Soil pore-water distributions and the temperature feedback of weathering in soils

A review of the literature suggests that large variations in pore-water chemistry exist within soils. The heterogeneity indicates that in soil microchemical environments, the chemistry of pore water evolves independently from one pore to another due to differences in surface area/volume ratios and water residence time. A plug-flow reactor model was developed to examine which size classes of pores contribute the most solute to water draining out of the soil profile, and to explore how temperature might affect a soil’s ability to generate solute. The model is based on the simplification that soil pores can be approximated as a suite of capillaries of varying diameter. The model simulates each size class of pores as a plug-flow reactor with an unique water residence time and surface area.In the model, the pores which drain at the highest water contents have low surface area to water volume ratios and contribute relatively little to the overall solute flux from a soil. The smallest pores that drain at the lowest water contents were found to have the highest surface area to volume ratios and contribute the most solute. The calculations also suggest that activation energy and water viscosity have competing effects on the temperature dependence of weathering. As the temperature increases, the dissolution rate constant increases and smaller pores drain; however, water residence time decreases. This decrease in the water residence time is due to decreasing water viscosity, which can be incorporated into the dissolution rate law for quartz with an activation energy of approximately −15 kJ/mole. Studies that parameterize the temperature dependence of weathering using the Arrhenius approach can account for this effect by reducing the predicted activation energy by an appropriate value.     

The geology and geochemistry of the Lumwana Cu (± Co ± U) deposits, NW Zambia

The Lumwana Cu (± Co ± U) deposits of NW Zambia are large, tabular, disseminated ore bodies, hosted within the Mwombezhi Dome of the Lufilian Arc. The host rocks to the Lumwana deposits are two mineralogically similar but texturally distinct gneisses, a granitic to pegmatitic gneiss and a banded to augen gneiss which both comprise quartz–feldspar ± biotite ± muscovite ± haematite ± amphibole and intervening quartz–feldspar ± biotite schist. The sulphide ore horizons are typically developed within a biotite–muscovite–quartz–kyanite schist, although mineralization locally occurs within internal gneiss units. Contacts between the ore and host rocks are transitional and characterized by a loss of feldspar. Kinematic indicators, such as S-C fabrics and pressure shadows on porphyroblasts, suggest a top to the north shear sense. The sulphides are deformed by a strong shear fabric, enclosed within kyanite or concentrated into low strain zones and pressure shadows around kyanite porphyroblasts. This suggests that the copper mineralization was introduced either syn- or pre-peak metamorphism. In addition to Cu and Co, the ores are also characterized by enrichments in U, V, Ni, Ba and S and small, discrete zones of uranium mineralization, occur adjacent to the hanging wall and footwall of the copper ore bodies or in the immediate footwall to the copper mineralization. Unlike typical Copperbelt mineralization, unmineralized units show very low background copper values. Whole rock geochemical analyses of the interlayered schist and ore schist, compared to the gneiss, show depletions in Ca, Na and Sr and enrichments in Mg and K, consistent with replacement of feldspar by biotite. The mineral chemistry of muscovite, biotite and chlorite reflect changes in the bulk rock chemistry and show consistent increases in X _Mg as the schists develop. δ³⁴S for copper sulphides range from +2.3?‰ to +18.5?‰, with pyrite typically restricted to values between +3.9?‰ and +6.2?‰. These values are atypical of sulphides precipitated by bacteriogenic sulphate reduction. δ³⁴S data for Chimiwungo (Cu + Co) show a broader range and increased δ³⁴S values compared to the Malundwe (Cu) mineralization. The Lumwana deposits show many characteristics which distinguish them from classical Copperbelt mineralization and which suggests that they are formed by metasomatic alteration, mineralization and shearing of pre-Katangan basement. Although this style of mineralization is reported elsewhere in the Copperbelt, sometimes associated with the more widely reported stratiform ores of the Lower Roan, none of the previously reported occurrences have so far developed the tonnages of ore reported at Lumwana.     

Economic impacts of climate change in Europe: sea-level rise

This paper uses two models to examine the direct and indirect costs of sea-level rise for Europe for a range of sea-level rise scenarios for the 2020s and 2080s: (1) the DIVA model to estimate the physical impacts of sea-level rise and the direct economic cost, including adaptation, and (2) the GTAP-EF model to assess the indirect economic implications. Without adaptation, impacts are quite significant with a large land loss and increase in the incidence of coastal flooding. By the end of the century Malta has the largest relative land loss at 12% of its total surface area, followed by Greece at 3.5% land loss. Economic losses are however larger in Poland and Germany (483 and483 and 391 million, respectively). Coastal protection is very effective in reducing these impacts and optimally undertaken leads to protection levels that are higher than 85% in the majority of European states. While the direct economic impact of sea-level rise is always negative, the final impact on countries’ economic performances estimated with the GTAP-EF model may be positive or negative. This is because factor substitution, international trade, and changes in investment patterns interact with possible positive implications. The policy insights are (1) while sea-level rise has negative and huge direct economic effects, overall effects on GDP are quite small (max −0.046% in Poland); (2) the impact of sea-level rise is not confined to the coastal zone and sea-level rise indirectly affects landlocked countries as well (Austria for instance loses −0.003% of its GDP); and (3) adaptation is crucial to keep the negative impacts of sea-level rise at an acceptable level.     

Crustal lineament control on magmatism and mineralization in northwestern Argentina: geological, geophysical, and remote sensing evidence

The relationship between long-lived deep crustal lineaments and the locations of magmatic centers and associated mineral deposits has been investigated in the Puna region of northwestern Argentina, through the analysis of regional aeromagnetic surveys, Landsat images, and geological information. The good exposure and excellent preservation of basement and supracrustal geology in this region makes it particularly suitable for such a study. At a regional scale, several contrasting magnetic domains are recognized, which correlate with crustal geology. Two basement domains are separated by a NNE-trending boundary, which is believed to correlate with a Paleozoic suture zone between the Pampia (to the southeast) and Arequipa–Antofalla terranes (to the northwest). Locally overlying these basement terranes is the Cenozoic magmatic domain, which is best developed in the N–S-trending volcanic arc at the western edge of the Puna (the Cordillera Occidental). In addition, four southeast-trending volcanic zones extend for several hundred kilometers across the Puna. Many important mineral deposits and areas of hydrothermal alteration are associated with these volcanic breakouts, and we have selected three such areas for more detailed study: Bajo de la Alumbrera (Argentina's largest porphyry copper deposit), Cerro Galán (the largest ignimbrite caldera in Argentina, with associated hydrothermal alteration zones), and El Queva (a historic polymetallic district located within a major volcanic range). A comparison of lineament maps generated from aeromagnetic and Landsat TM images reveals broad correlation between these different remote sensing techniques, which respectively highlight subsurface magnetic and surface geological features. In addition, the locations of magmatic and hydrothermal centers can be related to the interpreted structural framework, and are seen to occur near the intersections of major lineament zones. It is suggested that in three dimensions, such intersection zones form trans-lithospheric columns of low strength and high permeability during transpressional or transtensional tectonic strain, and may thereby serve as conduits for magma ascent to the shallow crust. Pooling of large volumes of deeply derived magma in shallow crustal magma chambers may then result in voluminous devolatilization and the formation of hydrothermal mineral deposits. It is important to note that in this model, structural intersections serve as facilitators for magma ascent and volatile exsolution, but do not in themselves cause this process—other factors such as magma supply rate and tectonic stress are essential primary ingredients, and local magmatic and volcanic processes affect the ultimate potential for ore formation. Nevertheless, we suggest that lineament analysis provides a valuable framework for guiding the early stages of mineral exploration; other regional and local geological considerations must then be applied to identify priority targets within this framework.     

Colliding winds in V1016 Cygni

We present MERLIN observations of the symbiotic nova V1016 Cygni made at 6 cm between 1992 and 1997 and at 18 cm in 1993 and 1997. In the 6-cm images we find complex structure which has not been previously seen, in particular three bright components. These components do not appear to be expanding as would be expected from the remains of a hot wind resulting from the nova outburst. The change in positions of two of the features exhibits tentative east–west movement. The brightness temperature of the peak with the highest flux density remains above 50 000 K in all epochs, thereby confirming the presence of shocked material in the system. At 18 cm there is no evidence of any non-thermal emission as might be expected from comparison with a sister star, HM Sge.