Carbonate equilibria in hydrothermal systems: First ionization of carbonic acid in NaCl media to 300°C

The ionization quotients of aqueous carbon dioxide (carbonic acid) have been precisely determined in NaCl media to 5 m and from 50° to 300°C using potentiometric apparatus previously developed at Oak Ridge National Laboratory. The pressure coefficient was also determined to 250°C in the same media. These results have been combined with selected information in the literature and modeled in two ways to arrive at the best fits and to derive the thermodynamic parameters for the ionization reaction, including the equilibrium constant, activity coefficient quotients, and pressure coefficients. The variation with temperature of the two fundamental quantities $\text{Δ}\text{V}\text{?}{}^{\mathrm{o}}$ and $\text{Δ}\text{C}\text{?}{}^{\mathrm{o}}{}_{\mathrm{p}}$ were examined along the saturation vapor pressure curve and at constant density. The results demonstrated again that for reactions with minimal electrostriction changes the magnitudes and variations of $\text{Δ}\text{C}\text{?}{}^{\mathrm{o}}{}_{\mathrm{p}}$ and $\text{Δ}\text{V}\text{?}{}^{\mathrm{o}}$ with temperature are small and, in addition, $\text{Δ}\text{C}\text{?}{}_{\mathrm{p}}$ and $\text{Δ}\text{V}\text{?}$ are approximately independent of salt concentration.The results have also been applied to an examination of the solubility of calcite as a function of pH (in a given NaCl medium) for the neutral to acidic region both for systems with fixed CO₂ pressure and systems where the calcium ion concentration equals the concentration of carbon. The pH of saturated solutions of calcite with P_CO2 of 12 bars increases from 5.1 to 5.5 between 100° and 300°C.     

The relation between typical concentrations of chemical constituents in potable water and their injurious limits

 There is an obvious similarity between the values of the typical concentrations of the inorganic and synthetic organic constituents in potable water and their injurious limits to human health. This similarity is attributed to the adaptation of man to his environment, i.e. it has resulted from natural selection. Received: 6 August 1999 · Accepted: 30 November 1999     

Martian rampart crater ejecta: Experiments and analysis of melt-water interaction

Viking images of Martian craters with rampart-bordered ejecta deposits reveal distinct impact ejecta morphology when compared to that associated with similar-sized craters on the Moon and Mercury. Topographic control of distribution, lobate and terraced margins, cross-cutting relationships, and multiple stratigraphic units are evidence for ejecta emplacement by surface flowage. It is suggested that target water explosively vaporized during impact alters initial ballistic trajectories of ejecta and produces surging flow emplacement. The dispersal of particulates during a series of controlled steam explosions generated by interaction of a thermite melt with water has been experimentally modeled. Preliminary results indicate that the mass ratio of water to melt and confining pressure control the degree of melt fragmentation (ejecta particle size) and the energy and mode of melt-ejecta dispersal. Study of terrestrial, lobate, volcanic ejecta produced by steam-blast explosions reveals that particle size and vapor to clast volume ratio are primary parameters characterizing the emplacement mechanism and deposit morphology. Martian crater ramparts are formed when ejecta surges lose fluidizing vapors and transported particles are deposited en masse. This deposition results from flow yield strength increasing above shear stress due to interparticle friction.     

Artificial light at night: implications for early life stages development in four temperate freshwater fish species

Flora and fauna have both evolved under a natural cycle of light and dark. But especially in urban areas, the night is now increasingly disturbed by artificial light. Many traits and behaviours in fish are triggered by a circadian clock, for example hatching and swim bladder inflation, which predominantly take place at dusk or night. As lighting becomes brighter and extends farther into rural areas, the distinction between day and night becomes increasingly blurred. Therefore, the loss of diurnal trigger by artificial light at night was hypothesized having deleterious effects on these traits and impact fish reproduction. To assess these effects, eggs of four native freshwater fishes, Eurasian perch Perca fluviatilis, roach Rutilus rutilus, bleak Alburnus alburnus and chub Leuciscus cephalus, were incubated under two different light conditions: a photoperiod of 14 h light:10 h darkness (LD) and continuous illumination (LL). The time to hatch and swim bladder inflation was recorded. The species showed inconsistent reactions to the light treatments. In roach and bleak, the time to 50% hatch was longer in LL, whereas continuous lighting had an accelerating effect in chub. Incubation in LL elongated the hatching period in perch and roach and, in perch, the onset of darkness seemed to trigger hatching. The swim bladder inflation was significantly promoted by continuous light in chub and bleak but was not affected in roach. In conclusion, nocturnal artificial illumination could have an effect on hatching and initial swim bladder filling by masking the day–night-change and thereby diminish the trigger effect. However, the reactions were species specific and the increase in variation indicated a lack of diurnal triggering, whilst a general deleterious effect of artificial light at night has not been identified on early life stages.     

土地利用变化空间模拟的进展--CLUE-S模型及其应用

土地利用变化的空间模拟是进行土地利用情景分析的重要基础。本文在介绍了国际上常用的细胞自控模型(CA)、土地利用变化及效应模型(CLUE)的基础上,重点分析了小尺度土地利用变化及效应模型(CLUE-S)的方法,并以邯郸地区为例进行了案例研究。认为CLUE-S模型采取经验模型的方法,通过建立土地利用空间分配和驱动因子之间的统计关系模拟近期土地利用变化的情景。同时也考虑了不同土地利用方式之间的竞争关系,因此可以较好地模拟小尺度地区的近期土地利用变化情景;考虑到短期或近期土地利用变化的因子主要与人类的社会经济活动有关,而社会经济因子的空间化尚存在一定难度。因此,突破这一瓶颈成为CLUE-S模型发展和应用的关键;CLUE-S模型主要解决的是不同空间尺度上的土地利用空间分配问题,在土地生产潜力评价、土地利用规划等方面具有广阔的应用前景。     

The role of prior model calibration on predictions with ensemble Kalman filter

This paper, based on a real world case study (Limmat aquifer, Switzerland), compares inverse groundwater flow models calibrated with specified numbers of monitoring head locations. These models are updated in real time with the ensemble Kalman filter (EnKF) and the prediction improvement is assessed in relation to the amount of monitoring locations used for calibration and updating. The prediction errors of the models calibrated in transient state are smaller if the amount of monitoring locations used for the calibration is larger. For highly dynamic groundwater flow systems a transient calibration is recommended as a model calibrated in steady state can lead to worse results than a noncalibrated model with a well-chosen uniform conductivity. The model predictions can be improved further with the assimilation of new measurement data from on-line sensors with the EnKF. Within all the studied models the reduction of 1-day hydraulic head prediction error (in terms of mean absolute error [MAE]) with EnKF lies between 31% (assimilation of head data from 5 locations) and 72% (assimilation of head data from 85 locations). The largest prediction improvements are expected for models that were calibrated with only a limited amount of historical information. It is worthwhile to update the model even with few monitoring locations as it seems that the error reduction with EnKF decreases exponentially with the amount of monitoring locations used. These results prove the feasibility of data assimilation with EnKF also for a real world case and show that improved predictions of groundwater levels can be obtained.     

Bildung bromhaltiger Desinfektionsnebenprodukte nach Chlorung von Bodenseewasser in Abhängigkeit von Aufbereitungsschritten und der Bromidkonzentration

Formation of Brominated Disinfection By-products after Chlorination of Water from Lake Constance Depending on Treatment Steps and Bromide Concentration The formation of halogenated disinfection by-products (DNP) (trihalomethanes (THM), haloacetic acids (HES), haloacetonitriles (HAN), haloketones (HKE) and chloropicrin (TCNM)) was studied after chlorination (0.5 mg/L) of raw water and drinking water from Lake Constance. The objectives of this study were to investigate the effect of bromide ion on the distribution of DNP-species resulting from chlorination and to draw up a bromide mass-balance. The treatment of water from Lake Constance with ozone decreased the formation of DNP about 35% and of total organic halogens (AOX) about 45%. This decline in DNP-formation is mainly due to the formation of chloroform, dichloro- and trichloroacetic acid. Though there is only a small amount of bromide (6.2 μg/L) in water from Lake Constance, about 32% of THM, 16% of HES, and 30% of HAN contained bromine after chlorination of treated water. The addition of bromide ion (up to 1 mg/L) shifted the DNP-composition to more brominated species. The distribution of the DNP-species depends on the initial molar bromide-to-chlorine ratio. A mathematic model showed the same pattern of DNP-species depending on the initial molar bromide-to-chlorine ratio that was observed experimentally in microstrained raw water and drinking water from Lake Constance. After chlorination of microstrained raw water, 27% of the bromide were incorporated in known DNP, 34% in unknown substances, and about 39% of bromide were not converted to organic bromine. After chlorination of treated water, only 16% of the bromide were incorporated in unknown substances, whereas 34% were found in known DNP. About 50% were found as bromide again. After addition of bromide (up to 25 μg/L) to ozonated and treated water from Lake Constance, between 60 and 72% of the bromide that had reacted after chlorination were found in analyzed low-molecular DNP.     

SporadicE ionization associated with meteor events

Two meteor events which were sighted in the Gujarat skies of India, were accompained by the visibility of sporadicE ionization on the ionograms recorded at Ahmedabad (Geog. Lat. 23·2°N, long. 72·30°E). The first event was the Dhajala fireball which flashed into the geoatmosphere along an E-N to W-S trail at about 20·40 h IST on 28 January 1976; the closest distance of the ground projection of meteor trail from Ahmedabad was 50km. The other event was a possible meteor group sighted over Ahmedabad on 28 May 1978, at about 21·10 h IST. This work describes the nature of the sporadicE ionization observed on Ahmedabad ionograms during the two events. Features of theEs echo during the Dhajala event which indicate that it could be of meteoric origin are discussed. Meteor theory is used to relate the observed ionization with the physical dimensions of the Dhajala meteorite as obtained by other workers.