accommodation space was initially generated close to several minor, isolated or overlapping faults. Subsidence became focused along a few master faults in the Early Volgian through progressive linkage of selected faults. Seismic time isochore geometries, seismic facies, amplitude trends and well ties indicate the presence of coarse clastic lithologies locally along the fault zone. The deposits probably represent submarine mass flow deposits supplied from footwall degradation and possibly also from the graben hinterland via a relay ramp. The latter source appears to have been cut off as the relay ramp was breached and the footwall block are uplifted. Fault growth and linkage processes thus controlled the spatial and temporal trends of accommodation space generation and sediment supply to the rift basin.     

Case study on the strategy and application of enhancement solutions to improve remediation of soils contaminated with Cu, Pb and Zn by means of electrodialysis

Numerous studies have been conducted with electrochemical removal of heavy metals from spiked kaolinite. Meanwhile, when moving from kaolinite to real soils, new factors must be taken into account—factors influencing, e.g., the buffering capacity of the soil against acidification and the adsorption/desorption processes of the heavy metals. The present study gives some examples where it is necessary to use an enhancement solution to aid desorption of Cu, Zn and Pb during electrodialytic treatment. Dependent on the composition of the pollution, different choices can be made. In the case of a Cu-polluted calcareous soil, ammonia may be used as enhancement solution, due to the formation of charged complexes between ammonia and Cu. Thus, Cu is mobile at high pH when ammonia is added and Cu can be removed without dissolving the calcareous parts. Zn is also mobilized by ammonia, but to a lesser extent than Cu. In the case of Cu, Zn and Pb at the same time, alkaline ammonium citrate may be a solution. It was shown that this enhancement solution could mobilize these three pollutants, but optimization of concentration and pH of the ammonium citrate is still needed. When choosing a remediation scheme for electrochemical treatment of an actual industrially polluted soil, this scheme must be chosen on basis of characterization of soil and pollution combination.