全文获取类型
收费全文 | 12396篇 |
免费 | 358篇 |
国内免费 | 361篇 |
专业分类
测绘学 | 321篇 |
大气科学 | 1010篇 |
地球物理 | 2577篇 |
地质学 | 4440篇 |
海洋学 | 1062篇 |
天文学 | 2734篇 |
综合类 | 38篇 |
自然地理 | 933篇 |
出版年
2022年 | 62篇 |
2021年 | 102篇 |
2020年 | 121篇 |
2019年 | 153篇 |
2018年 | 310篇 |
2017年 | 270篇 |
2016年 | 376篇 |
2015年 | 276篇 |
2014年 | 367篇 |
2013年 | 660篇 |
2012年 | 386篇 |
2011年 | 629篇 |
2010年 | 474篇 |
2009年 | 724篇 |
2008年 | 552篇 |
2007年 | 507篇 |
2006年 | 507篇 |
2005年 | 464篇 |
2004年 | 457篇 |
2003年 | 438篇 |
2002年 | 406篇 |
2001年 | 317篇 |
2000年 | 307篇 |
1999年 | 276篇 |
1998年 | 260篇 |
1997年 | 220篇 |
1996年 | 227篇 |
1995年 | 198篇 |
1994年 | 173篇 |
1993年 | 149篇 |
1992年 | 130篇 |
1991年 | 154篇 |
1990年 | 129篇 |
1989年 | 133篇 |
1988年 | 103篇 |
1987年 | 168篇 |
1986年 | 112篇 |
1985年 | 125篇 |
1984年 | 149篇 |
1983年 | 130篇 |
1982年 | 124篇 |
1981年 | 137篇 |
1980年 | 113篇 |
1979年 | 100篇 |
1978年 | 95篇 |
1977年 | 95篇 |
1976年 | 100篇 |
1975年 | 72篇 |
1974年 | 69篇 |
1973年 | 78篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
101.
Silicon isotope fractionation in bamboo and its significance to the biogeochemical cycle of silicon 总被引:2,自引:0,他引:2
A systematic investigation on silica contents and silicon isotope compositions of bamboos was undertaken. Seven bamboo plants and related soils were collected from seven locations in China. The roots, stem, branch and leaves for each plant were sampled and their silica contents and silicon isotope compositions were determined. The silica contents and silicon isotope compositions of bulk and water-soluble fraction of soils were also measured. The silica contents of studied bamboo organs vary from 0.30% to 9.95%. Within bamboo plant the silica contents show an increasing trend from stem, through branch, to leaves. In bamboo roots the silica is exclusively in the endodermis cells, but in stem, branch and leaves, the silica is accumulated mainly in epidermal cells. The silicon isotope compositions of bamboos exhibit significant variation, from −2.3‰ to 1.8‰, and large and systematic silicon isotope fractionation was observed within each bamboo. The δ30Si values decrease from roots to stem, but then increase from stem, through branch, to leaves. The ranges of δ30Si values within each bamboo vary from 1.0‰ to 3.3‰. Considering the total range of silicon isotope composition in terrestrial samples is only 7‰, the observed silicon isotope variation in single bamboo is significant and remarkable. This kind of silicon isotope variation might be caused by isotope fractionation in a Rayleigh process when SiO2 precipitated in stem, branches and leaves gradually from plant fluid. In this process the Si isotope fractionation factor between dissolved Si and precipitated Si in bamboo (αpre-sol) is estimated to be 0.9981. However, other factors should be considered to explain the decrease of δ30Si value from roots to stem, including larger ratio of dissolved H4SiO4 to precipitated SiO2 in roots than in stem. There is a positive correlation between the δ30Si values of water-soluble fractions in soils and those of bulk bamboos, indicating that the dissolved silicon in pore water and phytoliths in soil is the direct sources of silicon taken up by bamboo roots. A biochemical silicon isotope fractionation exists in process of silicon uptake by bamboo roots. Its silicon isotope fractionation factor (αbam-wa) is estimated to be 0.9988. Considering the distribution patterns of SiO2 contents and δ30Si values among different bamboo organs, evapotranspiration may be the driving force for an upward flow of a silicon-bearing fluid and silica precipitation. Passive silicon uptake and transportation may be important for bamboo, although the role of active uptake of silicic acid by roots may not be neglected. The samples with relatively high δ30Si values all grew in soils showing high content of organic materials. In contrast, the samples with relatively low δ30Si values all grew in soil showing low content of organic materials. The silicon isotope composition of bamboo may reflect the local soil type and growth conditions. Our study suggests that bamboos may play an important role in global silicon cycle. 相似文献
102.
A. van Geen K. Radloff Z. Aziz Z. Cheng M.R. Huq K.M. Ahmed B. Weinman S. Goodbred H.B. Jung Y. Zheng M. Berg P.T.K. Trang L. Charlet J. Metral D. Tisserand S. Guillot S. Chakraborty A.P. Gajurel B.N. Upreti 《Applied Geochemistry》2008
One of the reasons the processes resulting in As release to groundwater in southern Asia remain poorly understood is the high degree of spatial variability of physical and chemical properties in shallow aquifers. In an attempt to overcome this difficulty, a simple device that collects groundwater and sediment as a slurry from precisely the same interval was developed in Bangladesh. Recently published results from Bangladesh and India relying on the needle-sampler are augmented here with new data from 37 intervals of grey aquifer material of likely Holocene age in Vietnam and Nepal. A total of 145 samples of filtered groundwater ranging in depth from 3 to 36 m that were analyzed for As (1–1000 μg/L), Fe (0.01–40 mg/L), Mn (0.2–4 mg/L) and S (0.04–14 mg/L) are compared. The P-extractable (0.01–36 mg/kg) and HCl-extractable As (0.04–36 mg/kg) content of the particulate phase was determined in the same suite of samples, in addition to Fe(II)/Fe ratios (0.2–1.0) in the acid-leachable fraction of the particulate phase. Needle-sampler data from Bangladesh indicated a relationship between dissolved As in groundwater and P-extractable As in the particulate phase that was interpreted as an indication of adsorptive equilibrium, under sufficiently reducing conditions, across 3 orders of magnitude in concentrations according to a distribution coefficient of 4 mL/g. The more recent observations from India, Vietnam and Nepal show groundwater As concentrations that are often an order of magnitude lower at a given level of P-extractable As compared to Bangladesh, even if only the subset of particularly reducing intervals characterized by leachable Fe(II)/Fe >0.5 and dissolved Fe >0.2 mg/L are considered. Without attempting to explain why As appears to be particularly mobile in reducing aquifers of Bangladesh compared to the other regions, the consequences of increasing the distribution coefficient for As between the particulate and dissolved phase to 40 mL/g for the flushing of shallow aquifers of their initial As content are explored. 相似文献
103.
In order to evaluate thermodynamic speciation calculations inherent in biotic ligand models, the speciation of dissolved Cd, Cu, Pb, and Zn in aquatic systems influenced by historical mining activities is examined using equilibrium computer models and the diffusive gradients in thin films (DGT) technique. Several metal/organic-matter complexation models, including WHAM VI, NICA-Donnan, and Stockholm Humic model (SHM), are used in combination with inorganic speciation models to calculate the thermodynamic speciation of dissolved metals and concentrations of metal associated with biotic ligands (e.g., fish gills). Maximum dynamic metal concentrations, determined from total dissolved metal concentrations and thermodynamic speciation calculations, are compared with labile metal concentrations measured by DGT to assess which metal/organic-matter complexation model best describes metal speciation and, thereby, biotic ligand speciation, in the studied systems. Results indicate that the choice of model that defines metal/organic-matter interactions does not affect calculated concentrations of Cd and Zn associated with biotic ligands for geochemical conditions in the study area, whereas concentrations of Cu and Pb associated with biotic ligands depend on whether the speciation calculations use WHAM VI, NICA-Donnan, or SHM. Agreement between labile metal concentrations and dynamic metal concentrations occurs when WHAM VI is used to calculate Cu speciation and SHM is used to calculate Pb speciation. Additional work in systems that contain wide ranges in concentrations of multiple metals should incorporate analytical speciation methods, such as DGT, to constrain the speciation component of biotic ligand models. 相似文献
104.
105.
Joseph F. Whelan Leonid A. Neymark Richard J. Moscati Brian D. Marshall Edwin Roedder 《Applied Geochemistry》2008
Secondary calcite, silica and minor amounts of fluorite deposited in fractures and cavities record the chemistry, temperatures, and timing of past fluid movement in the unsaturated zone at Yucca Mountain, Nevada, the proposed site of a high-level radioactive waste repository. The distribution and geochemistry of these deposits are consistent with low-temperature precipitation from meteoric waters that infiltrated at the surface and percolated down through the unsaturated zone. However, the discovery of fluid inclusions in calcite with homogenization temperatures (Th) up to ∼80 °C was construed by some scientists as strong evidence for hydrothermal deposition. This paper reports the results of investigations to test the hypothesis of hydrothermal deposition and to determine the temperature and timing of secondary mineral deposition. Mineral precipitation temperatures in the unsaturated zone are estimated from calcite- and fluorite-hosted fluid inclusions and calcite δ18O values, and depositional timing is constrained by the 207Pb/235U ages of chalcedony or opal in the deposits. Fluid inclusion Th from 50 samples of calcite and four samples of fluorite range from ∼35 to ∼90 °C. Calcite δ18O values range from ∼0 to ∼22‰ (SMOW) but most fall between 12 and 20‰. The highest Th and the lowest δ18O values are found in the older calcite. Calcite Th and δ18O values indicate that most calcite precipitated from water with δ18O values between −13 and −7‰, similar to modern meteoric waters. 相似文献
106.
Abstract The Taiwan orogen has been the focus of a number of models of mountain building processes, but little attention has been paid to high‐pressure (HP) metamorphic rocks that are found as exotic blocks intermingled within the deepest units of the mountain belt. In this study, we re‐appraise from updated petrological and thermodynamic databases the physical conditions of HP metamorphism in Taiwan, and we combine our findings with available geochronological data to estimate the thermal history of these rocks. Our results indicate that peak metamorphic conditions of ~550 °C and 10–12 kbar have been followed by a rapid isothermal decompression, with exhumation possibly as rapid as burial. These units have subsequently been stored at a pressure of ~3 kbar for ~4–5 Myr, before their final exhumation, probably facilitated by the accretion of passive margin sequences during the Late Cenozoic collision. Therefore, HP units in Taiwan maintain a record of processes at depth from the early stages of oceanic subduction to the present arc‐continent collision. 相似文献
107.
A numerical analysis of cyclotron instabilities is carried out by computing the dispersion relation for a three component cold plasma-beam system. Rates of growth and damping for various values of the stream density are calculated from the dispersion relation. The rates of growth and damping increase monotonically as the number density of the proton stream increases. It is found that the frequencies at the rates of maximum growth and the damping decrease slightly to lower frequencies and a sharp peak at these frequencies becomes blunt. The minimum e-folding times of an ion cyclotron wave for (a) σs = 10−4, σi = 10−2 and (b) σs = 10−1, σi = 10−2 are about 3·84 and 0·16 sec respectively in the vicinity of the equatorial plane at 6 Re, where σs and σi are the ratios of the beam density Ns and the helium ion (H6+) density Ni to the total positive ions in the plasma-beam system. 相似文献
108.
109.
Summary In order to interpret the observed features of pressure records produced by waves from large explosions in the earth's atmosphere, the writers have obtained numerical solutions of the homogeneous equations governing acoustic-gravity wave propagation in a stratified compressible fluid. Theoretical dispersion curves and variations of perturbation kinetic energy with altitude are presented for 11 normal modes. It is shown that the step-like character of the phase velocity curves in the velocity-period plane can be interpreted as being the result of interference between two families of normal modes-«quasi-horizontal modes» representing energy propagation in the lower atmosphere (below the ozonosphere) and «quasi-vertical modes» representing energy propagation in the upper atmosphere (above the ozonosphere). The theoretical prediction that several normal modes contribute to the observed barogram traces is verified by Fourier analysis of a number of wave records.Lamont Geological Observatory Contribution No. 611. — This research was supported by National Science Foundation Grant NSF-G-11997, Office of Naval Research Contract Nonr 266 (70), and National Science Foundation Grant NSF-GP-550. — Part of this research was done at the NASA Institute for Space Studies, New York, N. Y. 相似文献
110.
The hydroelastic responses of a very-long floating structure (VLFS) placed behind a reverse T-shape freely floating breakwater with a built-in oscillating water column (OWC) chamber are analyzed in two dimensions. The Bernoulli–Euler beam equation is coupled with the equations of rigid and elastic motions of the breakwater and the VLFS. The interaction of waves between the floating rigid breakwater and the elastic VLFS is formulated in a consistent manner. It has been shown numerically that the structural deflections of the VLFS can be reduced significantly by a suitably designed reverse T-shape floating breakwater. 相似文献